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    • 5. 发明授权
    • Conductive primer composition for ambient cure
    • 用于环境固化的导电底漆组合物
    • US07144526B2
    • 2006-12-05
    • US10357828
    • 2003-02-04
    • Henry Stever Tremper, IIIHenry A. Tronco, Jr.Valentina Gordin
    • Henry Stever Tremper, IIIHenry A. Tronco, Jr.Valentina Gordin
    • H01B1/24B05D5/12
    • C09D175/06C08G18/283C08G18/4202C08G18/4219C08G18/6229C08G18/6295C08G18/792C08K3/013C08K3/04C09D5/24
    • The present invention provides electrically conductive and flexible primer compositions that harden to form conductive materials under room temperature or low bake temperature curing conditions. The primer composition contains solvents and 40–75% by weight of film forming binder and pigments in an overall pigment to binder weight ratio of about 1:100 to 100:100; wherein the binder contains (A) a flexible hydroxy containing polyester resin and (B) an organic polyisocyanate crosslinking agent; and wherein the pigments include electrically conductive pigments in a pigment to binder weight ratio of about 1:100 to 130:100 and the electrically conductive pigments consists essentially of a combination of graphite and conductive carbon black pigments in a graphite to carbon black weight ratio of about 120:1 to 1:1, and the composition forms a hard, flexible coating having a surface conductivity of at least 100 Ransburg units when cured at room temperature or low bake conditions. The coating composition can be used on metal or plastic substrates to render the substrate conductive.
    • 本发明提供在室温或低烘烤温度固化条件下硬化以形成导电材料的导电和柔性底漆组合物。 底漆组合物含有溶剂和40-75重量%的成膜粘合剂和颜料,其总颜料与粘合剂的重量比为约1:100至100:100; 其中所述粘合剂含有(A)含柔性羟基的聚酯树脂和(B)有机多异氰酸酯交联剂; 并且其中所述颜料包括颜料与粘合剂重量比为约1:100至130:100的导电颜料,并且所述导电颜料基本上由石墨和导电炭黑颜料的组合组成,石墨与炭黑的重量比为 约120:1至1:1,并且当在室温或低烘烤条件下固化时,组合物形成具有至少100兰斯堡单位的表面电导率的硬质柔性涂层。 涂料组合物可用于金属或塑料基材上以使基材导电。
    • 8. 发明授权
    • Curable composition for topcoating and articles coated therewith
    • 用于表面涂层的固化组合物和用其涂覆的制品
    • US06383648B1
    • 2002-05-07
    • US09402821
    • 1999-12-30
    • Hitoshi TamaiMasaharu Inoue
    • Hitoshi TamaiMasaharu Inoue
    • B32B904
    • C08G18/6216C08G18/3893C08G18/6295C09D175/04Y10T428/31663
    • The present invention has its objects to provide a curable composition for top coating which has an excellent stain resistance, adhesiveness, solvent resistance and impact resistance. The present invention relates to a curable composition for top coating which comprises an acrylic copolymer (A) containing a reactive silyl group bound to a carbon atom as represented by the general formula (1) (wherein R1 represents a hydrogen atom or an alkyl group containing 1 to 10 carbon atoms, R2 represents a hydrogen atom or a univalent hydrocarbon group selected from among alkyl groups containing 1 to 10 carbon atoms, aryl groups and aralkyl groups and a represents an integer of 0 to 2), together with a hydroxyl group; 2 to 70 parts by weight, per 100 parts by weight of acrylic copolymer (A), of a silicon compound represented by the general formula (2) (wherein R3 represents a univalent hydrocarbon group selected from among alkyl groups containing 1 to 10 carbon atoms, aryl groups and aralkyl groups, R4 represents a univalent hydrocarbon group selected from among alkyl groups containing 1 to 10 carbon atoms, aryl groups and aralkyl groups and b represents 0 or 1), and/or a partial hydrolyzate condensate (B) thereof; and 0.1 to 50 parts by weight of a compound (C) containing two or more isocyanate groups which serves as a crosslinking agent.
    • 本发明的目的是提供一种具有优异的耐污性,粘合性,耐溶剂性和耐冲击性的顶涂层用固化性组合物。 本发明涉及一种顶涂剂用固化性组合物,其包含含有与通式(1)表示的碳原子结合的活性甲硅烷基的丙烯酸共聚物(A)(其中,R1表示氢原子或含有烷基的烷基 1〜10个碳原子,R2表示氢原子或选自含1〜10个碳原子的烷基,芳基和芳烷基,a表示0〜2的整数的一价烃基)和羟基; 2〜70重量份,相对于100重量份丙烯酸共聚物(A),由通式(2)表示的硅化合物(其中,R 3表示选自含有1〜10个碳原子的烷基中的一价烃基) ,芳基和芳烷基,R 4表示选自含有1至10个碳原子的烷基,芳基和芳烷基,b表示0或1)的一价烃基,和/或其部分水解产物缩合物(B); 和0.1〜50重量份含有两个以上作为交联剂的异氰酸酯基的化合物(C)。
    • 9. 发明授权
    • Fluorochemical composition comprising a urethane having a fluorochemical oligomer and a hydrophilic segment to impart stain release properties to a substrate
    • 含氟化合物组合物包含具有含氟低聚物和亲水链段的氨基甲酸酯,以赋予基材去污性能
    • US06239247B1
    • 2001-05-29
    • US09381865
    • 1999-09-24
    • Kathy E. M. L. A. AllewaertRudolf J. DamsPierre J. Vander Elst
    • Kathy E. M. L. A. AllewaertRudolf J. DamsPierre J. Vander Elst
    • C08G1848
    • C08G18/4063C08G18/4825C08G18/6279C08G18/6295C08G18/672C08G18/8077
    • The present invention provides a method for preparing a fluorochemical composition comprising a urethane by reacting: (A) fluorochemical oligomer of the formula (I): MfmMn—Q1—T1 wherein MfmMn represents a fluorochemical oligomer comprising m units derived from fluorinated monomer and n units derived from fluorine-free monomer and wherein the fluorinated monomers and fluorine-free monomers may be the same or different; m is a value of about 2 to 40; n is a value of about 0 to 20; T1 is an —OH or —NH2 moiety; Q1 and T1 together represent an organic residue obtained by removing a hydrogen atom from a chain transfer agent that is functionalized with T1; (B) monofunctional compound capable of reacting with an isocyanate and comprising a poly(oxyalkylene) group; (C) isocyanate blocking agent or a fluorine-free oligomer; and (D) isocyanate-reactive compound other than said fluorochemical oligomer, said isocyanate blocking agent, said fluorine-free oligomer and said monofunctional compound; with (E) diisocyanate or a triisocyanate, wherein 33% to 67% of the number of isocyanate groups are reacted with the fluorochemical oligomer according to the formula (I), 33% to 67% of the number of isocyanate groups are reacted with said monofunctional compound, 0 to 33% of the number of isocyanate groups are reacted with an isocyanate blocking agent or a fluorine-free oligomer and 0 to 10% of the number of isocyanate groups are reacted with said isocyanate-reactive compound.
    • 本发明提供一种制备含有氨基甲酸酯的含氟化合物组合物的方法,该方法包括:(A)式(I)的氟化物低聚物:MfmMn-Q1-T1,其中MfmMn表示含有源自氟化单体的m个单元和n个单元的含氟低聚物 衍生自无氟单体,其中氟化单体和无氟单体可以相同或不同; m为约2〜40的值; n为约0〜20的值; T1是-OH或-NH2部分; Q1和T1一起表示通过用T1官能化的链转移剂除去氢原子获得的有机残基; (B)能够与异氰酸酯反应并且包含聚(氧化烯)基团的单官能化合物; (C)异氰酸酯封端剂或无氟低聚物; 和(D)除所述含氟低聚物以外的异氰酸酯反应性化合物,所述异氰酸酯封端剂,所述无氟低聚物和所述单官能化合物; 与(E)二异氰酸酯或三异氰酸酯反应,其中33%至67%的异氰酸酯基数与根据式(I)的含氟低聚物反应,33%至67%的异氰酸酯基数与所述 使异氰酸酯基数为0〜33%与异氰酸酯封端剂或无氟低聚物反应,0〜10%的异氰酸酯基与异氰酸酯反应性化合物反应。
    • 10. 发明授权
    • Resinous composition for coating
    • 用于涂层的树脂组合物
    • US5658988A
    • 1997-08-19
    • US496481
    • 1995-06-29
    • Shinichi OginoNobushige NumaShinji TomitaHajime Sukejima
    • Shinichi OginoNobushige NumaShinji TomitaHajime Sukejima
    • C08F230/08C08G18/62C08G18/72C09D201/10C08L43/04C08L83/06
    • C08G18/6295C08F230/08C08G18/728C09D201/10Y10T428/31547Y10T428/31663Y10T428/31855
    • A one-package resinous coating composition, especially for automobile finishes (A) a resin having a siloxy group, and (B) a catalyst for dissociating the siloxy group. Resinous mixture (A) contains one or more of the following (A-1) through (A-4). (A-1) a mixture of (a) a resin that contains at least one siloxy group and one alkoxysilyl group respectively in the one molecule, and (b) a resin that contains at least one isocyanate group and one alkoxysilyl group respectively in the one molecule; (A-2) a mixture of (a) a resin that contains at least one siloxy group and one alkoxysilyl group respectively in the one molecule, and (c) a compound or a resin that contains at least two isocyanate groups in the one molecule; (A-3) a mixture of (b) a resin that contains at least one isocyanate group and one alkoxysilyl group respectively in the one molecule, and (d) a compound or a resin that contains at least two siloxy groups in the one molecule; and (A-4) (e) a resin that contains at least one siloxy group, one isocyanate group and one alkoxysilyl group respectively in the one molecule.
    • 一种单组分树脂涂料组合物,特别是用于汽车涂料(A)具有甲硅烷氧基的树脂,和(B)用于解离甲硅烷氧基的催化剂。 树脂混合物(A)含有以下(A-1)〜(A-4)中的一种以上。 (A-1)分子中分别含有至少一个甲硅烷氧基和一个烷氧基甲硅烷基的树脂的混合物,和(b)分别含有至少一个异氰酸酯基和一个烷氧基甲硅烷基的树脂 一分子 (A-2)(a)在一个分子中分别含有至少一个甲硅烷氧基和一个烷氧基甲硅烷基的树脂的混合物,和(c)在一个分子中含有至少两个异氰酸酯基团的化合物或树脂 ; (A-3)分子中的(b)分子中含有至少一个异氰酸酯基和一个烷氧基甲硅烷基的树脂的混合物,和(d)在一个分子中含有至少两个甲硅烷氧基的化合物或树脂 ; 和(A-4)(e)分子中含有至少一个甲硅烷氧基,一个异氰酸酯基和一个烷氧基甲硅烷基的树脂。