会员体验
专利管家(专利管理)
工作空间(专利管理)
风险监控(情报监控)
数据分析(专利分析)
侵权分析(诉讼无效)
联系我们
交流群
官方交流:
QQ群: 891211   
微信请扫码    >>>
现在联系顾问~
热词
    • 9. 发明申请
    • PROCESS FOR PREPARING A POLYMER HAVING A 2,5-FURANDICARBOXYLATE MOIETY WITHIN THE POLYMER BACKBONE AND SUCH (CO)POLYMERS
    • 制备聚合物背胶和这种(CO)聚合物中的2,5-FURANDICARBOXYLATE MOIETY的聚合物的方法
    • US20160312008A1
    • 2016-10-27
    • US15203991
    • 2016-07-07
    • Furanix Technologies B.V.
    • Laszlo Sipos
    • C08K5/52
    • C08G63/85C08G63/181C08G63/60C08G63/668C08G63/672C08G63/80C08K5/52
    • A process for preparing a polymer having a 2,5-furandicarboxylate moiety within the polymer backbone and having a number average molecular weight of at least 10,000 (as determined by GPC based on polystyrene standards) includes a first step where a prepolymer is made having the 2,5-furandicarboxylate moiety within the polymer backbone, followed in a second step by a polycondensation reaction. In the first step a 2,5-furandicarboxylate ester is transesterified with a compound or mixture of compounds containing two or more hydroxyl groups, in the presence of a tin(IV) based transesterification catalyst. In the second step at reduced pressure and under melt conditions the prepolymer prepared in the first step is polycondensed in the presence of a tin (II) based polycondensation catalyst until the polymer is obtained. This polymer may then be subjected to Solid State Polycondensation. Polymers so produced may have a 2,5-furandicarboxylate moiety within the polymer backbone, and having a number average molecular weight of at least 20,000 (as determined by GPC based on styrene standards), and an absorbance as a 5 mg/mL solution in a dichloromethane:hexafluoroisopropanol 8:2 at 400 nm of below 0.05.
    • 制备聚合物主链中具有2,5-呋喃二羧酸酯部分并具有至少10,000的数均分子量(通过基于聚苯乙烯标准的GPC测定)的聚合物的方法包括第一步骤,其中制备预聚物,其具有 2,5-呋喃二羧酸酯部分,然后在第二步中进行缩聚反应。 在第一步中,在锡(IV)基酯交换催化剂的存在下,将2,5-呋喃二羧酸酯与含有两个或多个羟基的化合物或混合物进行酯交换。 在减压和熔融条件下的第二步中,在第一步中制备的预聚物在基于锡(II)的缩聚催化剂的存在下进行缩聚,直至得到聚合物。 然后可以对该聚合物进行固态缩聚。 如此制备的聚合物可以在聚合物主链内具有2,5-呋喃二羧酸酯部分,并且具有至少20,000的数均分子量(通过基于苯乙烯标准的GPC测定),并且作为5mg / mL溶液的吸光度 二氯甲烷:六氟异丙醇8:2在400nm以下0.05以下。