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1. 发明授权

US11988962B2 Colored photosensitive resin composition 有权
公开(公告)号：US11988962B2
公开(公告)日：2024-05-21
申请号：US16965430
申请日：2019-01-28
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Jumpei Morimoto , Takakiyo Terakawa
IPC分类号： G03F7/004 , C09B11/26 , C09B47/04 , C09B67/20 , C09B67/22 , G02B1/04 , G03F7/00 , G03F7/033 , G02B5/20
CPC分类号： G03F7/0045 , C09B11/26 , C09B47/04 , C09B67/0033 , C09B67/0064 , G02B1/04 , G03F7/0007 , G03F7/033 , G02B5/20
摘要： An object of the present invention is to provide a colored photosensitive resin composition capable of forming a color filter having a higher brightness than that of the color filter formed from the conventionally known colored photosensitive resin composition.
The colored photosensitive resin composition according to the present invention comprises a colorant, a resin, a polymerizable compound, and a polymerization initiator, the colorant comprising a compound represented by formula (1) and an α-type and/or β-type copper phthalocyanine pigment,

wherein Mr+ represents an r-valent metal ion; k represents the sum of the number of —SO3− and the number of —SO2—N−—SO2—Rf in the compound represented by formula (1); r represents an integer of 1 or more; Rf represents a fluoroalkyl group having 1 to 12 carbon atoms; and the compound represented by formula (1) has at least one —SO3− or —SO2—N−—SO2—Rf.

2. 发明授权

US11920039B2 Malachite green based radio-chromic compounds and radiation sensing systems incorporating the compounds 有权
公开(公告)号：US11920039B2
公开(公告)日：2024-03-05
申请号：US16775558
申请日：2020-01-29
申请人： SAVANNAH RIVER NUCLEAR SOLUTIONS, LLC , UNIVERSITY OF KENTUCKY RESEARCH FOUNDATION
发明人： Aaron L. Washington, II , John T. Bobbitt, III , John E. Anthony , Brent Peters , James C. Nicholson
IPC分类号： C09B11/20 , C09B11/26 , C09K9/02 , G01T1/04
CPC分类号： C09B11/20 , C09B11/26 , C09K9/02 , G01T1/04
摘要： Derivatized malachite green leuco dyes for use in radio-chromic systems are described. The dyes have the following structure:

in which Ar is a substituted phenyl or thiophene ring in which at least one substitution of the Ar ring is not ortho to the bond between the ring and the linking carbon, and in which R1, R2, R3, and R4 are independently selected from methyl, alkyl, or alkyl halide. The systems include the dyes in conjunction with an activator, e.g., a halogenated activator, and a carrier, e.g., a fluid carrier or an encapsulating polymeric matrix.

3. 发明授权

US08383841B2 Phenyl xanthene dyes 有权
标题翻译：苯基呫吨染料
公开(公告)号：US08383841B2
公开(公告)日：2013-02-26
申请号：US12351504
申请日：2009-01-09
申请人： Joe Y. L. Lam , Steven M. Menchen , Ruiming Zou , Scott C. Benson
发明人： Joe Y. L. Lam , Steven M. Menchen , Ruiming Zou , Scott C. Benson
IPC分类号： C09B11/06 , C09B11/24
CPC分类号： C09B11/24 , C07D311/82 , C07D491/14 , C09B11/06 , C09B11/12 , C09B11/22 , C09B11/26 , C09B13/00 , C09B57/00 , C09B62/0025
摘要： Fluorescent phenyl xanthene dyes are described that comprise any fluorescein, rhodamine or rhodol comprising a particular C9 phenyl ring. One or both of the ortho groups on the lower C9 phenyl ring is ortho substituted with a group selected from alkyl, heteroalkyl, alkoxy, halo, haloalkyl, amino, mercapto, alkylthio, cyano, isocyano, cyanato, mercaptocyanato, nitroso, nitro, azido, sulfeno, sulfinyl, and sulfino. In one embodiment, halo and/or hydroxy groups are used. Optimal dyes contain a lower C9 phenyl ring in which both ortho groups are the same and the lower ring exhibits some form a symmetry relative to an imaginary axis running from the phenyl rings point of attachment to the remainder of the xanthene dye through a point para to the point of attachment. The phenyl xanthene dyes may be activated. Furthermore, the phenyl xanthene dyes may be conjugated to one or more substances including other dyes. The phenyl xanthene dyes are useful for a number of purposes, including labels for use in automated DNA sequencing as well the formation of fluorescent “bar codes” for polymeric particles used in the multiplexed analysis of analytes.
摘要翻译：描述了包含任何含有特定C 9苯环的任何荧光素，罗丹明或若丹明的荧光苯基呫吨染料。下C9苯环上的一个或两个邻基被选自烷基，杂烷基，烷氧基，卤素，卤代烷基，氨基，巯基，烷硫基，氰基，异氰基，氰基，巯基氰基，亚硝基，硝基，叠氮基，磺酰亚胺基，亚磺酰基和亚磺酰基。在一个实施方案中，使用卤素和/或羟基。最佳染料含有较低的C 9苯环，其中两个邻基团相同，并且下环表现出相对于从苯环连接点到呫吨染料的其余部分的假想轴的对称性。附件点。苯基呫吨染料可以被活化。此外，苯基呫吨染料可以与一种或多种包括其它染料的物质共轭。苯基呫吨染料可用于许多目的，包括用于自动DNA测序的标记，以及在分析物多重分析中使用的聚合物颗粒的荧光条形码的形成。

4. 发明授权

US07211118B2 Composition for dyeing keratin fibers comprising a defined triheteroylmethane direct dye or leuco precursor of this dye and dyeing method using it 失效
标题翻译：用于染色角蛋白纤维的组合物，其包含该染料的限定的三酰基甲烷直接染料或无色前体和使用其的染色方法
公开(公告)号：US07211118B2
公开(公告)日：2007-05-01
申请号：US10746497
申请日：2003-12-29
申请人： Frédéric Guerin , Alain Lagrange
发明人： Frédéric Guerin , Alain Lagrange
IPC分类号： A61K7/13
CPC分类号： A61K8/49 , A61K8/492 , A61K8/4926 , A61Q5/10 , C09B11/26
摘要： A composition for dyeing keratin fibers, such as human keratin fibers, and further such as the hair, comprising at least one dye chosen from heteroylmethane type direct dyes, such as triheteroylmethane direct dyes and leuco precursors of such dyes, as defined herein. A method that uses the composition for dyeing keratin fibers, such as human keratin fibers, and further such as the hair, and a kit or device containing same.
摘要翻译：用于染色角蛋白纤维的组合物，例如人角蛋白纤维，以及进一步如头发，其包含至少一种选自异构甲烷型直接染料的染料，例如三酰基甲烷直接染料和如本文所定义的这种染料的无色前体。使用该组合物染色角蛋白纤维的方法，例如人角蛋白纤维，以及进一步如头发，以及含有其的试剂盒或装置。

5. 发明授权

US07211117B2 Composition for dyeing keratin fibers comprising at least one dye chosen from monoheteroyldiarylmethane direct dyes and the leuco precursors thereof and dyeing method using it 失效
标题翻译：用于染色角蛋白纤维的组合物，其包含至少一种选自单酰基二芳基甲烷直接染料和其无色前体的染料和使用其的染色方法
公开(公告)号：US07211117B2
公开(公告)日：2007-05-01
申请号：US10745634
申请日：2003-12-29
申请人： Frédéric Guerin , Alain Lagrange
发明人： Frédéric Guerin , Alain Lagrange
IPC分类号： A61K7/13
CPC分类号： A61Q5/10 , A61K8/411 , A61K8/492 , A61K8/4973 , A61K8/4986 , C09B11/26
摘要： A composition for dyeing keratin fibers, for example, human keratin fibers, such as hair, comprising at least one dye chosen from heteroyldiarylmethane type direct dyes, for example, monoheteroyidiarylmethane direct dyes, and the leuco precursors thereof; and also to methods for dyeing keratin fibers, for example, human keratin fibers, such as hair, using the composition, and multi-compartment devices.
摘要翻译：用于染色角蛋白纤维的组合物，例如人角蛋白纤维，例如毛发，其包含至少一种选自杂芳基二芳基甲烷型直接染料的染料，例如单异烟酰基芳基甲烷直接染料及其无色前体; 以及使用该组合物染色角蛋白纤维例如人角蛋白纤维如毛发的方法以及多室装置。

6. 发明授权

US5391762A Nir dyes, methods of preparing them and their use 失效
标题翻译：尼尔染料，其制备方法及其用途
公开(公告)号：US5391762A
公开(公告)日：1995-02-21
申请号：US121018
申请日：1993-09-14
申请人： Rudolf Naef , Beat Schmidhalter , Hanspeter Preiswerk
发明人： Rudolf Naef , Beat Schmidhalter , Hanspeter Preiswerk
IPC分类号： B41M5/26 , C07D209/14 , C07D401/06 , C07D405/06 , C07D409/06 , C07D471/04 , C07D491/16 , C09B11/02 , C09B11/26 , G11B7/244 , C07D221/18 , C07D221/06
CPC分类号： G11B7/244 , C09B11/26
摘要： The compounds of the formula I ##STR1## in which Y and Y.sub.1 are each, independently of one another, O, S, NH or N-alkyl, N-cycloalkyl, N-phenyl or N-benzyl, or Y and Y.sub.1 are together N-alkylene-N,R and R.sub.1 are each, independently of one another, H, alkyl, cycloalkyl, aralkyl or aryl,R.sub.2 and R.sub.3 are each, independently of one another, H, or R.sub.2 forms, together with R.sub.6 and the N and C atoms linking them, a 5- or 6-membered ring and R.sub.3 is H, or R.sub.3 forms, together with R.sub.7 and the N and C atoms linking them, a 5- or 6-membered ring and R.sub.2 is H,R.sub.4 and R.sub.5 are each, independently of one another, H, R.sub.4 forms, together with R.sub.8 and the N and C atoms linking them, a 5- or 6-membered ring and R.sub.5 is H, or R.sub.5 forms, together with R.sub.9 and the N and C atoms linking them, a 5- or 6-membered ring and R.sub.4 is H,R.sub.6, R.sub.7, R.sub.8 and R.sub.9 are each, independently of one another, H, alkyl, cycloalkyl, aralkyl or aryl, or R.sub.6 and R.sub.8 and/or R.sub.7 and R.sub.9 form, together with the N atom linking them, a piperidine radical, a morpholine radical or an unsubstituted piperazine radical or a piperazine radical substituted on the N atom by C.sub.1 -C.sub.4 alkyl, hydroxyl-C.sub.1 -C.sub.4 alkyl or amino-C.sub.1 -C.sub.4 alkyl,Z is H or aryl andAn.sup..crclbar. is an anion of a monobasic acid, the alkyl or cycloalkyl being unsubstituted or substituted by halogen, hydroxyl, C.sub.1 -C.sub.4 alkoxy, cyano or phenyl, andthe aryl or aralkyl being unsubstituted or substituted by halogen, hydroxyl, NH-alkyl, N(alkyl).sub.2, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.4 alkoxy, carboxyl, alkoxycarbonyl, carbonamido, mono- or dialkylcarbonamido, nitro or CN, are suitable as light-absorbing substances in optical recording media.
摘要翻译：其中Y和Y1各自独立地为O，S，NH或N-烷基，N-环烷基，N-苯基或N-苄基，或Y和 Y1一起是N-亚烷基-N，R和R 1各自独立地为H，烷基，环烷基，芳烷基或芳基，R 2和R 3各自独立地为H或R 2形式，以及R 6 连接它们的N和C原子，R 3是H或R 3与R 7和连接它们的N和C原子一起形成5-或6-元环，R 2是H R 4和R 5各自独立地为H，R 4与R 8和连接它们的N和C原子一起形成5-或6-元环，并且R 5是H或R 5与R 9和R 9一起形成连接它们的N和C原子，5或6元环，R 4是H，R 6，R 7，R 8和R 9彼此独立地是H，烷基，环烷基，芳烷基或芳基，或R 6和R 8 和/或R 7和R 9与连接它们的N原子一起形成哌啶基，一种脱模剂羟基-C 1 -C 4烷基或氨基-C 1 -C 4烷基，Z是H或芳基，An（ - ）是一元酸的阴离子，烷基或环烷基是未取代的或被卤素，羟基，C 1 -C 4烷氧基，氰基或苯基取代，芳基或芳烷基是未取代的或被卤素，羟基，NH-烷基，N（烷基）2，C 1 -C 6烷基， C1-C4烷氧基，羧基，烷氧基羰基，碳酰氨基，单或二烷基酰氨基，硝基或CN适合作为光记录介质中的光吸收物质。

7. 发明授权

US5233048A Triarylmethane color formers 失效
标题翻译：三芳基甲烷成色剂
公开(公告)号：US5233048A
公开(公告)日：1993-08-03
申请号：US942112
申请日：1992-09-08
申请人： Udo Eckstein , Roderich Raue
发明人： Udo Eckstein , Roderich Raue
IPC分类号： B41M5/136 , B41M5/323 , C07D249/08 , C09B11/10 , C09B11/26
CPC分类号： C09B11/26 , B41M5/1366 , B41M5/323 , C09B11/10
摘要： Color formers of the general formula ##STR1## in which --independently of one another-- R.sup.1 and R.sup.2 are hydrogen, halogen, alkyl, aralkyl etc.,Y.sup.1 and Y.sup.2 are alkyl, aryl, cycloalkyl or aralkyl,X.sup.1 is alkyl, alkenyl, cycloalkyl, aralkyl etc.,X.sup.2 is H, alkyl, alkenyl, cycloalkyl etc.X.sup.1 with X.sup.2 with the inclusion of the nitrogen atom carrying them can form a saturated or unsaturated 5- or 6-membered heterocyclic ring, andfurther isocyclic or heterocyclic rings can be fused with the rings A, B and C, upon incorporation in recording materials based on acid developers, show a particularly advantageous migration behaviour. Deep blue, green-blue, green, violet or red shades which have excellent sublimation and light fastness are obtained.
摘要翻译：通式（Ⅰ）所示的成色剂 - 其中R 1和R 2彼此独立地为氢，卤素，烷基，芳烷基等，Y 1和Y 2为烷基，芳基，环烷基或芳烷基，X 1为烷基，烯基，环烷基，芳烷基等，X 2是H，烷基，烯基，环烷基等。具有包含含有氮原子的X 2的X 1可以形成饱和或不饱和的5-或6-元杂环，并且还可以是环或当结合到基于酸显影剂的记录材料中时，杂环可以与环A，B和C稠合，显示出特别有利的迁移行为。获得了具有极好升华和耐光牢度的深蓝色，绿色 - 蓝色，绿色，紫色或红色色调。

8. 发明授权

US5143892A Chromogenic phthalides 失效
标题翻译：显色酞菁
公开(公告)号：US5143892A
公开(公告)日：1992-09-01
申请号：US700002
申请日：1991-05-14
申请人： Rudolf Zink
发明人： Rudolf Zink
IPC分类号： B41M5/145 , B41M5/327 , C07D405/04 , C09B11/26
CPC分类号： C09B11/26 , B41M5/145 , B41M5/327
摘要： Chromogenic phthalides of formula ##STR1## wherein X, R.sub.1 and R.sub.2 are each independently of the other C.sub.3 -C.sub.6 alkyl,Y.sub.1 is hydrogen, alkyl or not more than 12 carbon atoms which is unsubstituted or substituted by halogen, hydroxyl, cyano or lower alkoxy, or is acyl of 1 to 12 carbon atoms, benzyl or benzyl which is substituted by halogen, cyano, lower alkyl or lower alkoxy,Y.sub.2 is hydrogen, lower alkyl or phenyl, andthe benzene rings A and B are each independently of the other unsubstituted or substituted by halogen, nitro, lower alkyl, lower alkoxy, lower alkylthio, lower alkoxycarbonyl, amino, mono-lower alkylamino, di-lower alkylamino or lower alkanoylamino.These phthalides are particularly suitable for use as color formers in pressure-sensitive or heat-sensitive recording materials and give intense blue or violet blue colored images.
摘要翻译：式（1）的显色酞化物，其中X，R 1和R 2各自独立于其它C 3 -C 6烷基，Y 1是氢，烷基或不超过12个碳原子，未被取代或被卤素，羟基，氰基或低级烷氧基，或为1至12个碳原子的酰基，被卤素，氰基，低级烷基或低级烷氧基取代的苄基或苄基，Y2为氢，低级烷基或苯基，苯环A和B各自独立地为硝基，低级烷基，低级烷氧基，低级烷硫基，低级烷氧基羰基，氨基，单低级烷基氨基，二低级烷基氨基或低级烷酰基氨基取代。这些苯酞特别适合用作压敏或热敏记录材料中的成色剂，并产生强烈的蓝色或紫色蓝色图像。

9. 发明授权

US5094688A Triarylmethane color-forming agents 失效
标题翻译：三色甲醛成色剂
公开(公告)号：US5094688A
公开(公告)日：1992-03-10
申请号：US231796
申请日：1988-08-12
申请人： Udo Eckstein , Hubertus Psaar , Gert Jabs
发明人： Udo Eckstein , Hubertus Psaar , Gert Jabs
IPC分类号： C09B11/00 , B41M5/136 , B41M5/323 , C09B11/26
CPC分类号： C09B11/26 , B41M5/1366 , B41M5/323
摘要： Color-forming agents of the present formula ##STR1## wherein X denotes hydroxyl, alkoxy, alkenyloxy, aralkoxy, cycloalkoxy, aryloxy, acyloxy, alkylamino, dialkylamino, acylamino, aralkylamino or arylamino,R denotes alkyl, alkenyl or aralkyl,R.sub.1 denotes hydrogen, halogen or alkyl,R.sub.2 denotes alkoxy, aralkoxy, aryloxy or a radical of the formula ##STR2## Y.sub.1 and Y.sub.2 independently of one another denote alkyl, aryl, cycloalkyl or aralkyl or R.sub.2, with A in the o-position, forms a heterocyclic ring,a benzene ring can be fused onto the ring A, in the o-/m-position relative to R.sub.2, and the ring A and its fused-on rings and the cyclic and acyclic radicals can carry further non-ionic substitutents customary in dyestuffs chemistry,are used in thermoreactive papers and pressure-sensitive recording materials and for the preparation of highly concentrated solutions in organic solvents.
摘要翻译：本发明的成色剂（I）其中X表示羟基，烷氧基，烯氧基，芳烷氧基，环烷氧基，芳氧基，酰氧基，烷基氨基，二烷基氨基，酰氨基，芳烷基氨基或芳基氨基，R表示烷基，烯基或芳烷基表示氢，卤素或烷基，R 2表示烷氧基，芳烷氧基，芳氧基或式Y 1和Y 2基团彼此独立地表示烷基，芳基，环烷基或芳烷基或R 2，其中位于O位的A形成一个杂环，一个苯环可以相对于R2在o- / m-位上的A环上融合，并且环A及其稠合的环和环状和非环状的基团可以携带更多的非离子取代基常用于染料化学，用于热反应纸和压敏记录材料以及在有机溶剂中制备高浓度溶液。

10. 发明授权

US5039822A Chromogenic phthalides 失效
标题翻译：显色酞菁
公开(公告)号：US5039822A
公开(公告)日：1991-08-13
申请号：US395639
申请日：1989-08-16
申请人： Rudolf Zink
发明人： Rudolf Zink
IPC分类号： B41M5/145 , B41M5/327 , C07D405/04 , C09B11/26
CPC分类号： C09B11/26 , B41M5/145 , B41M5/327
摘要： Chromogenic phthalides of formula ##STR1## wherein X, R.sub.1 and R.sub.2 are each independently of the other C.sub.3 -C.sub.6 alkyl,Y.sub.1 is hydrogen, alkyl of not more than 12 carbon atoms which is unsubstituted or substituted by halogen, hydroxyl, cyano or lower alkoxy, or is acyl or 1 of 12 carbon atoms, benzyl or benzyl which is substituted by halogen, cyano, lower alkyl or lower alkoxy,Y.sub.2 is hydrogen, lower alkyl or phenyl, andthe benzene rings A and B are each independently of the other unsubstituted or substituted by halogen, nitro, lower alkyl, lower alkoxy, lower alkylthio, lower alkoxycarbonyl, amino, mono-lower alkylamino, di-lower alkylamino or lower alkanoylamino.These phthalides are particularly suitable for use as color formers in pressure-sensitive or heat-sensitive recording materials and give intense blue or violet blue colored images.
摘要翻译：式（1）的显色酞化物，其中X，R 1和R 2各自独立地为C 3 -C 6烷基，Y 1为氢，不超过12个碳原子的烷基，其未被取代或被卤素，羟基，氰基或低级烷氧基，或是酰基或12个碳原子中的1个，被卤素，氰基，低级烷基或低级烷氧基取代的苄基或苄基，Y2是氢，低级烷基或苯基，苯环A和B各自独立地为另一个未被取代或被卤素，硝基，低级烷基，低级烷氧基，低级烷硫基，低级烷氧基羰基，氨基，单低级烷基氨基，二低级烷基氨基或低级烷酰氨基取代。这些苯酞特别适合用作压敏或热敏记录材料中的成色剂，并产生强烈的蓝色或紫色蓝色图像。

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