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    • 4. 发明申请
    • POWDER DETERGENT GRANULE CONTAINING ACIDIC WATER-SOLUBLE POLYMER AND MANUFACTURING METHOD THEREOF
    • 含有酸性水溶性聚合物的粉末洗涤剂颗粒及其制造方法
    • US20110218136A1
    • 2011-09-08
    • US13046296
    • 2011-03-11
    • Min-Seok ChoYoung-Kee OhKee-Heon ChoHyun-Chang KimSang-Woon Kwak
    • Min-Seok ChoYoung-Kee OhKee-Heon ChoHyun-Chang KimSang-Woon Kwak
    • C11D17/06
    • C11D17/06C02F5/10C08F228/02C11D3/378C11D3/3784C11D11/04
    • The present invention relates to powder detergent granules that are substantially free of a water-insoluble component such as zeolite or silica, a method for manufacturing the powder detergent granules and a copolymer having various properties useful as a detergent component. The powder detergent granules of the present invention are substantially free of a water-insoluble component, and thus exhibit good solubility and washing performance (stain removal performance) in cold water, do not leave residue after laundry, and reduce the likelihood of a caking phenomenon during manufacture and storage. And, the powder detergent granules of the present invention are substantially free of zeolite or silica that absorbs a liquid component, but are capable of accommodating a considerable amount of liquid surfactant. Further, a copolymer comprising acrylic acid monomer unit and 2-acrylamido-2-methylpropane sulfonic acid monomer unit, an acidic water-soluble polymer of the present invention, is useful as a detergent component in various aspects.
    • 本发明涉及基本上不含水不溶性成分如沸石或二氧化硅的粉末洗涤剂颗粒,粉末洗涤剂颗粒的制造方法和可用作洗涤剂组分的各种性能的共聚物。 本发明的粉末洗涤剂颗粒基本上不含水不溶性组分,因此在冷水中表现出良好的溶解性和洗涤性能(去污性能),洗衣后不留下残留物,并降低结块现象的可能性 在制造和储存期间。 而且,本发明的粉末洗涤剂颗粒基本上不含吸收液体组分但能够容纳大量液体表面活性剂的沸石或二氧化硅。 此外,包含丙烯酸单体单元和2-丙烯酰氨基-2-甲基丙磺酸单体单元的共聚物,本发明的酸性水溶性聚合物在各个方面都可用作洗涤剂组分。
    • 6. 发明授权
    • Spray-drying process
    • 喷雾干燥过程
    • US07842657B2
    • 2010-11-30
    • US12480036
    • 2009-06-08
    • Hossam Hassan TantawyNigel Patrick Somerville RobertsSimon HoweStuart Andrew Caldwell
    • Hossam Hassan TantawyNigel Patrick Somerville RobertsSimon HoweStuart Andrew Caldwell
    • C11D11/02
    • C11D11/04C11D11/02
    • The present invention relates to a process for preparing a spray-dried powder comprising (i) anionic detersive surfactant; (ii) from 0 wt % to 10 wt % zeolite builder; (iii) from 0 wt % to 10 wt % phosphate builder; and (iv) optionally from 0 wt % to 15 wt % silicate salt; wherein the process comprises the steps of: (a) forming an alkaline slurry in a mixer, the slurry having a viscosity of from X to Y s−1 at a temperature of 70° C. and at a shear rate of 50 s−1, wherein the alkaline slurry is shear thinning; and (b) transferring the alkaline slurry from the mixer through at least one pump to a spray pressure nozzle; (c) contacting a viscosity increasing agent to the alkaline slurry after the mixer and before the spray pressure nozzle so as to increase the viscosity of the alkaline slurry to form a viscous alkaline slurry, step (c) being carried out at an average shear rate of from 10 s−1 to 150 s−1; (d) spraying the viscous alkaline slurry through the spray pressure nozzle into a spray-drying tower; (e) spray-drying the viscous alkaline slurry to form a spray-dried powder; and (f) optionally, contacting an alkalinity source with the alkaline slurry and/or the viscosity increasing agent, and/or the viscous alkaline slurry.
    • 本发明涉及一种制备喷雾干燥粉末的方法,包括(i)阴离子去污表面活性剂; (ii)0重量%至10重量%的沸石助洗剂; (iii)0重量%至10重量%的磷酸盐助洗剂; 和(iv)任选的0重量%至15重量%的硅酸盐; 其中所述方法包括以下步骤:(a)在混合器中形成碱性浆料,所述浆料在70℃的温度和50s -1的剪切速率下具有从X到Ys-1的粘度 其中碱性浆料是剪切稀化的; 和(b)将来自混合器的碱性浆料通过至少一个泵转移到喷雾压力喷嘴; (c)在混合器之后和喷雾压力喷嘴之前使粘度增加剂与碱性浆料接触,以增加碱性浆料的粘度以形成粘性碱性浆料,步骤(c)以平均剪切速率 为10秒-1至150秒-1; (d)将粘性碱性浆料通过喷雾压力喷嘴喷射到喷雾干燥塔中; (e)喷雾干燥粘性碱性浆料以形成喷雾干燥的粉末; 和(f)任选地,使碱度源与碱性浆料和/或增粘剂和/或粘性碱性浆液接触。
    • 7. 发明授权
    • Anionic surfactant powder
    • 阴离子表面活性剂粉末
    • US07833518B2
    • 2010-11-16
    • US10502404
    • 2003-01-29
    • Yasumitsu SakumaKazuhito Miyoshi
    • Yasumitsu SakumaKazuhito Miyoshi
    • A61K8/34
    • C11D11/04C11D1/29C11D17/06
    • To provide an anionic surfactant powder comprising a polyoxyalkylene ether sulfate which powder has high stability in hard water, high low-temperature solubility and is improved in powder characteristics such as caking characteristics, and a method of producing the anionic surfactant powder. An anionic surfactant powder comprising polyoxyalkylene alkyl ether sulfates in which the average addition mol number of alkylene oxides is 0.05 to 2, wherein the content of the polyoxyalkylene alkyl ether sulfates provided with alkylene oxides added thereto in an amount of 4 mol or more is 30 % by weight or less based on the total anionic surfactant, an anionic surfactant powder further comprising a water-soluble inorganic salt, a method of producing each of these anionic surfactant powders, and a detergent composition and a cement additive comprising these anionic surfactant powders.
    • 为了提供含有聚氧化烯醚硫酸盐的阴离子表面活性剂粉末,该粉末在硬水中具有高稳定性,高的低温溶解性,并且改善了粉末特性如结块特性,以及制备阴离子表面活性剂粉末的方法。 一种阴离子表面活性剂粉末,其包含其中环氧烷烃的平均加成摩尔数为0.05〜2的聚氧化烯烷基醚硫酸盐,其中以4摩尔以上的量添加有环氧烷烃的聚氧化烯烷基醚硫酸盐的含量为30质量% 基于总阴离子表面活性剂的阴离子表面活性剂粉末,进一步包含水溶性无机盐的阴离子表面活性剂粉末,每种这些阴离子表面活性剂粉末的制备方法,以及包含这些阴离子表面活性剂粉末的洗涤剂组合物和水泥添加剂。