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1. 发明授权

US08758871B2 Liquid crystal display and method for manufacturing same 有权
标题翻译：液晶显示器及其制造方法
公开(公告)号：US08758871B2
公开(公告)日：2014-06-24
申请号：US13212072
申请日：2011-08-17
申请人： Yasushi Tomioka , Hidetoshi Abe , Katsumi Kondo
发明人： Yasushi Tomioka , Hidetoshi Abe , Katsumi Kondo
IPC分类号： C09K19/56 , G02F1/1337
CPC分类号： G02F1/133723 , C09D179/08 , C09K19/542 , C09K19/56 , C09K2019/548 , G02F1/133788 , G02F1/134363 , G02F2201/121 , G02F2201/123 , G02F2202/08 , Y10T428/10 , Y10T428/1005 , Y10T428/1018 , Y10T428/1023 , Y10T428/1027 , Y10T428/1036
摘要： A liquid crystal display is provided which is capable of reducing the occurrence of defective display due to variations in the initial alignment direction of a liquid crystal alignment control film in a liquid crystal display of an IPS scheme, realizing the stable liquid crystal alignment, providing excellent mass productivity, and having high image quality with a higher contrast ratio. The liquid crystal display has a liquid crystal layer disposed between a pair of substrates, at least one of the substrates being transparent, and an alignment control film formed between the liquid crystal layer and the substrate. At least one of the alignment control films 109 comprises photoreactive polyimide and/or polyamic acid provided with an alignment control ability by irradiation of substantially linearly polarized light.
摘要翻译：提供了一种液晶显示器，其能够减少由IPS方案的液晶显示器中的液晶取向控制膜的初始取向方向的变化引起的不良显示的发生，实现了稳定的液晶取向，从而提供优异的批量生产率，并具有较高的图像质量和更高的对比度。液晶显示器具有设置在一对基板之间的液晶层，至少一个基板是透明的，以及形成在液晶层和基板之间的取向控制膜。取向控制膜109中的至少一个包括通过基本线性偏振光的照射而具有取向控制能力的光反应性聚酰亚胺和/或聚酰胺酸。

2. 发明申请

US20090197019A1 POLY(ARYLETHERIMIDES) FOR NEGATIVE BIREFRINGENT FILMS FOR LCDS 有权
公开(公告)号：US20090197019A1
公开(公告)日：2009-08-06
申请号：US11867372
申请日：2007-10-04
申请人： Frank W. Harris , Limin Sun , Dong Zhang , Stephen Z. D. Cheng
发明人： Frank W. Harris , Limin Sun , Dong Zhang , Stephen Z. D. Cheng
IPC分类号： C09K19/02 , C08G69/32 , B32B27/08
CPC分类号： C08G73/1039 , C08G73/1042 , C08G73/1067 , C08J5/18 , C08J2379/08 , G02B5/3083 , G02F1/133634 , Y10T428/1027 , Y10T428/1036 , Y10T428/1041 , Y10T428/31721
摘要： A negative birefringence film prepared from a poly(aryletherimide) which is the reaction product of a dianhydride and a diamine, where the dianhydride is BisADA, ODPA, BPEDA, BPQDA, BPDA, or 6FDA, alone or a mixture with one or more of: BPDA, 6FDA, BisADA, Bis-AF-DA, BPQDA, BPEDA, and ODPA; and where the diamine is 4,4′-diaminophenyl ether, 2-trifluoromethyl-4,4′-diaminophenyl ether, 2-trifluoromethyl-2′-methyl-4,4′-diaminophenyl ether, 1,4-bis(4-aminophenoxy)benzene, 4,4′-bis(4-aminophenoxy)biphenyl, 4,4′-bis(3-aminophenoxy)biphenyl, 4,4′-bis(4-aminophenoxy)terphenyl, 4,4′-bis(3-aminophenoxy)terphenyl, 2,2-bis[4-(4-aminophenoxy)phenyl]propane, 2,2-bis[4-(4-aminophenoxy)phenyl]1,1,1,3,3,3-hexafluoropropane, 1,4-bis(4-amino-2-trifluoromethylphenoxy)benzene, 2,2′-bis(trifluoromethyl)-4,4′-diaminophenyl ether (6FODA), 4,4′-bis(4-amino-2-trifluoromethylphenoxy)biphenyl (6FOBDA), 4,4′-bis(4-amino-2-trifluoromethylphenoxy)-3,3′,5,5′-tetramethylbiphenyl, 4,4′-bis(4-amino-2-trifluoromethylphenoxy)-3,3′,5,5′-tetra(tert-butyl)biphenyl, 4,4′-bis(3-amino-trifluoromethylphenoxy)biphenyl, 4,4′-bis(4-amino-2-trifluoromethylphenoxy)terphenyl, 2,2-bis[4-(4-amino-2-trifluoromethylphenoxy)-phenyl]propane, 2,2-bis[4-(4-amino-2-trifluoromethylphenoxy)-phenyl]1,1,1,3,3,3-hexafluoropropane, 1,4-bis(2-trifluoromethyl-4-aminophenoxy)-2,5-di(t-butyl)benzene (BTBDA), 3,3′-dimethyl-4,4′-diamino biphenyl (OTOL), 1,4-bis(2-trifluoromethyl-4-aminophenoxy)-2-t-butylbenzene, or mixtures thereof and wherein when a mixture of dianhydrides is present, they are present in a molar amount of between 99 to 1 (99:1) and 1 to 99 (1:99), and the film has a negative birefringence greater than 0.01, at a thickness of less than 15 μm, when the poly(aryletherimide) is solution cast or coated onto a substrate.

3. 发明授权

US07211302B2 Photostable liquid crystalline medium 有权
标题翻译：光稳定液晶介质
公开(公告)号：US07211302B2
公开(公告)日：2007-05-01
申请号：US10531376
申请日：2003-09-25
申请人： Atsutaka Manabe , Ulrich Heywang , Detlef Pauluth , Michael Heckmeier , Peer Kirsch , Elvira Montenegro
发明人： Atsutaka Manabe , Ulrich Heywang , Detlef Pauluth , Michael Heckmeier , Peer Kirsch , Elvira Montenegro
IPC分类号： C09K19/12 , C09K19/30 , C09K19/20
CPC分类号： C09K19/46 , C09K19/44 , C09K2019/123 , C09K2019/124 , C09K2019/3083 , Y10T428/10 , Y10T428/1027
摘要： The invention relates to a photostable liquid-crystalline medium comprising at least one compound of the formula I and at least one compound of the formula II and to the use thereof for electro-optical purposes, and to displays containing this medium.
摘要翻译：本发明涉及包含至少一种式I化合物和至少一种式II化合物的光稳定液晶介质及其用于电光学目的的用途，以及含有该介质的显示器。

4. 发明申请

US20050279968A1 Photostable liquid crystalline medium 有权
标题翻译：光稳定液晶介质
公开(公告)号：US20050279968A1
公开(公告)日：2005-12-22
申请号：US10531376
申请日：2003-09-25
申请人： Atsutaka Manabe , Ulrich Heywang , Detlef Pauluth , Michael Heckmeier , Peer Kirsch , Elvira Montenegro
发明人： Atsutaka Manabe , Ulrich Heywang , Detlef Pauluth , Michael Heckmeier , Peer Kirsch , Elvira Montenegro
IPC分类号： C09K19/44 , C09K19/46 , C09K19/30 , C09K19/12
CPC分类号： C09K19/46 , C09K19/44 , C09K2019/123 , C09K2019/124 , C09K2019/3083 , Y10T428/10 , Y10T428/1027
摘要： The invention relates to a photostable liquid-crystalline medium comprising at least one compound of the formula I and at least one compound of the formula II and to the use thereof for electro-optical purposes, and to displays containing this medium.
摘要翻译：本发明涉及包含至少一种式I化合物和至少一种式II化合物的光稳定液晶介质及其用于电光学目的的用途，以及含有该介质的显示器。

5. 发明申请

US20020012758A1 Polyimide angularity enhancement layer 有权
标题翻译：聚酰亚胺角度增强层
公开(公告)号：US20020012758A1
公开(公告)日：2002-01-31
申请号：US09825562
申请日：2001-04-03
申请人： 3M Innovative Properties Company
发明人： Stephen A. Ezzell , Hassan Sahouani , Ernest L. Thurber
IPC分类号： C09K019/00
CPC分类号： G02F1/133634 , C08G73/10 , C08G73/1039 , C08G73/1042 , C08G73/1075 , C08G73/1078 , C08G73/1082 , G02B5/3083 , Y10T428/10 , Y10T428/1005 , Y10T428/1023 , Y10T428/1027 , Y10T428/1036 , Y10T428/31721
摘要： An angularity enhancement layer in a liquid crystal display, which display comprises a liquid crystal cell, wherein the angularity enhancement layer includes a negative birefringent polyimide layer comprising a plurality of structural units having pendant fluorene groups, said angularity enhancement layer being disposed on at least one surface of said liquid crystal cell. A liquid crystal display can comprise an angularity enhancement construction of the invention which comprises a polyimide layer.
摘要翻译：液晶显示器中的角度增强层，其显示器包括液晶单元，其中所述角度增强层包括负的双折射聚酰亚胺层，所述负双折射聚酰亚胺层包含多个具有芴基侧基的结构单元，所述角度增强层设置在至少一个所述液晶单元的表面。液晶显示器可以包括本发明的角度增强结构，其包括聚酰亚胺层。

6. 发明授权

US06238753B1 Polyimide angularity enhancement layer 有权
标题翻译：聚酰亚胺角度增强层
公开(公告)号：US06238753B1
公开(公告)日：2001-05-29
申请号：US09534148
申请日：2000-03-23
申请人： Stephen A. Ezzell , Hassan Sahouani , Ernest L. Thurber
发明人： Stephen A. Ezzell , Hassan Sahouani , Ernest L. Thurber
IPC分类号： G02F11335
CPC分类号： G02F1/133634 , C08G73/10 , C08G73/1039 , C08G73/1042 , C08G73/1075 , C08G73/1078 , C08G73/1082 , G02B5/3083 , Y10T428/10 , Y10T428/1005 , Y10T428/1023 , Y10T428/1027 , Y10T428/1036 , Y10T428/31721
摘要： An angularity enhancement layer in a liquid crystal display, which display comprises a liquid crystal cell, wherein the angularity enhancement layer includes a negative birefringent polyimide layer comprising a plurality of structural units having pendant fluorene groups, said angularity enhancement layer being disposed on at least one surface of said liquid crystal cell. A liquid crystal display can comprise an angularity enhancement construction of the invention which comprises a polyimide layer.
摘要翻译：液晶显示器中的角度增强层，其显示器包括液晶单元，其中所述角度增强层包括负的双折射聚酰亚胺层，所述负双折射聚酰亚胺层包含多个具有芴基侧基的结构单元，所述角度增强层设置在至少一个所述液晶单元的表面。液晶显示器可以包括本发明的角度增强结构，其包括聚酰亚胺层。

7. 发明授权

US5858274A Treating agent for liquid crystal alignment 失效
标题翻译：液晶对准处理剂
公开(公告)号：US5858274A
公开(公告)日：1999-01-12
申请号：US875929
申请日：1997-08-13
申请人： Makoto Mishina , Terumi Sato , Kiyoshi Sawahata , Atsuko Tanaka , Hiroyoshi Fukuro
发明人： Makoto Mishina , Terumi Sato , Kiyoshi Sawahata , Atsuko Tanaka , Hiroyoshi Fukuro
IPC分类号： C08L79/04 , C08L79/08 , G02F1/1337 , C09K19/38 , C09K19/56
CPC分类号： G02F1/133723 , Y10T428/10 , Y10T428/1027
摘要： A treating agent for liquid crystal alignment useful for formation of a liquid crystal alignment film obtained by coating a film on a substrate equipped with transparent electrodes, baking the film, and subjecting the film surface to a rubbing treatment, wherein the treating agent for liquid crystal alignment contains a polyimide precursor containing a repeating unit of the formula (I) and a solvent-soluble polyimide resin containing a repeating unit of the formula (II), and at least 1 mol % of R.sub.4 of the solvent-soluble polyimide resin of the formula (II) being a bivalent organic group constituting a diamine which has a long-chain alkyl group or fluorine-containing alkyl group with a carbon number of at least 6, and the solvent-soluble polyimide resin of the formula (II) being from 1 to 80% by weight based on the total polymer weight: ##STR1## (wherein each of R.sub.1 and R.sub.2 is a tetravalent organic group which constitutes tetracarboxylic acid or its derivative, each of R.sub.2 and R.sub.4 is a bivalent organic group which constitutes a diamine, and m and k are positive integers).
摘要翻译： PCT No.PCT / JP96 / 00283 Sec。 371日期1997年8月13日 102（e）日期1997年8月13日PCT 1996年2月9日PCT公布。 WO96 / 25688 PCT出版物日期：1996年8月22日用于形成液晶取向膜的液晶取向处理剂，其通过在配备有透明电极的基材上涂布膜，烘烤该膜，并对该膜表面进行摩擦处理而获得，其中用于液晶取向的处理剂包含含有式（I）的重复单元的聚酰亚胺前体和含有式（II）的重复单元的溶剂可溶性聚酰亚胺树脂和至少1mol％的溶剂 - 式（II）的可溶性聚酰亚胺树脂是构成具有碳原子数至少为6的长链烷基或含氟烷基的二胺的二价有机基团，溶剂可溶性聚酰亚胺树脂为式（II）占总聚合物重量的1至80重量％：其中R 1和R 2各自是构成四羧酸的四价有机基团或其衍生物 R 2和R 4各自是构成二胺的二价有机基团，m和k是正整数）。

8. 发明授权

US5858273A Liquid crystal device 失效
标题翻译：液晶装置
公开(公告)号：US5858273A
公开(公告)日：1999-01-12
申请号：US684864
申请日：1996-07-25
申请人： Masanobu Asaoka , Yasuaki Takeda , Yukio Hanyu , Ikuo Nakazawa , Nobuhiro Ito , Yasufumi Asao , Takashi Moriyama
发明人： Masanobu Asaoka , Yasuaki Takeda , Yukio Hanyu , Ikuo Nakazawa , Nobuhiro Ito , Yasufumi Asao , Takashi Moriyama
IPC分类号： C09K19/04 , C09K19/34 , C09K19/56 , C09K19/02 , C09K19/52 , G02F1/1337
CPC分类号： C09K19/04 , C09K19/34 , Y10T428/1027
摘要： A liquid crystal device is constituted by a pair of transparent substrates each having thereon a transparent electrode, and a chiral smectic liquid crystal composition disposed between the substrates so as to assume at least two optically stable states. At least one of the substrates is provided with an alignment film which comprises a polyimide represented by a recurring unit of formula (I) shown below and has been subjected to a uniaxial aligning treatment. ##STR1## wherein A denotes a planar tetravalent organic residue group comprising an aromatic ring, an aromatic polycyclic ring, a heterocyclic ring or a condensed polycyclic ring, and B denotes a divalent aliphatic group comprising .paren open-st.CH.sub.2 .paren close-st..sub.n (n: an integer of at least 1) or an alicyclic ring. The chiral smectic liquid crystal composition may contain at least one species of fluorine-containing mesomorphic compound comprising a fluorocarbon terminal portion and a hydrocarbon terminal portion connected with a central core and having a smectic phase or a latent smectic phase.
摘要翻译：液晶装置由一对透明基板构成，每个透明基板上具有透明电极，并且手性近晶液晶组合物设置在基板之间以便呈现至少两个光学稳定状态。至少一个基板设置有取向膜，该取向膜包含由下述式（I）的重复单元表示的聚酰亚胺，并进行单轴对准处理。式（I）：其中A表示包括芳香环，芳族多环，杂环或稠合多环的平面四价有机残基，B表示包含+545CH 2 + 546 + E，ovs n + EE（n：至少为1的整数）或脂环族环。手性近晶液晶组合物可以含有至少一种含氟介晶化合物，其含氟碳末端部分和与中心核心连接并具有近晶相或潜层晶相的烃末端部分。

9. 发明授权

US5674575A Liquid crystal aligning film and liquid crystal display device using it 失效
标题翻译：液晶取向膜和液晶显示装置使用它
公开(公告)号：US5674575A
公开(公告)日：1997-10-07
申请号：US423728
申请日：1995-04-18
申请人： Yukino Abe , Shizuo Murata
发明人： Yukino Abe , Shizuo Murata
IPC分类号： C08G73/10 , C08J5/18 , G02F1/1337 , C09K19/00
CPC分类号： C08J5/18 , C08G73/105 , G02F1/133723 , C08J2379/08 , Y10T428/1018 , Y10T428/1027 , Y10T428/31721
摘要： The present invention provides a liquid crystal aligning film containing as the principal constituent a polyimide resin, which comprises two or more diamines, and having a stripping load of 4.0 gf or more measured by particular conditions, and a liquid crystal display device using it. The liquid crystal aligning film has excellent resistance to liquid crystals, and does not have partial disorder of liquid crystal alignment caused by many scratches made by rubbing treatment.
摘要翻译：本发明提供一种液晶取向膜以及使用该液晶取向膜的液晶显示装置，所述液晶取向膜包含两种或更多种二胺，并且通过特定条件测定剥离负载为4.0gf以上的聚酰亚胺树脂。液晶取向膜对液晶具有优异的耐性，并且由于通过摩擦处理造成的许多划痕而不会产生部分液晶取向紊乱。

10. 发明授权

US5552193A Liquid crystal device 失效
标题翻译：液晶装置
公开(公告)号：US5552193A
公开(公告)日：1996-09-03
申请号：US399043
申请日：1995-03-06
申请人： Masanobu Asaoka , Hideaki Takao , Takeshi Togano , Makoto Kojima
发明人： Masanobu Asaoka , Hideaki Takao , Takeshi Togano , Makoto Kojima
IPC分类号： G02F1/1337
CPC分类号： G02F1/133723 , Y10T428/1018 , Y10T428/1023 , Y10T428/1027
摘要： A liquid crystal device is constituted by disposing a liquid crystal between a pair of substrates; at least one of which has thereon an alignment film comprising a polymer selected from Polymers (I)-(III) below:Polymer (I), which is a polymer composite comprising at least two polymer components including a polyamide represented by a structural unit of the following formula (1): ##STR1## wherein R.sub.11 and R.sub.12 independently denote an alkyl group having 1-10 carbon atoms or a fluoroalkyl group having 1-10 carbon atoms;Polymer (II) which is a composite polyamide having at least two species of dicarboxylic acid-originated units each represented by formula (2) below: ##STR2## wherein R.sub.21 denotes a divalent organic residue group including an aromatic ring; and a diamine-originated unit represented by formula (3) below: ##STR3## wherein R.sub.22 and R.sub.23 independently denote an alkyl group having 1-10 carbon atoms, with the proviso that at least one species of the dicarboxylic acid originated units is one having a straight molecular structure; andPolymer (III) which is a polyamide composite comprising at least two polyamides formed from an aromatic ring-containing acid component and a diamine component represented by formula (4) below: ##STR4## wherein R.sub.41 and R.sub.42 independently denote an alkyl group having 1-10 carbon atoms.
摘要翻译：液晶装置通过在一对基板之间设置液晶而构成; 其中至少一个具有取向膜，该取向膜包含选自以下的聚合物（I） - （III）的聚合物：聚合物（I），其为包含至少两种聚合物组分的聚合物复合物，所述聚合物组分包括由以下结构单元下式（1）：其中R11和R12独立地表示具有1-10个碳原子的烷基或具有1-10个碳原子的氟代烷基; 聚合物（II），其为具有由下式（2）表示的至少两种二羧酸起始单元的复合聚酰胺：其中R 21表示包含芳环的二价有机残基; 和由下式（3）表示的二胺起始单元：y表示具有1-10个碳原子的烷基，条件是至少一种二羧酸起始单元是具有直链分子结构的单元; 和聚合物（III），其是包含至少两种由含芳环的酸组分形成的聚酰胺和由下式（4）表示的二胺组分的聚酰胺复合物：其中R41和R42独立地表示烷基具有1-10个碳原子的基团。

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