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    • 9. 发明授权
    • Cellulose acetate butyrate gas separation membranes
    • 乙酸丁酸纤维素气体分离膜
    • US5096468A
    • 1992-03-17
    • US547549
    • 1990-06-29
    • Bhupender S. Minhas
    • Bhupender S. Minhas
    • B01D53/22B01D71/18C01C1/04
    • B01D71/18B01D53/22C01C1/0476Y02P20/52
    • High performance cellulose acetate butyrate gas separation membranes are prepared from a casting solution containing from about 10 to 30 percent polymer, 35 to 70 percent solvent, and 15 to 30 percent pore-forming agents. A film casting solution is cast onto a substantially flat support surface and a dense layer is formed on the exposed film surface. The film is gelled, washed, and dried to produce a particularly useful gas separation membrane. The cellulose acetate polymers used in this preparation have molecular weights of at least about 20,000, and have about 10 to about 45% butyryl groups, about 2 to about 35% acetyl groups, and about 0.8 to about 2 percent hydroxyl groups, by weight. The membranes may be used for separating a feed gas into a permeate fraction and a residual fraction, and are particularly useful for separating gases in the purge gas stream of ammonia plants to recover a permeate which is relatively rich in hydrogen. Cellulose acetate butyrate membranes may be used to improve the separation of ammonia plant purge gases which contain ammonia as well as hydrogen and nitrogen, especially when there is no pretreatment of the purge gas to remove ammonia gas.
    • 高性能醋酸丁酸纤维素气体分离膜由含有约10-30%聚合物,35-70%溶剂和15-30%成孔剂的流延溶液制备。 将薄膜浇铸溶液浇铸到基本平坦的支撑表面上,并且在暴露的膜表面上形成致密层。 将膜胶化,洗涤和干燥以产生特别有用的气体分离膜。 在该制备中使用的乙酸纤维素聚合物具有至少约20,000的分子量,并且具有按重量计约10至约45%的丁酰基,约2至约35%的乙酰基和约0.8至约2%的羟基。 该膜可用于将进料气体分离成渗透物馏分和残余馏分,并且特别可用于分离氨装置的吹扫气流中的气体以回收相对富含氢的渗透物。 乙酸丁酸纤维素膜可用于改善含氨和氢气和氮气的氨厂清洗气体的分离,特别是当没有预处理净化气体以除去氨气时。