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    • 3. 发明申请
    • Polyalkylenimine-derived polymer and its production process and uses
    • 聚亚烷基亚胺衍生的聚合物及其制备方法和用途
    • US20050176897A1
    • 2005-08-11
    • US11033951
    • 2005-01-12
    • Akihiko KanzakiYoshikazu FujiiShigeru YamaguchiTakahiro MiwaAkiko Hemmi
    • Akihiko KanzakiYoshikazu FujiiShigeru YamaguchiTakahiro MiwaAkiko Hemmi
    • B01F17/16B01F17/52C02F5/12C08G73/02C08G73/04C11D3/37C08L79/00
    • C08G73/0213C02F5/12C02F2103/002C11D3/3723
    • An object of the present invention is to provide a polyalkylenimine-derived polymer and its production process and uses, wherein the polyalkylenimine-derived polymer can efficiently disperse such as liquid (particularly, water-soluble) dirt and dyes and can exercise excellent performances in uses for such as detergents and water-treating agents. As a means of achieving this object, a polyalkylenimine-derived polymer according to the present invention is an addition product of a carboxyalkyl group to a polyalkylenimine chain and is in the range of 30,000 to 5,000,000 in weight-average molecular weight. In addition, a process according to the present invention for production of a polyalkylenimine-derived polymer comprises a step of causing a polyalkylenimine of 20,000 to 1,000,000 in weight-average molecular weight and an unsaturated carboxylic acid to react together wherein the reaction is carried out under conditions where its reaction concentration is in the range of from 5 weight % up to an X value (weight %) determined by the following equation: X value (weight %)=34−(ratio (mol %) of unsaturated carboxylic acid (mols) to be caused to react relative to all amino groups (mols) of polyalkylenimine chain)/5.
    • 本发明的目的是提供一种聚亚烷基亚胺衍生的聚合物及其制备方法和用途,其中聚亚烷基亚胺衍生的聚合物可以有效地分散如液体(特别是水溶性)污垢和染料,并且可以在使用中起到优异的性能 例如洗涤剂和水处理剂。 作为实现该目的的手段,根据本发明的聚亚烷基亚胺衍生的聚合物是羧基烷基与聚亚烷基亚胺链的加成产物,其重均分子量在30,000至5,000,000的范围内。 此外,根据本发明的用于制备聚亚烷基亚胺衍生的聚合物的方法包括使重均分子量为20,000至1,000,000的聚亚烷基亚胺和不饱和羧酸反应的步骤,其中反应在 其反应浓度在5重量%至X值(重量%)范围内的条件,其由下式确定:<?in-line-formula description =“In-line formula”end =“lead”? >相对于聚亚烷基亚胺链的所有氨基(摩尔),X值(重量%)= 34-(不饱和羧酸(摩尔)的比例(摩尔%))与5反应。 <?in-line-formula description =“In-line Formulas”end =“tail”?>