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    • 4. 发明申请
    • CATALYST SYSTEM FOR PRODUCING AROMATIC AMINES
    • US20220161237A1
    • 2022-05-26
    • US17602887
    • 2020-04-01
    • BASF SE
    • Veronika WLOKADominik GARELLAMichael REISERThomas HEIDEMANNHendrik DE WINNE
    • B01J23/72B01J27/224B01J37/02B01J37/08B01J8/24C07C209/36
    • The invention relates to a catalyst system suitable for hydrogenating aromatic nitro compounds (I) to form the corresponding aromatic amines (II), the catalyst system containing, as essential constituents: a component A selected from the group consisting of silicon carbide, corundum (alpha-Al2O3) and slightly porous to non-porous zirconium oxide (ZrO2); and a component B, containing B1—a carrier substance selected from the group consisting of silicon dioxide, gamma-, delta- or theta-aluminum oxide Al2O3, titanium dioxide, zirconium dioxide and graphite, B2—a metal or a plurality of metals selected from the group consisting of copper, nickel, palladium, platinum and cobalt, and optionally B3—an additional metal selected from the group consisting of at least one metal selected from main group I, main group II, main group IV and sub-groups II, V, VI and VIII of the periodic table of the elements, the proportion of component A being in the range of 5 to 60 wt %, in relation to the total weight of the catalyst system, and the aromatic nitro compounds (I) being those of the general formula R—(NO2)n, (I), and the aromatic amines (II) being those of the general formula R—(NH2)n, (II), and the moieties R and indices n in formulas (I) and (II) having the following meaning: R is a substituted or unsubstituted aromatic C6-C10 moiety and n is an integer from 1 to 5.