会员体验
专利管家(专利管理)
工作空间(专利管理)
风险监控(情报监控)
数据分析(专利分析)
侵权分析(诉讼无效)
联系我们
交流群
官方交流:
QQ群: 891211   
微信请扫码    >>>
现在联系顾问~
热词
    • 4. 发明授权
    • Process for producing hypo-phosphorous acid (H.sub.3 PO.sub.2) and
non-transition metal hypophosphites
    • 生产次磷酸(H3PO2)和非过渡金属次磷酸盐的方法
    • US4374816A
    • 1983-02-22
    • US207306
    • 1980-11-17
    • Gregory G. ArzoumanidisKirk V. Darragh
    • Gregory G. ArzoumanidisKirk V. Darragh
    • C01B25/165C01B25/12C01B15/16C01B25/16
    • C01B25/165
    • A process for producing hypophosphorous acid (H.sub.3 PO.sub.2) by reacting, in the absence of a catalyst and under an acidic condition, phosphine with an aqueous solution of hydrogen peroxide to produce an acid solution. The acid solution is then contacted with an non-transition metal hydroxide, oxide or carbonate, e.g. sodium hydroxide, to produce a product composition containing a hypophosphite, e.g. sodium hypophosphite (NaH.sub.2 PO.sub.2.H.sub.2 O). The process of this invention finds particular utility in processes of the type wherein phosphorus is reacted with an aqueous non-transition metal hydroxide composition, e.g. an aqueous suspension of a sodium hydroxide and calcium hydroxide, to produce a hypophosphite and byproduct phosphine. The process of this invention converts a substantial portion of the byproduct phosphine to hypophosphite.
    • 在不存在催化剂的情况下,在酸性条件下使磷化氢与过氧化氢水溶液反应,生成次磷酸(H 3 PO 2)的方法,生成酸溶液。 然后将酸溶液与非过渡金属氢氧化物,氧化物或碳酸盐例如, 氢氧化钠,以产生含有次磷酸盐的产物组合物,例如 次磷酸钠(NaH2PO2·H2O)。 本发明的方法在其中磷与非过渡金属氢氧化物水溶液组合物反应的方法中具有特别的用途。 氢氧化钠和氢氧化钙的水悬浮液,以产生次磷酸盐和副产物膦。 本发明的方法将大部分副产物膦转化为次磷酸盐。