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    • 5. 发明授权
    • Method for converting UO3 or U3O8 into hydrated UO4
    • 将UO3或U3O8转化为水合UO4的方法
    • US09045350B2
    • 2015-06-02
    • US13995277
    • 2011-12-16
    • Bertrand MorelDavid AmaraggiMehdi ArabRudy ThomasMurielle RivenetFrancis Abraham
    • Bertrand MorelDavid AmaraggiMehdi ArabRudy ThomasMurielle RivenetFrancis Abraham
    • C01G43/01C01B15/047C01G43/06
    • C01G43/01C01B15/0475C01G43/06C01P2002/72C01P2004/03C01P2004/10C01P2004/54C01P2006/12
    • A method for converting UO3 and/or U3O8 into hydrated UO4 of formula UO4.nH2O wherein n is 2 or 4, comprising the following successive steps: a) preparing an aqueous suspension of a UO3 powder and/or a U3O8 powder; b) adding hydrogen peroxide H2O2 to the aqueous suspension of a UO3 and/or U3O8 powder, converting the UO3 and/or U3O8 into hydrated UO4 and precipitating, crystallizing the hydrated UO4 in the suspension; c) recovering the precipitate, crystals of UO4 hydrate; d) optionally, washing the recovered UO4 hydrate precipitate, crystal(s); e) optionally, repeating step d); f) optionally, drying the precipitate, the crystals; wherein the addition of H2O2 to the aqueous suspension is carried out so that the suspension contains a stoichiometric excess of H2O2 relatively to the stoichiometry of the reaction from UO3: UO3+nH2O+H2O2→UO4.nH2O+H2O  (1) or of the reaction from U3O8 UO2.67+1.33H2O2+nH2O→UO4.nH2O+1.33H2O  (2), and the pH of the suspension is maintained in steps a) and b) at a value comprised between 2 and 3.
    • 将UO 3和/或U 3 O 8转化为式UO·4H 2 O的水合UO 4的方法,其中n为2或4,包括以下连续步骤:a)制备UO 3粉末和/或U 3 O 8粉末的水性悬浮液; b)向UO 3和/或U 3 O 8粉末的水性悬浮液中加入过氧化氢H 2 O 2,将UO 3和/或U 3 O 8转化为水合UO 4并沉淀,使悬浮液中的水合UO4结晶; c)回收沉淀物,UO4水合物晶体; d)任选地,洗涤回收的UO4水合物沉淀物,晶体; e)任选地,重复步骤d); f)任选地,干燥沉淀物,晶体; 其中向含水悬浮液中加入H 2 O 2使得悬浮液相对于来自UO 3 :OO 3 + nH 2 O + H 2 O 2→UO 4·n H 2 O + H 2 O(1)或反应的反应的化学计量比含有化学计量过量的H 2 O 2 从U3O8 UO2.67 + 1.33H2O2 + nH2O→UO4·nH2O + 1.33H2O(2),并且悬浮液的pH在步骤a)和b)中保持在2和3之间的值。
    • 6. 发明申请
    • INTERNAL CYCLONE FOR FLUIDIZED BED REACTOR
    • 流化床反应器内循环
    • US20140065049A1
    • 2014-03-06
    • US13975817
    • 2013-08-26
    • Honeywell International Inc.
    • Terris YangRobert JohnsonHsueh Sung Tung
    • B01J8/24C01G43/06
    • B01J8/24B01J8/0055B01J8/1827B01J2208/00681B01J2208/00752B01J2208/00761C01G43/06F23C10/08
    • A fluidized bed reactor comprising a reaction column having a fluid portion; a gas inflow means for flowing a gas upwardly from the fluid portion of the reaction column; a particle feed means for feeding particles to the fluid portion of the reaction column; a cyclone capable of separating particles from the gas flowing upwardly from the fluid portion of the reaction column, the cyclone being located within the reaction column and being in communication with the gas flowing upwardly, wherein the cyclone comprises a cyclone body having an inlet, a gas outlet, and a particle drop port; and a particle discharge pipe having an upper part connected to the particle drop port of the cyclone body, and a lower part, wherein the particle discharge pipe is located substantially outside of the reaction column.
    • 一种流化床反应器,包括具有流体部分的反应塔; 用于使气体从反应塔的流体部分向上流动的气体流入装置; 用于将颗粒供给到反应塔的流体部分的颗粒进料装置; 旋风分离器,其能够从从反应塔的流体部分向上流动的气体分离颗粒,旋风分离器位于反应塔内并与向上流动的气体连通,其中旋风分离器包括具有入口的旋风体, 气体出口和颗粒滴入口; 以及具有与旋风主体的粒子滴入口连接的上部的粒子排出管,以及下部,其中,所述排出管基本位于所述反应塔的外侧。
    • 9. 发明授权
    • Apparatus and method for processing a sublimed material
    • 用于处理升华材料的装置和方法
    • US6023944A
    • 2000-02-15
    • US147776
    • 1999-02-26
    • Neil Blundell
    • Neil Blundell
    • G21C19/44B01D7/02C01G43/06C22B9/02C22B60/02F25J1/00F25J3/00
    • B01D7/02C22B60/0286
    • Apparatus for the solidification by desublimation of a sublimed gaseous substance and the subsequent trapping and liquidation of the desublimed substance is described. The apparatus comprises: means for the supply of a coolant fluid to a process vessel means; means for the supply of the sublimed substance to the vessel; means for enabling the direct contact and mixing of the coolant fluid with the sublimed substance so as to reduce the temperature of the sublimed substance to below a dewpoint thereof; the vessel means including heating means at least about the tank portion; valve means to enable the vessel means to be sealed to allow a raised pressure to be established in the vessel; conduit means having a first end at the position adjacent a lower end of the tank portion such as to be immersed in liquid resulting from the liquefaction of the desublimed substance, and a second end remote from the first end outside the vessel and connected to means to receive the liquefied substance; and the conduit means having means to permit the controlled expulsion of the liquefied substance.
    • PCT No.PCT / GB97 / 02181 Sec。 371日期1999年2月26日 102(e)1999年2月26日PCT PCT 1997年8月14日PCT公布。 公开号WO98 / 08994 日期1998年3月5日描述了通过叙述升华的气态物质凝固的装置以及随后的遗留物质的捕获和清除。 该装置包括:用于向处理容器装置供应冷却剂流体的装置; 将升华物质供应给船只的手段; 用于使冷却剂流体与升华物质直接接触和混合的装置,以将升华物质的温度降低到其露点以下; 所述容器装置包括至少围绕所述罐部分的加热装置; 阀装置,以使容器装置能够被密封,以允许在容器中建立升高的压力; 导管装置具有在与罐部分的下端相邻的位置处的第一端,以便浸没在由所述静止物质液化而导致的液体中;以及远离容器外部的第一端的第二端, 接收液化物质; 并且管道装置具有允许液化物质受控排出的装置。