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1. 发明授权

US11639322B2 Sulfuric acid catalyzed alkylation process 有权
公开(公告)号：US11639322B2
公开(公告)日：2023-05-02
申请号：US17470034
申请日：2021-09-09
申请人： UOP LLC
发明人： Christopher P. Nicholas , Susie C. Martins , David E. Mackowiak , Hayim Abrevaya , Joel T. Walenga
IPC分类号： C07C2/62
摘要： A process for sulfuric acid catalyzed alkylation involving the use of surfactants which form bi-continuous micro-emulsions with the sulfuric acid and the hydrocarbon is described. The bi-continuous phase facilitates and improves the sulfuric acid catalyzed alkylation reactions. The concentration of the surfactant is selected based on the type of olefin feed. Easy to alkylate feeds, such as 2-butene, use lower concentrations of surfactant, while feeds which are harder to alkylate, such as propene or isobutene, use higher concentrations of the surfactant. In addition, increasing the concentration of sulfuric acid when a surfactant is included resulted in higher calculated RON. The use of a surfactant and a high concentration of sulfuric acid can provide a calculated RON over 100 and close to theoretical yields.

2. 发明授权

US11511256B2 Flexible production of gasoline and jet fuel in alkylation reactor 有权
公开(公告)号：US11511256B2
公开(公告)日：2022-11-29
申请号：US16881734
申请日：2020-05-22
申请人： LUMMUS TECHNOLOGY LLC
发明人： Zan Liu , Jackeline Medina Bolívar , Maurice Korpelshoek , Romain Lemoine , Manoj Som
IPC分类号： C07C2/62 , C07C7/00 , B01J19/00 , C10L1/06
摘要： Systems and processes for the flexible production of gasoline and jet fuel via alkylation of C4 and C5 olefins.

3. 发明授权

US11286215B2 Reverse acid and hydrocarbon cascading in alkylation 有权
公开(公告)号：US11286215B2
公开(公告)日：2022-03-29
申请号：US17097176
申请日：2020-11-13
申请人： LUMMUS TECHNOLOGY LLC
发明人： Zan Liu , Peter Loezos , Jackeline Medina , Romain Lemoine
IPC分类号： C07C2/62 , B01J19/24
摘要： A cascade reactor scheme with acid and hydrocarbon flowing in reverse directions. The systems and processes for alkylation of olefins herein may include providing a first olefin to a first alkylation zone, and a second olefin to a second alkylation zone. Isoparaffin may be provided to the first alkylation zone. The isoparaffin and first olefin may be contacted with a partially spent sulfuric acid in the first alkylation zone to form a spent acid phase and a first hydrocarbon phase including alkylate and unreacted isoparaffin. The first hydrocarbon phase and second olefin may be contacted with a sulfuric acid feed in the second alkylation zone to form a second hydrocarbon phase, also including alkylate and unreacted isoparaffin, and the partially spent sulfuric acid that is fed to the first alkylation zone. Further, the second hydrocarbon phase may be separated, recovering an isoparaffin fraction and an alkylate product fraction.

4. 发明授权

US11135575B2 Apparatus for regeneration of acidic ionic liquid without addition of a hydrogenation catalyst 有权
公开(公告)号：US11135575B2
公开(公告)日：2021-10-05
申请号：US15928690
申请日：2018-03-22
申请人： Chevron U.S.A. Inc.
发明人： Michael John Girgis , Huping Luo , Bong Kyu Chang , Hye-Kyung Cho Timken , Steven Xugi Song , Michael Sean Driver
IPC分类号： C07C2/58 , B01J31/40 , B01J31/02 , B01J38/10 , C07C2/62 , C10L1/06 , C10G29/20 , C10G45/60 , C10G47/02 , C10G50/00 , B01J35/12 , C07C2/56
摘要： We provide a process for regenerating a spent acidic ionic liquid, comprising contacting the spent acidic ionic liquid with hydrogen and without an addition of a hydrogenation catalyst; wherein a conjunct polymer content is decreased in the spent acidic ionic liquid to produce regenerated acidic ionic liquid. We also provide a process for making an alkylate gasoline blending component, comprising: a) alkylating a mixture of isoparaffins and olefins using an acidic ionic liquid and an alkyl halide or a hydrogen halide, wherein a conjunct polymer accumulates in a spent acidic ionic liquid; and b) feeding the spent acidic ionic liquid and a hydrogen, and without an addition of a hydrogenation catalyst, to a regeneration reactor operated under selected hydrogenation conditions to produce a regenerated acidic ionic liquid that is used for the alkylating, wherein the conjunct polymer in the regenerated acidic ionic liquid is decreased by at least 50 wt %.

5. 发明申请

US20210061731A1 REVERSE ACID AND HYDROCARBON CASCADING IN ALKYLATION 有权
公开(公告)号：US20210061731A1
公开(公告)日：2021-03-04
申请号：US17097176
申请日：2020-11-13
申请人： LUMMUS TECHNOLOGY LLC
发明人： Zan Liu , Peter Loezos , Jackeline Medina , Romain Lemoine
IPC分类号： C07C2/62
摘要： A cascade reactor scheme with acid and hydrocarbon flowing in reverse directions. The systems and processes for alkylation of olefins herein may include providing a first olefin to a first alkylation zone, and a second olefin to a second alkylation zone. Isoparaffin may be provided to the first alkylation zone. The isoparaffin and first olefin may be contacted with a partially spent sulfuric acid in the first alkylation zone to form a spent acid phase and a first hydrocarbon phase including alkylate and unreacted isoparaffin. The first hydrocarbon phase and second olefin may be contacted with a sulfuric acid feed in the second alkylation zone to form a second hydrocarbon phase, also including alkylate and unreacted isoparaffin, and the partially spent sulfuric acid that is fed to the first alkylation zone. Further, the second hydrocarbon phase may be separated, recovering an isoparaffin fraction and an alkylate product fraction.

6. 发明授权

US10384990B2 Method for producing 1,3-butadiene by dehydrogenating n-butenes, a material flow containing butanes and 2-butenes being provided 有权
公开(公告)号：US10384990B2
公开(公告)日：2019-08-20
申请号：US15525330
申请日：2015-11-09
申请人： BASF SE , Linde AG
发明人： Jan Ungelenk , Philipp Grüne , Christian Walsdorff , Jan Pablo Josch , Michael Bender
IPC分类号： C07C5/48 , C07C2/10 , C07C2/62 , C07C6/04 , C07C7/08 , C07C7/11 , C07C2/06 , C07C2/56 , C07C9/16 , C07C11/06 , C07C11/167
摘要： The invention relates to a process for preparing 1,3-butadiene from n-butenes, comprising the steps of: A) providing an input gas stream a comprising butanes, 1-butene, 2-butene and isobutene, with or without 1,3-butadiene, from a fluid catalytic cracking plant; B) removing isobutene from the input gas stream a, giving a stream b comprising butanes, 1-butene and 2-butene, with or without 1,3-butadiene; C) feeding the stream b comprising butanes, 1-butene and 2-butene and optionally an, oxygenous gas and optionally water vapor into at least one dehydrogenating zone and dehydrogenating 1-butene and 2-butene to 1,3-butadiene, giving a product gas stream c comprising 1,3-butadiene, butanes, 2-butene and water vapor, with or without oxygen, with low-boiling hydrocarbons, with high-boiling secondary components, with or without carbon oxides and with or without inert gases; D) cooling and compressing the product gas stream c, giving at least one aqueous condensate stream d1 and a gas stream d2 comprising 1,3-butadiene, butanes, 2-butene and water vapor, with or without oxygen, with low-boiling hydrocarbons, with or without carbon oxides and with or without inert gases; Ea) removing uncondensable and low-boiling gas constituents comprising low-boiling hydrocarbons, with or without oxygen, with or without carbon oxides and with or without inert gases, as gas stream e2 from the gas stream d2 by absorbing the C4 hydrocarbons comprising 1,3-butadiene, butanes and 2-butene in an absorbent, giving an absorbent stream laden with C4 hydrocarbons and the gas stream e2, and Eb) subsequently desorbing the C4 hydrocarbons from the laden absorbent stream, giving a C4 hydrocarbon stream e1; F) separating the C4 hydrocarbon stream e1 by extractive distillation with a 1,3-butadiene-selective solvent into a stream f1 comprising 1,3-butadiene and the selective solvent and a stream f2 comprising butanes and 2-butene, wherein at least 90% of the 1-butene present in stream b is converted in step C) and a product stream f2 comprising butanes and 2-butene is obtained in step F.

7. 发明授权

US10294173B2 Integration of a dehydrogenation unit and an alkylation unit 有权
公开(公告)号：US10294173B2
公开(公告)日：2019-05-21
申请号：US15994996
申请日：2018-05-31
申请人： UOP LLC
发明人： Charles P. Luebke , Raul Zavala , Christopher D. DiGiulio
IPC分类号： C07C2/62 , C07C2/60 , C07C5/27 , C07C5/05 , C07C9/16 , C07C5/52
摘要： The present invention relates to the integration of an alkylation unit for use in a hydrocarbon conversion process. More specifically, the present invention relates to the integration of a dehydrogenation unit and an alkylation unit and the placement of different isomerization units located off the deisobutanizer and the debutanizer.

8. 发明授权

US10252956B2 Viscosity modifiers for decreasing the viscosity of ionic liquids 有权
公开(公告)号：US10252956B2
公开(公告)日：2019-04-09
申请号：US16035851
申请日：2018-07-16
申请人： UOP LLC
发明人： Avram M. Buchbinder , Erin M. Broderick , Susie C. Martins , Alakananda Bhattacharyya , Stuart Smith
IPC分类号： C07C2/58 , C07C2/62 , C07C2/60 , B01J31/02
摘要： A process utilizing an ionic liquid is described. The process includes contacting a hydrocarbon feed with an ionic liquid component, the ionic liquid component comprising a mixture of a first ionic liquid and a viscosity modifier, wherein a viscosity of the ionic liquid component is at least about 10% less than a viscosity of the first ionic liquid.

9. 发明申请

US20180327333A1 Optimizing An Alkylation Olefins Source 审中-公开
公开(公告)号：US20180327333A1
公开(公告)日：2018-11-15
申请号：US16041494
申请日：2018-07-20
申请人： ExxonMobil Chemical Patents Inc.
发明人： Ipokratis Polizopoulos , Ezra J. Czuba , Brian C. Mayo
IPC分类号： C07C2/58 , G06Q30/02 , B01J19/24 , C10G29/20 , C07C2/62 , C07C9/16
CPC分类号： C07C2/58 , B01J19/245 , B01J2219/00002 , B01J2219/00049 , B01J2219/24 , C07C2/62 , C10G29/205 , C10G2300/1081 , C10G2300/1092 , C10G2300/201 , G06Q30/0206 , C07C9/16
摘要： Alkylate is produced by supplying iso-C4+ hydrocarbon feed to an alkylation reactor, and by further selectively supplying to the alkylation reactor an olefin selected from the group consisting of refinery grade propylene (RGP) and polymer grade propylene (PGP), and combinations thereof. The olefin feed is controlled such that the proportion of PGP supplied through the olefin feed inlet exceeds that of RGP for a predetermined time interval, using a special purpose computer programmed to optimize the allocation of PGP between alkylation production and a commodity market in order to increase total net profit margin.

10. 发明授权

US10093594B2 High viscosity index lubricants by isoalkane alkylation 有权
公开(公告)号：US10093594B2
公开(公告)日：2018-10-09
申请号：US15159205
申请日：2016-05-19
申请人： Chevron U.S.A. Inc.
发明人： Sven Ivar Hommeltoft
IPC分类号： C07C2/62 , C10M105/04
摘要： An isoalkane alkylate base oil and a process to make an isoalkane alkylate base oil having a VI higher than 90, comprising: a. selecting an isoalkane feed containing at least one isoalkane and an olefin feed containing at least one linear olefin such that a combined carbon number of the isoalkane feed and the olefin feed is from 20 to 60; and b. alkylating the isoalkane feed with the olefin feed in the presence of an acidic alkylation catalyst under alkylation conditions to make the isoalkane alkylate base oil having the VI higher than 90; wherein the isoalkane alkylate base oil has a kinematic viscosity at 100° C. from 2 to 30 mm2/s, a pour point less than 0° C., and a bromine index less than 2000 mg Br/100 g.

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