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    • 9. 发明申请
    • METHODS FOR CONVERSION OF A GLYCOL REACTION PRODUCT OBTAINED FROM HYDROTHERMAL DIGESTION OF CELLULOSIC BIOMASS SOLIDS INTO A DRIED MONOHYDRIC ALCOHOL FEED
    • 将从细胞生物质固体的氢热消解中获得的甘油反应产物转化成干燥的单糖原料的方法
    • US20140128639A1
    • 2014-05-08
    • US14067399
    • 2013-10-30
    • SHELL OIL COMPANY
    • Joseph Broun POWELLKimberly Ann JOHNSON
    • C07C31/02
    • C07C31/02C07C29/132C07C29/60C10G3/42C10G3/50C10G3/56C10G2300/1011C10G2300/1014C10G2400/02C10G2400/04Y02P30/20C07C31/205C07C31/202C07C31/10
    • Hydrothermal digestion of cellulosic biomass solids may produce a glycol reaction product for subsequent processing. Methods for digesting cellulosic biomass solids to form and process a glycol reaction product may comprise: providing cellulosic biomass solids and a slurry catalyst in a hydrothermal digestion unit, the slurry catalyst being capable of activating molecular hydrogen; heating the cellulosic biomass solids in the hydrothermal digestion unit in the presence of the slurry catalyst, a digestion solvent, and molecular hydrogen, thereby forming a liquor phase comprising soluble carbohydrates; performing a first catalytic reduction reaction on the soluble carbohydrates within the hydrothermal digestion unit, thereby at least partially converting the soluble carbohydrates into a reaction product comprising a glycol; at least partially drying the reaction product, thereby forming a dried reaction product comprising a dried glycol; and at least partially converting the dried glycol into a monohydric alcohol external to the hydrothermal digestion unit.
    • 纤维素生物质固体的水热消解可以产生用于后续加工的二醇反应产物。 用于消化纤维素生物质固体以形成和加工二醇反应产物的方法可以包括:在水热消解单元中提供纤维素生物质固体和浆料催化剂,所述浆料催化剂能够活化分子氢; 在浆液催化剂,消解溶剂和分子氢的存在下,加热水热消解装置中的纤维素生物质固体,从而形成包含可溶性碳水化合物的液相; 对水热消解单元内的可溶性碳水化合物进行第一催化还原反应,从而至少部分地将可溶性碳水化合物转化成包含二醇的反应产物; 至少部分地干燥反应产物,从而形成包含干燥的二醇的干燥反应产物; 并且至少部分地将干燥的二醇转化成水热消解单元外部的一元醇。