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1. 发明授权

US06149836A Liquid solutions of dicarboxylic acids 失效
标题翻译：二羧酸液体溶液
公开(公告)号：US06149836A
公开(公告)日：2000-11-21
申请号：US724505
申请日：1996-09-30
申请人： Salih Mumcu , Franz-Erich Baumann
发明人： Salih Mumcu , Franz-Erich Baumann
IPC分类号： C07B63/04 , C07C51/50 , C07C55/02 , C07C55/14 , C07C55/16 , C07C55/18 , C07C55/20 , C07C55/21 , C07C63/24 , C07C63/26 , C07C63/333 , C07C63/38 , C08G69/04 , C08G69/36 , C09K3/00
CPC分类号： C08G69/36 , C07C51/50
摘要： Liquid melts of dicarboxylic acid have a tendency to undergo unwanted discoloration on prolonged storage. By means of a solution of the dicarboxylic acids in a lactam of an aliphatic .alpha.,.omega.-aminocarboxylic acid, the discoloration can be avoided.
摘要翻译：二羧酸的液体熔融物在长期储存时具有不希望的变色的倾向。通过二羧酸在脂族α，ω-氨基羧酸的内酰胺中的溶液，可以避免变色。

2. 发明授权

US5319134A Process for introducing a carboxyl group to an aromatic carboxylic acid or a derivative thereof 失效
标题翻译：将羧基引入芳族羧酸或其衍生物的方法
公开(公告)号：US5319134A
公开(公告)日：1994-06-07
申请号：US966448
申请日：1992-10-26
申请人： Hidefumi Hirai , Rikinori Terakado , Hisashi Mihori , Tsutomu Nakamura , Kazuhiro Saito
发明人： Hidefumi Hirai , Rikinori Terakado , Hisashi Mihori , Tsutomu Nakamura , Kazuhiro Saito
IPC分类号： B01J23/72 , B01J23/825 , B01J23/835 , B01J23/84 , B01J27/053 , B01J31/04 , C07B61/00 , C07C51/00 , C07C51/093 , C07C63/15 , C07C63/333 , C07C63/38 , C07C67/313 , C07C69/76 , C07C227/02 , C07C229/52 , C07C245/08 , C07C317/44 , C07C323/62
CPC分类号： C07C51/00
摘要： Disclosed is a process for introducing a carboxyl group to an aromatic carboxylic acid or a derivative thereof, which comprises reacting a starting aromatic carboxylic acid, such as a benzoic acid, a biphenylcarboxylic acid, a naphthalenecarboxylic acid, a diphenylcarboxylic acid, or a derivative thereof, with a carbon tetrahalide in the presence of a cyclodextrin and an alkali metal hydroxide, thereby introducing a carboxyl group to the aromatic ring of the starting aromatic carboxylic acid or the derivative thereof in substitution for a hydrogen atom bonded thereto. By the process of the present invention, a desired aromatic polycarboxylic acid or a derivative thereof can be easily obtained with high selectivity.
摘要翻译：公开了将羧基引入到芳族羧酸或其衍生物中的方法，其包括使起始芳族羧酸如苯甲酸，联苯羧酸，萘甲酸，二苯基羧酸或其衍生物在环糊精和碱金属氢氧化物的存在下用四卤化碳引入羧基，从而将羧基引入到起始芳族羧酸或其衍生物的芳环上，以取代键合的氢原子。通过本发明的方法，可以容易地以高选择性获得所需的芳族多元羧酸或其衍生物。

3. 发明授权

US4885384A Process for the carbonylation of iodoaromatic compounds 失效
标题翻译：碘芳香族化合物的羰基化方法
公开(公告)号：US4885384A
公开(公告)日：1989-12-05
申请号：US168050
申请日：1988-03-14
申请人： Guy R. Steinmetz , Kevin J. Edgar , Stephen N. Falling
发明人： Guy R. Steinmetz , Kevin J. Edgar , Stephen N. Falling
IPC分类号： C07C51/10 , C07C63/00 , C07C63/26 , C07C63/331 , C07C63/38 , C07C65/03 , C07C65/21
CPC分类号： C07C51/10 , Y02P20/582
摘要： A process for the production of aromatic carboxylic acids which comprises carbonylating substituted iodoaromatic compounds in the presence of carbon monoxide, a catalytic amount of a transition metal catalyst, and a Bronsted base in a mixture of a carboxylic acid and water under aromatic carboxylic acid forming conditions of temperature and pressure.
摘要翻译：一种制备芳族羧酸的方法，其包括在芳族羧酸形成条件下在一氧化碳存在下羰基化取代的碘代芳族化合物，催化量的过渡金属催化剂和Bronsted碱在羧酸和水的混合物中的温度和压力。

4. 发明授权

US4783548A Processes for preparing 3,4-dihydro 2-naphthanoic acid and 2-naphthanoic acid and esters thereof 失效
标题翻译：制备3,4-二氢-2-萘甲酸和2-萘酸的方法及其酯
公开(公告)号：US4783548A
公开(公告)日：1988-11-08
申请号：US97021
申请日：1987-09-16
申请人： Joseph R. Zoeller
发明人： Joseph R. Zoeller
IPC分类号： B01J23/44 , C07B61/00 , C07C51/347 , C07C61/13 , C07C61/29 , C07C61/39 , C07C61/40 , C07C62/06 , C07C62/14 , C07C62/34 , C07C63/38 , C07C67/30 , C07C69/757 , C07C69/76 , C07C149/40
CPC分类号： C07C62/34 , C07C61/29 , C07C61/39 , C07C61/40 , C07C63/38
摘要： A process for preparing a 3,4-dihydro 2-naphthanoic acid or an ester thereof comprises heating an alpha-vinyl cinnamic acid or a (C.sub.1 -C.sub.12)alkyl, (C.sub.6 -C.sub.12)aryl, (C.sub.6 -C.sub.12)aralkyl or (C.sub.6 -C.sub.12)alkylaryl ester thereof at a temperature effective to cyclize said acid or ester thereof and obtain the corresponding 3,4-dihydro 2-naphthanoic acid or ester thereof. The alpha-vinyl cinnamic acid or ester thereof may be obtained by contacting crotonic anhydride and a benzaldehyde substituted with halo or (C.sub.1 -C.sub.12)alkyl, acyl, acyloxy, carboxy, carbalkoxy, alkylthiol or alkoxy.A process for preparing 2-naphthanoic acid or an ester thereof comprises the above steps to prepare a 3,4-dihydro-2-naphthanoic acid, and dehydrogenating said 3,4-dihydro 2-naphthanoic acid or ester thereof to obtain the 2-naphthanoic acid.
摘要翻译：制备3,4-二氢-2-萘酸或其酯的方法包括加热α-乙烯基肉桂酸或（C 1 -C 12）烷基，（C 6 -C 12）芳基，（C 6 -C 12）芳烷基或（ C6-C12）烷基芳基酯在有效使所述酸或酯环化的温度下得到相应的3,4-二氢-2-萘酸或其酯。 α-乙烯基肉桂酸或其酯可以通过使巴豆酸酐和被卤素或（C 1 -C 12）烷基，酰基，酰氧基，羧基，烷氧基，烷基硫醇或烷氧基取代的苯甲醛接触来获得。制备2-萘酸或其酯的方法包括上述步骤制备3,4-二氢-2-萘酸，并使所述3,4-二氢-2-萘酸或其酯脱氢得到2- 萘酸。

5. 发明授权

US4011261A Process for the manufacture of 1,4-disubstituted bicyclic or tricyclic compounds and new 1,4-disubstituted bicyclic compounds 失效
标题翻译： 1,4-取代的双环或三聚化合物和新的1,4-取代双环化合物的制备方法
公开(公告)号：US4011261A
公开(公告)日：1977-03-08
申请号：US629180
申请日：1975-11-05
申请人： Leonardo Guglielmetti
发明人： Leonardo Guglielmetti
IPC分类号： C07C255/52 , C07C51/08 , C07C63/38
CPC分类号： C07C255/52 , C07C2103/24
摘要： The present invention provides a new process for the manufacture of 1,4-disubstituted bicyclic or tricyclic compounds by reacting a 1,2-bis-cyanomethyl-benzene or 2,3-bis-cyanomethyl-naphthalene with glyoxal in the presence of a base and a solvent as well as new 1,4-disubstituted bicyclic compounds.

6. 发明授权

US3916012A Purification of 2,6 and 2,7 naphthalene dicarboxylic acid 失效
标题翻译： 2,6和2,7萘二羧酸的纯化
公开(公告)号：US3916012A
公开(公告)日：1975-10-28
申请号：US13767771
申请日：1971-04-26
申请人： STANDARD OIL CO
发明人： KNOBLOCH JAMES O
IPC分类号： C07C51/487 , C07C51/42 , C07C63/38
CPC分类号： C07C51/487 , C07C63/38
摘要： Naphthalene dicarboxylic acids are purified by low concentration permanganate treatment at a pH upward from 10 and carbon treatment to remove at least manganous ions. The process is particularly useful for the purification of 2,6 and 2,7 naphthalene dicarboxylic acids that are to be converted to beta hydroxy alkyl esters from which corresponding film and fiber forming polyesters are made.
摘要翻译：萘二羧酸通过低浓度高锰酸盐处理，在10℃以上的pH下进行纯化，并进行碳处理以除去至少三价锰离子。该方法特别可用于纯化待转化成β羟基烷基酯的2,6和2,7萘二羧酸，由此制备相应的成膜和成纤的聚酯。

7. 发明授权

US3894971A Oxidation catalysts 失效
标题翻译：氧化催化剂
公开(公告)号：US3894971A
公开(公告)日：1975-07-15
申请号：US34153273
申请日：1973-03-15
申请人： BASF AG
发明人： REUTER PETER , WIRTH FRIEDRICH
IPC分类号： C07D307/60 , B01J23/22 , B01J27/198 , B01J37/02 , C07B31/00 , C07B33/00 , C07B61/00 , C07C46/04 , C07C51/00 , C07C51/25 , C07C51/265 , C07C51/31 , C07C63/38 , C07C67/00 , C07D307/89 , B01J27/14
CPC分类号： C07C51/265 , B01J23/22 , B01J27/198 , B01J37/0221 , B01J37/0228 , C07C46/04 , C07C51/252 , C07C51/313 , C07C57/145 , C07C63/16 , C07C63/313
摘要： A catalyst for the oxidation of aromatic or unsaturated aliphatic hydrocarbons which contains in the active material from 60 to 99 percent by weight of titanium dioxide and/or zirconium dioxide, from 1 to 40 percent by weight of vanadium pentoxide and up to 6 percent by weight of combined phosphorus, and which contains from 0 to 0.3 percent by weight of phosphorus in the outer layer and more than 0.3 percent up to 6 percent by weight of phosphorus in the remaining catalytic material.
摘要翻译：用于氧化芳族或不饱和脂族烃的催化剂，其在活性物质中含有60至99重量％的二氧化钛和/或二氧化锆，1至40重量％的五氧化二钒和至多6重量％的组合磷，并且其在外层中含有0至0.3重量％的磷，在剩余的催化材料中含有大于0.3重量％至6重量％的磷。

8. 发明授权

US3847977A Purification process for aromatic acids 失效
标题翻译：芳香酸的净化过程
公开(公告)号：US3847977A
公开(公告)日：1974-11-12
申请号：US26380972
申请日：1972-06-19
申请人： SUN RESEARCH DEVELOPMENT
发明人： NORTON R
IPC分类号： C07C63/04 , C07C51/00 , C07C51/48 , C07C63/14 , C07C63/33 , C07C63/34 , C07C67/00 , C07C51/42 , C07C63/36 , C07C63/38
CPC分类号： C07C51/48
摘要： 1. A PROCESS FOR PURIFICATION OF AN AROMATIC ACID CONTAINING COLOR AND NITROGEN IMPURITIES SELECTED FROM HE GROUP OF POLY ACIDS OF THE BENZENES SERIES AND MONO- AND POLY ACIDS OF THE NAPHTHALENES SERIES AND OBTAINED BY THE HYDROLYSIS OF NITRILES, WHICH COMPRISES EXTRACTING SAID IMPURE ACID WITH A THREE PHASE HETEROGENEOUS SYSTEM CONSISTING ESSENTIALLY OF AN AQUEOUS SOLUTION OF ACETIC ACID, A LIQUID AROMATIC HYDROCARBON HAVING FROM SIX TO NINE CARBON ATOMS, AND AROMATIC ACID; THE AQUEOUS ACETIC ACID SOLUTION CONTAINING FROM ABOUT 40% TO ABOUT 65% BY WEIGHT OF WATER, THE WEIGHT RATIO OF AQUEOUS EXTRACTANT SOLUTION TO AROMATIC HYDROCARBON BEING FROM ABOUT 3:75:1 TO ABOUT 20:1, FROM ABOUT 15% TO ABOUT 90% BY WEIGHT OF THE AROMATIC ACID BEING IN THE SOLID PHASE, AND SAID EXTRACTION BEING MADE TO OCCUR IN A CLOSED SYSTEM AT A TEMPERATURE OF BETWEEN ABOUT 200* AND ABOUT 250* C.

9. 发明授权

US3487106A Preparation of naphthalene-2,3-dicarboxylic acid 失效
标题翻译：萘磺酸-2,3-二羧酸的制备
公开(公告)号：US3487106A
公开(公告)日：1969-12-30
申请号：US3487106D
申请日：1965-02-08
申请人： MARATHON OIL CO
发明人： PATTON JAMES W , SON MARION O JR
IPC分类号： C07C51/15 , C07C63/38
CPC分类号： C07C51/15 , C07C63/38

10. 发明申请

US20050187403A1 Process for producing 1,3-naphthalenedicarboxylic acid 审中-公开
标题翻译： 1,3-萘二甲酸的制备方法
公开(公告)号：US20050187403A1
公开(公告)日：2005-08-25
申请号：US11063970
申请日：2005-02-24
申请人： Hiroshi Ogawa , Junya Nishiuchi , Mitsuharu Kitamura , Kinji Kato
发明人： Hiroshi Ogawa , Junya Nishiuchi , Mitsuharu Kitamura , Kinji Kato
IPC分类号： C07C51/255 , C07C51/265 , C07C63/38
CPC分类号： C07C51/265 , C07C63/38
摘要： 1,3-Naphthalenedicarboxylic acid is produced by oxidizing 1,3-dialkylnaphthalene in a liquid-phase with an oxygen-containing gas in the presence of a C2-C6 lower aliphatic carboxylic acid solvent and a catalyst comprising a heavy metal and a bromine compound. By regulating the ratio of the total number of bromine atoms fed into a reaction system to the total number of 1,3-dialkylnaphthalene molecules fed into the reaction system within a specific range, 1,3-naphthalenedicarboxylic acid is efficiently produced with low costs. Using 1,3-dimethylnaphthalene, as the starting 1,3-dialkylnaphthalene, which is produced by isomerizing dimethylnaphthalenes in a liquid phase in the presence of a catalyst comprising hydrogen fluoride and boron trifluoride together with a C5-C10 alicyclic saturated hydrocarbon having a five-membered or six-membered ring structure, a highly pure 1,3-naphthalenedicarboxylic acid is efficiently produced.
摘要翻译： 1,3-二萘基二羧酸是通过在C 2 -C 6 -C 6的存在下用含氧气体在液相中氧化1,3-二烷基萘而制备的，低级脂族羧酸溶剂和包含重金属和溴化合物的催化剂。通过调节进料到反应体系中的溴原子总量与进料到反应体系中的1,3-二烷基萘分子的总数在特定范围内的比例，可以低成本有效地制备1,3-萘二羧酸。使用1,3-二甲基萘作为起始1,3-二烷基萘，其通过在包含氟化氢和三氟化硼的催化剂存在下在液相中异构化二甲基萘一起制备，与C 5 N 5 具有5元或6元环结构的-C 10脂肪族饱和烃，高纯度的1,3-萘二羧酸。

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