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1. 发明申请

US20230079313A1 ENZYME-ASSISTED ATRP PROCEDURES 有权
公开(公告)号：US20230079313A1
公开(公告)日：2023-03-16
申请号：US17942952
申请日：2022-09-12
申请人： Carnegie Mellon University
发明人： Krzysztof Matyjaszewski , Alan Enciso Barros , Liye Fu , Alan J. Russell
IPC分类号： C08F4/10 , C08F2/16 , C08K5/1545 , C08F4/26 , C12P7/00
摘要： Materials and methods for conducting an atom transfer radical polymerization in the presence of oxygen by interlocking enzymatic activities are provided herein.

2. 发明申请

US20210047456A1 Compositions for forming polymer brushes 有权
公开(公告)号：US20210047456A1
公开(公告)日：2021-02-18
申请号：US17065750
申请日：2020-10-08
申请人： RADISURF APS
发明人： Stefan Urth Nielsen , Mikkel Skorkjaer Kongsfelt
IPC分类号： C08F293/00 , C08F4/10 , C08F4/26 , C08F292/00 , C08F2/06 , C08F2/10
摘要： The present invention relates to novel chemical solutions suitable for forming polymer brushes on a surface of a solid part. The present invention further relates to methods of forming polymer brushes on the surface of a solid part using the novel chemical solutions as well as solid parts having polymer brushes coated onto the surface and uses of such solid parts.

3. 发明申请

US20190284313A1 PROCESS FOR PREPARING HIGH-REACTIVITY ISOBUTENE HOMO- OR COPOLYMERS 审中-公开
公开(公告)号：US20190284313A1
公开(公告)日：2019-09-19
申请号：US16318749
申请日：2017-07-14
申请人： BASF SE
发明人： Rosa CORBERAN ROC , Klaus MUEHLBACH , Thomas WETTLING , Sergei V. KOSTJUK , Irina VASILENKO , Dmitryi SHIMAN , Ivan BERAZIANKA
IPC分类号： C08F10/10 , C08F4/14 , C08F4/26 , C08K5/3472 , C08K5/3445 , C08K5/353 , C08K5/19 , C08K5/50 , C08F4/18
摘要： The present invention relates to a novel process for preparing high-reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per polyisobutene chain end of at least 70 mol %. The present invention further relates to novel isobutene polymers.

4. 发明授权

US09156924B2 Polymerization initiating system and method to produce highly reactive olefin functional polymers 有权
公开(公告)号：US09156924B2
公开(公告)日：2015-10-13
申请号：US13796405
申请日：2013-03-12
申请人： University of Massachusetts , Infineum International Limited
发明人： Rudolf Faust , Jacob Emert
IPC分类号： C08F4/26 , C08F110/10
CPC分类号： C08F4/26 , C08F110/10 , C08F4/12 , C08F4/06 , C08F4/16 , C08F2500/02 , C08F2500/03
摘要： A method for producing highly reactive olefin polymers wherein at least 50 mol. % of the polymer chains have terminal double bonds, and a novel polymerization initiating system for accomplishing same.

5. 发明授权

US09156923B2 Oxidizing agent useful for oxidative polymerization of high conductive polymers 有权
标题翻译：可用于高导电聚合物氧化聚合的氧化剂
公开(公告)号：US09156923B2
公开(公告)日：2015-10-13
申请号：US12588323
申请日：2009-10-13
申请人： Li-Duan Tsai , Yi-Chang Du
发明人： Li-Duan Tsai , Yi-Chang Du
IPC分类号： A63D3/00 , C08F4/26 , C08F4/40
CPC分类号： C08F4/26 , C08F4/40
摘要： An oxidizing agent useful for oxidative polymerization of high conductive polymers is provided. This oxidizing agent is a kind of organic metal complex formed of metal ion salts having oxidizing capability and nitrogen-containing compound having lone pair electrons with partial π-electron character. This organic metal complex has weak oxidizing strength for monomers at room temperature. As such, a mixture of the organic metal complex and the monomers has long-term stability under room temperature. While, at a high temperature, the organic metal complex provides proper oxidative polymerization capability for the monomers. The conductive polymers synthesized by the organic metal complex have excellent conductivity.
摘要翻译：提供了可用于高导电聚合物的氧化聚合的氧化剂。该氧化剂是由具有氧化能力的金属离子盐和具有部分和电子特性的具有孤对电子的含氮化合物形成的一种有机金属络合物。该有机金属络合物在室温下对单体的氧化强度弱。因此，有机金属络合物和单体的混合物在室温下具有长期的稳定性。而在高温下，有机金属络合物为单体提供适当的氧化聚合能力。由有机金属络合物合成的导电聚合物具有优异的导电性。

6. 发明申请

US20130041121A1 PROCESS FOR PREPARING HIGH-REACTIVITY ISOBUTENE HOMO- OR COPOLYMERS 有权
标题翻译：制备高反应性异丁基苯酚或共聚物的方法
公开(公告)号：US20130041121A1
公开(公告)日：2013-02-14
申请号：US13568421
申请日：2012-08-07
申请人： Hannah Maria KÖNIG , Klaus Mühlbach , Thomas Wettling , Ulrich Eichenauer , Herbert Mayr
发明人： Hannah Maria KÖNIG , Klaus Mühlbach , Thomas Wettling , Ulrich Eichenauer , Herbert Mayr
IPC分类号： C08F110/10 , C08F4/14 , C08F4/26
CPC分类号： C08F110/10 , C08F10/10 , C08F4/00 , C08F4/06 , C08F2500/02 , C08F2500/03
摘要： Preparation of high-reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per polyisobutene chain end of at least 50 mol % by polymerization of isobutene or isobutene-comprising monomer mixtures in the presence of Lewis acids suitable as polymerization catalysts or of complexes which are effective as polymerization catalysts and are formed from Lewis acids and donors, and in the presence of initiators, wherein the initiators used are organic sulfonic acids Z—SO3H in which the variable Z denotes an alkyl radical, haloalkyl radical, cycloalkyl radical, aryl radical or arylalkyl radical.
摘要翻译：通过在适合作为聚合催化剂的路易斯酸存在下异丁烯或含异丁烯的单体混合物的聚合制备具有至少50mol％的聚异丁烯链末端亚乙烯基双键含量的高反应性异丁烯均聚物或共聚物，或者作为聚合催化剂有效并且由路易斯酸和供体形成的络合物，并且在引发剂的存在下，其中所用的引发剂是有机磺酸Z-SO 3 H，其中变量Z表示烷基，卤代烷基，环烷基，芳基或芳基烷基。

7. 发明申请

US20100324235A1 CATALYTIC COMPOSITION FOR PRODUCING 1-ALKENE AND ACRYLATES COPOLYMER AND METHOD FOR PRODUCING 1-ALKENE AND ACRYLATES COPOLYMER 有权
标题翻译：用于生产1-丙烯酸和丙烯酸酯共聚物的催化组合物及其制备方法1-烯烃和丙烯酸酯共聚物
公开(公告)号：US20100324235A1
公开(公告)日：2010-12-23
申请号：US12745274
申请日：2008-11-28
申请人： Won-Hee Kim , Byoung-Ho Jeon , Kyung-Seop Noh , Eun-Kyoung Song , Ki-Su Ro , Bae-Kun Shin
发明人： Won-Hee Kim , Byoung-Ho Jeon , Kyung-Seop Noh , Eun-Kyoung Song , Ki-Su Ro , Bae-Kun Shin
IPC分类号： C08F4/26 , B01J23/46 , B01J23/44 , C08F20/10 , C08F32/08
CPC分类号： C08F210/02 , C08F4/26 , C08F10/00 , C08F4/025
摘要： The present invention relates to a catalytic composition for producing a 1-alkene-acrylate copolymer that includes a metal nano catalyst, and a method for producing a 1-alkene-acrylate copolymer. In the catalytic composition for producing a 1 -alkene-acrylate copolymer, since the content of the polar comonomer is high, it may be used to produce the 1-alkene-acrylate copolymer that has no crystallinity and is capable of being used as an optical material. The method for producing the 1-alkene-acrylate copolymer may be produced by using a simple process of a mild polymerization condition without a polymerization condition of high temperature and high pressure, and it is easy to control physical properties.
摘要翻译：本发明涉及一种用于制备包含金属纳米催化剂的1-烯烃 - 丙烯酸酯共聚物的催化组合物和1-烯烃 - 丙烯酸酯共聚物的制备方法。在用于制备1-烯烃 - 丙烯酸酯共聚物的催化组合物中，由于极性共聚单体的含量高，因此可用于生产不具有结晶性并能够用作光学的1-烯烃 - 丙烯酸酯共聚物材料。制备1-烯烃 - 丙烯酸酯共聚物的方法可以通过使用温和聚合条件简单的方法制备，而不需要高温和高压的聚合条件，并且易于控制物理性能。

8. 发明申请

US20090054609A1 Process for the Preparation of Unsymmetric Bis(Imino) Compounds 有权
标题翻译：制备不对称双（亚氨基）化合物的方法
公开(公告)号：US20090054609A1
公开(公告)日：2009-02-26
申请号：US12087554
申请日：2007-01-08
申请人： Shahram Mihan , Benno Bildstein , Lars Kolling , Alexander Solchinger , Sascha Schlawjinski
发明人： Shahram Mihan , Benno Bildstein , Lars Kolling , Alexander Solchinger , Sascha Schlawjinski
IPC分类号： C08F4/26 , C07D213/50 , C07F15/02
CPC分类号： C07F15/025 , B01J2531/0238 , B01J2531/842 , C07D213/44 , C07D213/53 , C08F10/00 , C08F110/02 , C08F2500/17 , C08F2500/04 , C08F4/7042
摘要： Process for the preparation of monoimine compounds, wherein a dicarbonyl compound is reacted in an aliphatic, non-aromatic solvent with aniline. Monoimine compounds having electron-withdrawing substituents in the ortho position and unsymmetric bis(imino) compounds and unsymmetric iron complexes prepared therefrom and the use thereof in the polymerization of olefins.
摘要翻译：制备单亚胺化合物的方法，其中二羰基化合物在脂族，非芳族溶剂中与苯胺反应。在邻位具有吸电子取代基的单亚胺化合物和由其制备的不对称双（亚氨基）化合物和不对称铁络合物及其在烯烃聚合中的用途。

9. 发明授权

US07462673B2 Method for producing aqueous polymer dispersions 失效
标题翻译：生产聚合物水分散体的方法
公开(公告)号：US07462673B2
公开(公告)日：2008-12-09
申请号：US10556605
申请日：2004-05-06
申请人： Markus Schmid , Mubarik Mahmood Chowdhry , Peter Preishuber-Pfluegl , Xavier Sava , Ekkehard Lindner , Mahmoud Sunjuk , Peter Wegner
发明人： Markus Schmid , Mubarik Mahmood Chowdhry , Peter Preishuber-Pfluegl , Xavier Sava , Ekkehard Lindner , Mahmoud Sunjuk , Peter Wegner
IPC分类号： C08F4/26
CPC分类号： C08F10/00 , C08F110/06 , C08F2/18 , C08F4/7016
摘要： Process for preparing an aqueous polymer dispersion by polymerization of at least one olefinically unsaturated compound in an aqueous medium in the presence of at least one dispersant and a solid polymerization catalyst.
摘要翻译：在至少一种分散剂和固体聚合催化剂的存在下，通过在水介质中聚合至少一种烯属不饱和化合物来制备聚合物水分散体的方法。

10. 发明授权

US07022788B2 Polymerization process catalyzed by a bidentate bisphosphine-group VIII metal complex 失效
标题翻译：由二齿双膦Ⅷ族金属络合物催化的聚合方法
公开(公告)号：US07022788B2
公开(公告)日：2006-04-04
申请号：US10062673
申请日：2002-02-05
申请人： Duncan Frank Wass
发明人： Duncan Frank Wass
IPC分类号： C08F4/26 , C08F4/70
CPC分类号： C07F9/46 , C07F15/045 , C08F10/00 , C08F110/02 , C08F210/16 , C08F2500/03 , C08F2500/10 , C08F2500/04 , C08F210/14 , C08F4/7004 , C08F4/7016
摘要： A process for the polymerization and copolymerization of olefins is disclosed, comprising contacting the monomeric olefin under polymerization conditions with a polymerization catalyst or catalyst system which comprises (a) a source of a Group VIII metal; (b) a bidentate phosphine ligand having the formula (R1)(R1)P—X—P(R1)(R1), where each R1 is independently selected from a phenyl group or a substitued phenyl group with the proviso that at least one of the R1 groups is a phenyl group having at least one ortho substituent, and X is a bridging group of the structure —[N]x—[P]y—[N]— where x and y are independently 0 or 1, or —C(R4)2— where R4 may be the same or different and is hydrogen or a monovavlent hydrocarbyl, substituted hydrocarbyl or hetero-hydrocarbyl group; and optionally (c) a promoter.
摘要翻译：公开了一种用于烯烃聚合和共聚的方法，包括在聚合条件下使单体烯烃与聚合催化剂或催化剂体系接触，所述聚合催化剂或催化剂体系包含（a）Ⅷ族金属源; （b）具有下式（R 1）的二齿膦配体（R 1）（PX 1）（R 1）（R 1）其中每个R 1独立地选自苯基或取代的苯基，条件是至少一个R 1基团是具有至少一个邻位取代基的苯基，X是结构的桥连基团 - [N] - [N - ] - [P] Y - - - - - [N] - 其中x和 y独立地为0或1，或-C（R 4）2 - ，其中R 4可以相同或不同，为氢或单不饱和烃基，取代的烃基或杂烃基; 和任选地（c）启动子。

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