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1. 发明授权

US06825298B2 Amine organoborane complex initiated polymerizable compositions containing siloxane polymerizable components 失效
公开(公告)号：US06825298B2
公开(公告)日：2004-11-30
申请号：US10858114
申请日：2004-06-01
申请人： Mark F. Sonnenschein , Steven P. Webb , Benjamin L. Wendt , Daniel R. Harrington
发明人： Mark F. Sonnenschein , Steven P. Webb , Benjamin L. Wendt , Daniel R. Harrington
IPC分类号： C08F452
CPC分类号： C08L83/04 , C08G77/00 , C08G77/045 , C08G77/12 , C08G77/14 , C08G77/16 , C08G77/20 , C08K5/55 , C09J4/00 , C08L83/00
摘要： In one embodiment the invention is a polymerizable composition comprising a) an organoborane amine complex; b) one or more of monomers, oligomers or polymers having olefinic unsaturation which is capable of polymerization by free radical polymerization; c) one or more compounds, oligomers or prepolymers having a siloxane backbone and reactive moieties capable of polymerization; and d) a catalyst for the polymerization of the one or more compounds, oligomers or prepolymers having a siloxane backbone and reactive moieties capable of polymerization. This composition may further comprise a compound which causes the organoborane amine complex to disassociate. In a preferred embodiment, the two part composition further comprises a compound which is reactive with both the b) one or more of monomers, oligomers or polymers having olefinic unsaturation which is capable of polymerization by free radical polymerization; and the c) one or more compounds, oligomers or prepolymers having a siloxane backbone and reactive moieties capable of polymerization. This composition can be polymerized by contacting the two parts of the composition. In another embodiment the invention is an organoborane amine complex comprising an alkyl borane having ligands which are alkyl, cycloalkyl or both and an amino siloxane.

2. 发明授权

US06800706B1 Propylene polymer, molded object thereof, and process for producing propylene polymer 失效
标题翻译：丙烯聚合物，其成型物，以及丙烯聚合物的制造方法
公开(公告)号：US06800706B1
公开(公告)日：2004-10-05
申请号：US09784444
申请日：2001-02-26
申请人： Masami Kanamaru , Yutaka Minami , Koji Kakigami , Hideo Funabashi
发明人： Masami Kanamaru , Yutaka Minami , Koji Kakigami , Hideo Funabashi
IPC分类号： C08F452
CPC分类号： C08F10/06 , C08F4/65912 , C08F4/65916 , C08F110/06 , C08F210/06 , Y10S526/901 , Y10S526/943 , C08F4/65927 , C08F2500/20 , C08F2500/26 , C08F2500/17 , C08F2500/03 , C08F2500/15 , C08F210/08
摘要： The propylene polymer of the invention is transparent and has good low-temperature heat-sealability and scratch resistance, and is favorable to wrapping and packaging films. (1) The polymer has a melting point, Tm (° C.), measured through differential scanning calorimetry, of 110≦Tm≦140; (2) its heat of fusion &Dgr;H (J/g) and melting point Tm (° C.) satisfy &Dgr;H≧0.45×Tm+22; (3) the half-value width Th (° C.) of the peak top of its elution curve obtained in programmed-temperature fractionation is Th≦5; and (4) its intrinsic viscosity [&eegr;] (dl/g) measured in a solvent of tetralin at 135° C. falls between 0.5 and 5.
摘要翻译：本发明的丙烯聚合物是透明的，并且具有良好的低温热封性和耐划伤性，并且有利于包装和包装膜。（1）通过差示扫描量热法测定的聚合物的熔点Tm（℃）为110 = 0.45×Tm + 22; （3）程序温度分馏得到的洗脱曲线峰顶的半值宽度Th（℃）为Th <= 5; 和（4）在135℃下在四氢化萘的溶剂中测得的特性粘度η（dl / g）为0.5-5。

3. 发明授权

US06787617B1 Process for producing olefin living polymer 失效
标题翻译：生产烯烃活性聚合物的方法
公开(公告)号：US06787617B1
公开(公告)日：2004-09-07
申请号：US10009094
申请日：2001-11-08
申请人： Kazuo Soga , Takeshi Shiono , Michihiko Asai , Yasuzo Suzuki , Akira Miyazawa , Kenji Tsuchihara , Masahide Murata , Hiroyuki Ozaki , Masanao Kawabe , Toshio Kase , Jizhu Jin , Hideaki Hagiwara , Yoshifumi Fukui
发明人： Kazuo Soga , Takeshi Shiono , Michihiko Asai , Yasuzo Suzuki , Akira Miyazawa , Kenji Tsuchihara , Masahide Murata , Hiroyuki Ozaki , Masanao Kawabe , Toshio Kase , Jizhu Jin , Hideaki Hagiwara , Yoshifumi Fukui
IPC分类号： C08F452
CPC分类号： C08F297/08 , C08F4/65904 , C08F4/6592 , C08F4/65922 , C08F10/00 , C08F10/06 , C08F110/06 , C08F210/06 , Y10S526/943 , C08F4/65908 , C08F2500/03 , C08F210/14
摘要： A process for preparing olefinic living polymers having a molecular weight distribution (Mw/Mn) of 1 to 1.3, comprising polymerizing an olefinic monomer having 2 to 20 carbon atoms at low temperatures in the presence of a catalyst comprising (A) a hafnium or zirconium-containing compound having one or two cyclopentadienyl backbones, (B) a triphenyl boron compound or a tetraphenyl borate compound and optionally (C) a specific mono-, di- or trialkylaluminum compound. When the catalyst comprising the zirconium-containing compound is prepared by further using a titanium-containing compound (D), the polymerization temperature can be raised.
摘要翻译：一种制备具有1至1.3的分子量分布（Mw / Mn）的烯属活性聚合物的方法，包括在催化剂存在下在低温下聚合具有2至20个碳原子的烯烃单体，所述催化剂包含（A）铪或锆（B）三苯基硼化合物或四苯基硼酸盐化合物和任选的（C）特定的单 - ，二 - 或三烷基铝化合物。当通过进一步使用含钛化合物（D）制备包含含锆化合物的催化剂时，可以提高聚合温度。

4. 发明授权

US06740716B2 Organoborane amine complex polymerization initiators and polymerizable compositions 失效
标题翻译：有机硼烷胺络合物聚合引发剂和可聚合组合物
公开(公告)号：US06740716B2
公开(公告)日：2004-05-25
申请号：US10012629
申请日：2001-10-30
申请人： Steven P. Webb , Mark F. Sonnenschein
发明人： Steven P. Webb , Mark F. Sonnenschein
IPC分类号： C08F452
CPC分类号： C08G18/3268 , C08G18/8038 , Y10T428/31855 , Y10T428/31909 , Y10T428/31913
摘要： The invention is a two part composition useful for initiating cure of one or more polymerizable monomers which cure when exposed to free radicals comprising in one part an organoboraneamine complex and in a second part an isocyanate which is capable of decomplexing the organoborane complex wherein the ratio of amine nitrogen atoms to boron atoms is greater than 4.0:1.0. In another embodiment the invention is a two part polymerizable composition comprising part 1, a) an organoborane amine complex; and part 2, b) one or more of monomers, oligomers or polymers having olefinic unsaturation which is capable of polymerization by free radical polymerization c) an effective amount of a compound which causes the complex to disassociate thereby freeing the borane to initiate polymerization of the one or more monomers, oligomers or polymers having olefinic unsaturation wherein the compound which causes disassociation of the complex is kept separate from the complex until initiation of polymerization is desired; and d) a material which manages the heat of the polymerization reaction such that adhesion to the substrate is maintained, which material can be located in either part 1, part 2 or both parts.
摘要翻译：本发明是用于引发一种或多种可聚合单体的起始固化的两部分组合物，其当暴露于包含一部分有机硼烷胺络合物的自由基时固化，在第二部分中是能够使有机硼烷络合物分解的异氰酸酯，其中，胺氮原子与硼原子的比例大于4.0：1.0。在另一个实施方案中，本发明是两部分可聚合组合物，其包含部分1，a）有机硼烷胺络合物; 和第2部分，b）一种或多种具有烯属不饱和键的单体，低聚物或聚合物，其能够通过自由基聚合进行聚合; c）有效量的化合物，其导致络合物脱离，由此释放硼烷以引发一个或多个更多具有烯属不饱和基团的单体，低聚物或聚合物，其中引起复合物分解的化合物与络合物分离直到需要聚合开始; andd）一种管理聚合反应热量的材料，使得保持对基材的粘附，哪种材料可以位于第一部分或第二部分中，或两部分。

5. 发明授权

US06713578B2 Amine organoborane complex polymerization initiators and polymerizable compositions 失效
标题翻译：胺有机硼烷络合物聚合引发剂和可聚合组合物
公开(公告)号：US06713578B2
公开(公告)日：2004-03-30
申请号：US09881985
申请日：2001-06-15
申请人： Mark F. Sonnenschein , Steven P. Webb , Nelson G. Rondan
发明人： Mark F. Sonnenschein , Steven P. Webb , Nelson G. Rondan
IPC分类号： C08F452
CPC分类号： C08F4/52 , C07F5/027 , C09J4/06 , Y10T428/3154 , Y10T428/31544 , Y10T428/31909 , C08F265/06
摘要： A method of bonding two or more substrates together which comprises I. contacting the components of the composition comprising a) an organoborane/amine complex wherein the amine is selected from the group of amines having an amidine structural component; aliphatic heterocycles having at least one nitrogen in the heterocyclic ring; an alicyclic compound having bound to the ring a substituent having an amine moiety; primary amines which in addition to a primary amine have one or more hydrogen bond accepting groups of an ether, polyether, thioether or halogen wherein there is an alkylene chain of at least two carbon atoms between the primary amine and the hydrogen bond accepting group, and conjugated imines; b) one or more of monomers, oligomers or polymers having olefinic unsaturation; and, c) optionally an effective amount of a compound which causes the complex to disassociate or heating the composition to a temperature at which the complex dissassociates; II. contacting the adhesive composition with the two or more substrates; III. positioning the two or more substrates such that the adhesive composition is located between them; and IV. allowing the adhesive to cure so as to bind the two or more substrates together.
摘要翻译：将两个或更多个基板结合在一起的方法，其包括I。使包含a）有机硼烷/胺络合物的组合物的组分接触，其中胺选自具有脒结构组分的胺类; 在杂环中具有至少一个氮的脂族杂环; 与环结合的具有胺部分的取代基的脂环化合物; 除伯胺之外的伯胺具有一个或多个醚，聚醚，硫醚或卤素的氢键接受基团，其中在伯胺和氢键接受基团之间存在至少两个碳原子的亚烷基链，以及共轭亚胺; b）一种或多种具有烯属不饱和键的单体，低聚物或聚合物; 和c）任选地有效量的使复合物将组合物解离或加热至复合物不凝结的温度的化合物; II。使粘合剂组合物与两种或更多种基材接触; III。定位两个或更多个基板，使得粘合剂组合物位于它们之间; 和IV。使粘合剂固化，从而将两个或多个基底结合在一起。

6. 发明授权

US06683140B2 Catalyst for polymerization 有权
标题翻译：聚合催化剂
公开(公告)号：US06683140B2
公开(公告)日：2004-01-27
申请号：US09945666
申请日：2001-09-05
申请人： Shojiro Kaita , Zhaomin Hou , Yasuo Wakatsuki
发明人： Shojiro Kaita , Zhaomin Hou , Yasuo Wakatsuki
IPC分类号： C08F452
CPC分类号： C08F36/04 , Y10S526/943 , C08F4/52
摘要： A catalyst in a solid state for polymerization of a conjugated diene or copolymerization of a conjugated diene and an aromatic vinyl compound, which comprises a metallocene-type cation complex of a rare earth metal compound. The catalyst typically is a trivalent rare earth metal compound represented by the general formula (I): RaMXb wherein M represents a rare earth metal; R represents cyclopentadienyl group, a substituted cyclopentadienyl group, indenyl group, a substituted indenyl group, fluorenyl group, or a substituted fluorenyl group; X represents an anion; symbol “a” represents an integer of 1 or 2; and symbol “b” represents an integer of 1 or 2.
摘要翻译：用于共轭二烯的聚合的固体催化剂或共轭二烯和芳族乙烯基化合物的共聚合，其包含稀土金属化合物的茂金属型阳离子络合物。催化剂通常是由通式（I）表示的三价稀土金属化合物：其中M表示稀土金属的RaMXb; R代表环戊二烯基，取代的环戊二烯基，茚基，取代的茚基，芴基或取代的芴基; X表示阴离子; 符号“a”表示1或2的整数; 符号“b”表示1或2的整数。

7. 发明授权

US06630554B1 Process for polymerizing a methacrylic ester or an acrylic ester 有权
标题翻译：聚合甲基丙烯酸酯或丙烯酸酯的方法
公开(公告)号：US06630554B1
公开(公告)日：2003-10-07
申请号：US09664336
申请日：2000-09-18
申请人： Kenichi Hamada , Kazushige Ishiura , Toru Takahashi , Sachie Yaginuma , Makoto Akai , Tomohiro Ono , Kenji Shachi
发明人： Kenichi Hamada , Kazushige Ishiura , Toru Takahashi , Sachie Yaginuma , Makoto Akai , Tomohiro Ono , Kenji Shachi
IPC分类号： C08F452
CPC分类号： C08F4/48 , C08F4/52 , C08F20/18 , C08F212/08 , C08F297/026 , C08F220/14 , C08F2220/1825
摘要： (1) A methacrylic ester or an acrylic ester is anionically polymerized, using a polymerization initiator compound comprising an addition reaction product of a conjugated diene compound and an organic alkali metal compound, in the presence of a tertiary organoaluminum compound having in the molecule thereof a chemical structure represented by a formula: Al—O—Ar wherein Ar represents an aromatic ring; or (2) a methacrylic ester or an acrylic ester is anionically polymerized, using a polymerization initiator compound comprising an addition reaction product of an organic alkali metal compound and a compound having a 1,1-diaryl-1-alkene structure, by adding the ester in the form of a mixture with the above-mentioned specific tertiary organoaluminum compound to the polymerization system. In this way, various species of the esters can be anionically polymerized with a high initiation efficiency and a high living polymerization property in a solvent which can easily be recovered and reused under a mild cooling condition, using an organic alkali metal compound which has relatively good convenience.
摘要翻译：（1）使用包含共轭二烯化合物和有机碱金属化合物的加成反应产物的聚合引发剂化合物，在其分子内具有叔有机铝化合物的存在下，将甲基丙烯酸酯或丙烯酸酯阴离子聚合由下式表示的化学结构：Al-O-Ar，其中Ar表示芳环; 或（2）甲基丙烯酸酯或丙烯酸酯通过使用包含有机碱金属化合物与具有1,1-二芳基-1-烯烃结构的化合物的加成反应产物的聚合引发剂化合物进行阴离子聚合，酯与上述特定的叔有机铝化合物的混合物形式与聚合体系形成。这样，各种酯可以在溶剂中以高引发效率和高活性聚合性阴离子聚合，使用有利的碱金属化合物，在温和的冷却条件下容易回收和再次使用。

8. 发明授权

US06525148B1 Polymerization catalyst systems and processes therefor and therewith 有权
标题翻译：聚合催化剂体系及其工艺及其
公开(公告)号：US06525148B1
公开(公告)日：2003-02-25
申请号：US09640868
申请日：2000-08-18
申请人： Max P. McDaniel , Elizabeth A. Benham , Al R. Wolfe , Paul J. DesLauriers
发明人： Max P. McDaniel , Elizabeth A. Benham , Al R. Wolfe , Paul J. DesLauriers
IPC分类号： C08F452
CPC分类号： F16L9/127 , C08F10/00 , C08F210/16 , Y10T428/139 , C08F4/69 , C08F210/14 , C08F2500/12 , C08F2500/07 , C08F2500/13 , C08F2500/04 , C08F4/025
摘要： A copolymer of ethylene and a higher alpha olefin, preferably 1-hexene, can be produced using an activated chromium containing catalyst system and a cocatalyst selected from the group consisting of trialkylboron, trialkylsiloxyaluminum, and a combination of trialkylboron and trialkylaluminum compounds. The polymerization process must be carefully controlled to produce a copolymer resin having an exceptionally broad molecular weight distribution, extremely high PENT ESCR values, and a natural branch profile that impacts branching preferably into the high molecular weight portion of the polymer. The resulting copolymer resin is especially useful in high stiffness pipe applications.
摘要翻译：可以使用活化的含铬催化剂体系和选自三烷基硼，三烷基硅氧烷铝和三烷基硼和三烷基铝化合物的组合的助催化剂来制备乙烯和较高级α-烯烃（优选1-己烯）的共聚物。聚合过程必须仔细控制，以产生具有非常宽的分子量分布，极高的PENT ESCR值和天然分支分布的共聚物树脂，其优选地影响聚合物的高分子量部分的分支。所得共聚物树脂在高刚度管道应用中特别有用。

9. 发明授权

US06482903B1 Method for preparing a supported catalyst system and its use in a polymerization process 有权
标题翻译：制备负载型催化剂体系的方法及其在聚合过程中的应用
公开(公告)号：US06482903B1
公开(公告)日：2002-11-19
申请号：US09664908
申请日：2000-09-18
申请人： Agapios K. Agapiou , Chi-I Kuo
发明人： Agapios K. Agapiou , Chi-I Kuo
IPC分类号： C08F452
CPC分类号： C08F10/00 , C08F4/659 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F4/65927 , C08F10/02 , C08F210/16 , C08F4/025 , C08F4/02 , C08F4/027 , C08F210/14
摘要： The present invention relates to a composition of carboxylate metal salt and a flow improver useful in combination with a polymerization catalyst to improve the flowability and bulk density of the catalyst. The invention also relates to a polymerization process using the catalyst.
摘要翻译：本发明涉及羧酸金属盐的组合物和与聚合催化剂组合使用以改善催化剂的流动性和体积密度的流动改进剂。本发明还涉及使用该催化剂的聚合方法。

10. 发明授权

US06451725B1 Method for preparing catalyst components 失效
标题翻译：制备催化剂组分的方法
公开(公告)号：US06451725B1
公开(公告)日：2002-09-17
申请号：US09489662
申请日：2000-01-21
申请人： Hilkka Knuuttila , Harri Hokkanen , Eija Salo
发明人： Hilkka Knuuttila , Harri Hokkanen , Eija Salo
IPC分类号： C08F452
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65925 , C08F110/02 , C08F210/16 , Y10S526/907 , Y10S526/943 , C08F4/65916 , C08F2500/12 , C08F2500/03 , C08F210/14
摘要： Method for preparing a catalyst component for homo or copolymerization of olefins, said catalyst component comprising at least one metallocene compound on porous inorganic carrier, wherein said metallocene compound is mixed as pure compound in the absence of solvents with said carrier at a temperature which is at least 50° C. but below the vaporization temperature of the metallocene compound in reactor conditions for a sufficient time to obtain said catalyst component having said metallocene evenly distributed onto carrier particles.
摘要翻译：制备用于烯烃均相或共聚的催化剂组分的方法，所述催化剂组分在多孔无机载体上包含至少一种茂金属化合物，其中所述茂金属化合物在不存在溶剂的条件下与所述载体在温度为至少50℃，但低于茂金属化合物在反应器条件下的蒸发温度足够长的时间，以获得所述茂金属均匀分布在载体颗粒上的催化剂组分。

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