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    • 10. 发明申请
    • COATING COMPOSITIONS CONTAINING POLYSILOXANE MICHAEL ADDUCTS
    • 含有聚硅氧烷微胶囊的涂料组合物
    • US20160075834A1
    • 2016-03-17
    • US14785795
    • 2014-05-08
    • 3M INNOVATIVE PROPERTIES COMPANY
    • Frans Albert Audenaert
    • C08G77/392C09D133/14B05D3/06C08G77/388
    • C08G77/392B05D3/067C08G77/26C08G77/28C08G77/388C08K5/0025C08L83/08C09D4/06C09D133/06C09D133/14C09D175/16C08L83/00C09D183/16C08L75/16
    • There is provided a curable composition comprising more than 50% by weight of one or more compounds having at least two free radical polymerizable groups and at least 0.1% by weight of one or more polysiloxane additives comprising from 5 to 250 SiO-units and one or more terminal groups T selected from —N(R12)r—[CH2CHR9—C(═O)O—R10—(OCO—CR11═CH2)n]2-r or —S—CH2—CHR9—C(═O)O—R10—(OCO—CR11═CH2)n wherein R12 represents a group having from 1 to 30 carbon atoms, which may contain sulfur, nitrogen and/or oxygen, r is 0 or 1, R10 represents a linking group containing from 1 to 30 carbon atoms, which may contain sulfur, nitrogen and/or oxygen atoms, R9 and R11 represent H or a CH3 group and n is 1 to 5. Also provided are methods of making the curable compositions. The curable compositions can be used to provide stain release and/or stain repellency properties to a substrate.
    • 提供了包含大于50重量%的一种或多种具有至少两个可自由基聚合基团的化合物和至少0.1重量%的一种或多种聚硅氧烷添加剂的可固化组合物,所述聚硅氧烷添加剂包含5至250个SiO-单元和一个或多个 从-N(R 12)r- [CH 2 CHR 9 -C(= O)O-R 10 - (OCO-CR 11 = CH 2)n] 2-r或-S-CH 2 -CHR 9 -C(= O)选择的更多末端基团T O-R 10 - (OCO-CR 11 = CH 2)n其中R 12表示具有1至30个碳原子的基团,其可以含有硫,氮和/或氧,r为0或1,R 10表示含有1 至30个碳原子,其可以含有硫,氮和/或氧原子,R 9和R 11表示H或CH 3基团,n为1至5.还提供制备可固化组合物的方法。 可固化组合物可用于向基材提供污渍释放和/或防污性能。