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    • 2. 发明授权
    • Vacuum deposition and curing of oligomers and resins
    • 低聚物和树脂的真空沉积和固化
    • US06358570B1
    • 2002-03-19
    • US09283075
    • 1999-03-31
    • John D. Affinito
    • John D. Affinito
    • C08J716
    • B05D3/0493
    • The present invention is the formation of solid polymer layers under vacuum. More specifically, the present invention is the use of “standard” polymer layer-making equipment that is generally used in an atmospheric environment in a vacuum, and degassing the liquid material prior to injection into the vacuum. Additional layers of polymer or non-polymer may be vacuum deposited onto solid polymer layers. Formation of polymer layers under a vacuum improves material and surface characteristics, and subsequent quality of bonding to additional layers. Further advantages include use of less to no photoinitiator for curing, faster curing, fewer impurities in the polymer electrolyte, as well as improvement in material properties including no trapped gas resulting in greater density, and reduced material wetting angle that facilitates spreading of the material and provides a smoother finished surface.
    • 本发明是在真空下形成固体聚合物层。 更具体地,本发明是使用通常在真空中的大气环境中使用的“标准”聚合物层制备设备,并且在注入真空之前使液体材料脱气。 聚合物或非聚合物的附加层可以真空沉积到固体聚合物层上。 聚合物层在真空下的形成改善了材料和表面特性,以及随后的附着层粘接质量。 另外的优点包括使用少于或者没有光引发剂固化,更快固化,更低的聚合物电解质中的杂质,以及改善材料性能,包括没有产生更大密度的被捕获的气体,以及有助于材料扩散的材料润湿角度降低 提供更光滑的成品表面。
    • 3. 发明授权
    • Process for preparing interpenetrating polymer networks of controlled morphology
    • 制备控制形态的互穿聚合物网络的方法
    • US06331578B1
    • 2001-12-18
    • US09442830
    • 1999-11-17
    • Josephine TurnerYu-Ling Cheng
    • Josephine TurnerYu-Ling Cheng
    • C08J716
    • C08J3/246C08F283/12C08G77/442Y10S525/903C08F220/06
    • The invention relates to a method of making an interpenetrating polymer network (IPN) of at least a first polymer and a second polymer from a first and second component wherein the first component is the first polymer, or a polymerizable reactant selected from monomers or pre-polymers polymerizable to the first polymer and mixtures thereof, and the second component is a polymerizable reactant selected from monomers or pre-polymers polymerizable to the second polymer and mixtures thereof, the method comprising the steps of forming a reaction mixture of at least the first component, the second component, an initiator or catalyst and a crosslinker, effecting polymerization and crosslinking of polymerizable reactant, and recovering the IPN so obtained, wherein during the polymerization and crosslinking, a surface of the reaction mixture is maintained in contact with a third component comprising each said polymerizable reactant at a chemical potential similar to the chemical potential of the same reactant in the reaction mixture.
    • 本发明涉及一种从第一和第二组分制备至少第一聚合物和第二聚合物的互穿聚合物网络(IPN)的方法,其中第一组分是第一聚合物,或可选择的单体或预聚物的可聚合反应物, 可聚合到第一聚合物的聚合物及其混合物,第二组分是选自可聚合到第二聚合物的单体或预聚物及其混合物的可聚合反应物,该方法包括以下步骤:形成至少第一组分, 第二组分,引发剂或催化剂和交联剂,进行可聚合反应物的聚合和交联,并回收如此获得的IPN,其中在聚合和交联期间,反应混合物的表面保持与包含每个 所述可聚合反应物具有类似于s的化学势的化学势 在反应混合物中的反应物。