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    • 4. 发明申请
    • Process for the Conversion of a Solid Material Containing Hemicellulose, Cellulose and Lignin
    • US20220081731A1
    • 2022-03-17
    • US16966791
    • 2019-01-31
    • Avantium Knowledge Centre B.V.
    • Martijn KersbulckBenjamin McKayGerardus Johannes Maria Gruter
    • C13K1/02C13K13/00
    • A process for the conversion of a solid material containing hemicellulose, cellulose and lignin, which process comprises the following steps:
      (i) hydrolyzing, at a temperature equal to or less than 40° C., preferably equal to or less than 30° C., at least part of the hemicellulose of the solid material by contacting the solid material with a first aqueous hydrochloric acid solution, which first aqueous hydrochloric acid solution has a hydrochloric acid concentration in the range from equal to or more than 15.0 wt. % to less than 40.0 wt. %, based on the weight amount of water and hydrochloric acid in such first aqueous hydrochloric acid solution, yielding a remaining solid material and an aqueous first hydrolysate product solution;
      (ii) displacing aqueous solution from the remaining solid material with a non-aqueous displacement fluid;
      (iii) hydrolyzing, at a temperature equal to or less than 40° C., preferably equal to or less than 30° C., at least part of the cellulose of the remaining solid material by replacing the non-aqueous displacement fluid with a second aqueous hydrochloric acid solution, which second aqueous hydrochloric acid solution has a hydrochloric acid concentration in the range from equal to or more than 40.0 wt. % to equal to or less than 51.0 wt. %, based on the weight amount of water and hydrochloric acid in such second aqueous hydrochloric acid solution, yielding a residue and an aqueous second hydrolysate product solution
      wherein the process is carried out in one or more reactors and wherein the reactor comprises a cylindrical vessel with its axis arranged in an essentially vertical manner, and
      wherein said non-aqueous displacement fluid is a non-aqueous, preferably hydrophobic, liquid having a density equal to or less than 1000 kilograms per cubic meter (kg/m3), and
      wherein the non-aqueous displacement fluid is supplied to such reactor in a downward fashion.