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1. 发明授权

US10941283B2 Nitrile rubber composition and rubber cross-linked product 有权
公开(公告)号：US10941283B2
公开(公告)日：2021-03-09
申请号：US16084709
申请日：2017-03-13
申请人： ZEON CORPORATION
发明人： Yoshio Fukumine
IPC分类号： C08L83/04 , C08L13/00 , C08K3/36 , C09K3/10 , C08K5/5435 , C08K5/544 , C08K5/5419 , C08K5/548 , C08L33/18 , C08K5/5425 , C08L79/02 , F16L11/04
摘要： A nitrile rubber composition including: a carboxyl group-containing nitrile rubber containing 5 to 30% by weight of an α,β-ethylenically unsaturated nitrile monomer unit, 0.1 to 10% by weight of a carboxyl group-containing monomer unit, 15 to 60% by weight of an α,β-ethylenically unsaturated monocarboxylic acid ester monomer unit, and 20 to 64.9% by weight of a conjugated diene monomer unit and having an iodine value of 120 or less; and a reactive silicone oil.

2. 发明申请

US20190299166A1 Macroporous Or Mesoporous Polymer Films In Hollow Fiber Geometry 审中-公开
公开(公告)号：US20190299166A1
公开(公告)日：2019-10-03
申请号：US16307627
申请日：2018-04-26
申请人： Helmholtz-Zentrum Geesthacht Zentrum für Material- und Küstenforschung GmbH
发明人： Nazia NOOR , Volker ABETZ , Joachim KOLL
IPC分类号： B01D67/00 , B01D71/16 , B01D69/08 , B01D71/80 , C08L1/14 , C08L25/06 , C08L33/18 , C08L27/16 , C08L79/08
摘要： The present invention is directed towards a method for the preparation of macroporous or mesoporous polymer films in hollow fiber geometry. The method according to the present invention reliably produces macroporous or mesoporous homopolymer or copolymer films in hollow fiber geometry having an ordered porous structure. Preferably, the pores are isoporous. The method involves the purging or casting a polyol adjacent to a film forming polymer solution of at least one homopolymer or at least one copolymer in a suitable solvent while polyol diffuses in and then condenses out of the film forming solution before the solution is immersed into a coagulation bath. The methods also require the presence of a carrier solution or carrier substrate during spinning or casting. The method makes macroporous or mesoporous film formation possible with a single step processing method.

3. 发明授权

US10385647B2 Swellable rubber compositions 有权
公开(公告)号：US10385647B2
公开(公告)日：2019-08-20
申请号：US15210814
申请日：2016-07-14
申请人： WEIR SLURRY GROUP, INC.
发明人： Francisco A. Gozalo , Sanford W. Clark
IPC分类号： E21B33/12 , C09K8/44 , C08L33/18 , C09K8/493
摘要： This disclosure relates to swellable compositions, such as those, for example, comprising super absorbent polymers.

4. 发明授权

US10239979B2 Highly saturated nitrile rubber composition and cross-linked rubber 有权
公开(公告)号：US10239979B2
公开(公告)日：2019-03-26
申请号：US15508822
申请日：2015-09-04
申请人： ZEON CORPORATION
发明人： Yoshio Fukumine
IPC分类号： C08F236/12 , C08L13/00 , C08L33/18 , C08L67/00 , C08K5/14 , C08L67/02
摘要： A highly saturated nitrile rubber composition obtained by mixing 7 to 40 wt % of a carboxyl group-containing highly saturated nitrile rubber (A1) containing 15 to 60 wt % of α,β-ethylenically unsaturated nitrile monomer units and 1 to 60 wt % of α,β-ethylenically unsaturated dicarboxylic acid monoester monomer units and having an iodine value of 120 or less, 10 to 78 wt % of a highly saturated nitrile rubber (A2) containing α,β-ethylenically unsaturated nitrile monomer units in 15 to 60 wt %, having a content of α,β-ethylenically unsaturated dicarboxylic acid monoester monomer units of 0.9 wt % or less, and having an iodine value of 120 or less, and 15 to 50 wt % of a polyester resin (B) at a temperature of a melting point of the polyester resin (B) or more is provided.

5. 发明授权

US09273173B2 Flame retardant acrylic-based copolymer, resin composition comprising same and molding form thereof 有权
标题翻译：阻燃丙烯酸类共聚物，包含其的树脂组合物和其模塑形式
公开(公告)号：US09273173B2
公开(公告)日：2016-03-01
申请号：US14365101
申请日：2012-11-28
申请人： CHEIL INDUSTRIES INC.
发明人： Joo Hyun Jang , Kee Hae Kwon , Jin Hwa Chung , Yong Hee Kang , Ja Kwan Goo , Man Suk Kim , Kwang Soo Park
IPC分类号： C08F220/18 , C08L33/08 , C08L69/00 , C08F230/02 , C08F220/14 , C08L33/18
CPC分类号： C08F220/18 , C08F220/14 , C08F230/02 , C08L33/08 , C08L33/18 , C08L69/00 , C08L2201/02 , C08F212/08 , C08F220/44
摘要： The present invention provides a flame retardant acrylic-based copolymer which includes a derivative unit obtained from a monomer mixture comprising: (A) a (meth)acrylic monomer; (B) at least one vinyl monomer selected from the group consisting of an aromatic vinyl monomer and an unsaturated nitrile monomer; and (C) a phosphorus-based (meth)acrylic monomer. The flame retardant acrylic copolymer has high refractivity and exhibits excellent flame retardancy and scratch resistance.
摘要翻译：本发明提供一种阻燃丙烯酸系共聚物，其包含由单体混合物获得的衍生单元，所述单体混合物包含：（A）（甲基）丙烯酸单体; （B）至少一种选自芳族乙烯基单体和不饱和腈单体的乙烯基单体; 和（C）磷基（甲基）丙烯酸类单体。阻燃丙烯酸共聚物具有高折射率并且显示出优异的阻燃性和耐擦伤性。

6. 发明授权

US09181406B2 Process of incorporating additives into vinylidene chloride polymers without the use of a blender 有权
标题翻译：将添加剂加入到偏二氯乙烯聚合物中而不使用混合器的方法
公开(公告)号：US09181406B2
公开(公告)日：2015-11-10
申请号：US14343258
申请日：2012-09-13
申请人： Susan M. Kling
发明人： Susan M. Kling
IPC分类号： B05D7/26 , C08L27/04 , C08L33/18 , C08J3/20 , C08J3/12 , C08L27/08
CPC分类号： C08J3/203 , C08F14/08 , C08J3/128 , C08J2327/08 , C08L27/08 , C08L23/06 , C08L91/08 , C08L91/06 , C08K5/1515 , C08K5/11 , C08K2003/265 , C08L83/04 , C08L23/30
摘要： Solid additive particles are added to solid vinylidene chloride (VDC) polymer particles by a process comprising the steps of: A. Polymerizing VDC monomer, optionally with one or more mono-ethylenically unsaturated comonomers, in a polymerization zone under polymerization conditions to form solid VDC polymer particles; B. Stopping the polymerization of the VDC monomers after formation of the solid VDC polymer particles; and C. Contacting the solid VDC polymer particles with the solid additive particles (i) before the solid VDC polymer particles are de-watered, and (ii) at a temperature sufficient to melt or soften the solid additives particles but insufficient to melt or soften the solid VDC polymer particles such that the melted or softened solid additive particles adhere to the solid VDC polymer particles upon contact.
摘要翻译：通过包括以下步骤的方法将固体添加剂颗粒加入到固体偏二氯乙烯（VDC）聚合物颗粒中：A.聚合条件下聚合VDC单体，任选与一个或多个单烯属不饱和共聚单体在聚合区中形成固体VDC 聚合物颗粒; B.形成固体VDC聚合物颗粒后停止VDC单体的聚合; 在固体VDC聚合物颗粒脱水之前，将固体VDC聚合物颗粒与固体添加剂颗粒（i）接触，和（ii）在足以熔化或软化固体添加剂颗粒但不足以熔化或软化的温度下固体VDC聚合物颗粒，使得熔融或软化的固体添加剂颗粒在接触时粘附到固体VDC聚合物颗粒上。

7. 发明授权

US08962138B2 Organically functionalized polysiloxane nanoparticles, method for the production thereof, and use thereof 有权
标题翻译：有机官能化聚硅氧烷纳米颗粒，其制备方法及其用途
公开(公告)号：US08962138B2
公开(公告)日：2015-02-24
申请号：US13377064
申请日：2010-06-10
申请人： Monika Bauer , Hans-Juergen Glaesel
发明人： Monika Bauer , Hans-Juergen Glaesel
IPC分类号： B32B5/16 , C08G77/04 , C08G77/06 , C08G77/20 , C08G77/54 , C08G77/62 , C08K5/544 , C08L33/18
CPC分类号： C08G77/04 , C08G77/54 , C08G77/62 , C08K5/544 , C08L33/18 , Y10T428/2982 , Y10T428/2991 , Y10T428/2998 , Y10T428/31663 , C08L2666/44
摘要： The present invention relates to polysiloxane nanoparticles having the following properties: an average particle size d50 (measured using REM recordings) in the range of 10-200 nm, a specific surface area Ao of at least 50 m2/g, a pore volume of at least 0.2 cm3/g, an average pore volume d50 of at least 0.8 nm, wherein the particles have groups that contain carbon, which groups are bonded to the silicon at least partially in the form of unsubstituted or substituted alkyl, alkenyl, aryl, arylalkyl, or alkylaryl groups. Said polysiloxane nanoparticles can be produced, among other things, in that either a silazane or a mixture of different silazanes having one or more —[Si(R)(R1)—NR2]— units and/or a silane or a mixture of different silanes having the formula R′x—SiX4-a or an oligosiloxane obtainable by means of hydrolytic condensation of said silane/said silanes or a mixture of such oligosiloxanes are provided in a solvent and brought in contact with a strongly alkaline medium in such a way that the pH is not below 13 after the addition thereof. In specific embodiments, synthesis in acid is also successful.
摘要翻译：本发明涉及具有以下特性的聚硅氧烷纳米粒子：10-200nm范围内的平均粒径d50（使用REM记录测定），比表面积Ao为至少50m 2 / g，孔体积为至少0.2cm 3 / g，平均孔体积d50至少为0.8nm，其中所述颗粒具有含有碳的基团，所述基团至少部分地以未取代或取代的烷基，烯基，芳基，芳烷基，或烷基芳基。可以制备所述聚硅氧烷纳米颗粒，其特征在于，硅氮烷或具有一个或多个 - [Si（R）（R 1）-NR 2] - 单元和/或硅烷或不同的混合物的不同硅氮烷的混合物具有式R'x-SiX4-a的硅烷或通过所述硅烷/所述硅烷或这种低聚硅氧烷的混合物的水解缩合得到的低聚硅氧烷在溶剂中提供，并以这种方式与强碱性介质接触加入后pH不低于13。在具体实施方案中，酸中的合成也是成功的。

8. 发明授权

US08227549B2 Composition with increased stress cracking resistance 失效
标题翻译：具有增加的抗开裂性的组合物
公开(公告)号：US08227549B2
公开(公告)日：2012-07-24
申请号：US12600840
申请日：2008-04-09
申请人： Klaus Schultes , Werner Hoess , Nils Mehler
发明人： Klaus Schultes , Werner Hoess , Nils Mehler
IPC分类号： C08L25/02 , C08L33/02 , C08L33/04 , C08L33/14 , C08L33/18 , C08L33/20 , C08L35/02
CPC分类号： C08L33/08 , C08L25/12 , C08L33/10 , C08L2666/04
摘要： Composition containing, based in each case on its total weight, A) 50.0% by weight to 99.5% by weight of at least one (meth)acrylate (co)polymer and B) 0.5% by weight to 50.0% by weight of at least one copolymer obtainable by polymerization of a monomer mixture comprising i. 70% by weight to 92% by weight of a vinylaromatic monomer and ii. 8% by weight to 30% by weight of acrylonitrile or methacrylonitrile or mixtures thereof and iii. 0% by weight to 22% by weight of at least one further monomer, the composition having a haze according to ASTM D1003 of less than 2.0% at 23° C. and a haze according to ASTM D1003 of less than 4.0% at 40° C. and the composition containing at least one (meth)acrylate (co)polymer a) having a solution viscosity in chloroform at 25° C. (ISO 1628—part 6) of greater than 55 ml/g. The moldings obtainable from the composition are distinguished in particular by improved stress cracking resistance and are suitable in particular for coverings, finishes or films.
摘要翻译：包含基于每种情况的总重量的组合物A）50.0重量％至99.5重量％的至少一种（甲基）丙烯酸酯（共）聚合物，和B）至少0.5重量％至50.0重量％一种共聚物，其通过单体混合物的聚合获得，所述单体混合物包含i。 70重量％至92重量％的乙烯基芳族单体，和ii。 8重量％至30重量％的丙烯腈或甲基丙烯腈或其混合物，iii。 0重量％至22重量％的至少一种其它单体，该组合物在-23℃下具有根据ASTM D1003的雾度小于2.0％，并且根据ASTM D1003的雾度小于4.0％ 40℃，组合物含有至少一种在-25℃（ISO 1628-第6部分）中溶液粘度在55ml / g以上的（甲基）丙烯酸酯（共）聚合物）a）。可从组合物获得的模制品特别是通过改进的耐应力开裂性来区分，特别适用于覆盖物，表面处理剂或膜。

9. 发明授权

US08183324B2 Antistatic acrylic fiber and a method for manufacturing the same 有权
标题翻译：抗静电丙烯酸纤维及其制造方法
公开(公告)号：US08183324B2
公开(公告)日：2012-05-22
申请号：US12918161
申请日：2009-06-19
申请人： Yoshiki Yamato , Yoshihiro Watanabe
发明人： Yoshiki Yamato , Yoshihiro Watanabe
IPC分类号： C08F8/00 , C08L33/02 , C08L33/04 , C08L33/18 , C08L33/20 , C08L35/02
CPC分类号： D06P3/76 , D01F1/09 , D01F6/18 , D01F6/38 , D02J13/00 , D06P1/41 , D06P1/6533
摘要： The present invention is an antistatic acrylic fiber which comprises 90 to 99% by weight of acrylonitrile polymer containing 80 to 100% by weight of acrylonitrile as a constituting component and 10 to 1% by weight of acrylic antistatic resin containing 10 to 70% by weight of acrylonitrile as a constituting component, characterized in that alkali metal ion is contained in the fiber in an amount of not less than 150 ppm. The acrylic fiber of the present invention has antistatic property which does not lower so much even if the fiber is subjected to a spinning and dyeing step.
摘要翻译：本发明是一种抗静电丙烯酸纤维，其包含90至99重量％的含有80至100重量％的丙烯腈作为构成成分的丙烯腈聚合物和10至1重量％的含10至70重量％的丙烯酸类抗静电树脂的丙烯腈作为构成成分，其特征在于纤维中含有不少于150ppm的碱金属离子。本发明的丙烯酸纤维具有抗静电性能，即使经过纺丝和染色步骤也不会降低太多。

10. 发明申请

US20120094104A1 ABLATABLE ELEMENTS FOR MAKING FLEXOGRAPHIC PRINTING PLATES 有权
标题翻译：用于制作柔版印刷板的可拆卸元件
公开(公告)号：US20120094104A1
公开(公告)日：2012-04-19
申请号：US13325093
申请日：2011-12-14
申请人： Michael T. Regan , David B. Bailey , Christine J. Landry-Coltrain
发明人： Michael T. Regan , David B. Bailey , Christine J. Landry-Coltrain
IPC分类号： C08L69/00 , C08L33/18
CPC分类号： B41C1/05 , B41N1/12 , Y10S430/145
摘要： Flexographic printing plates and other relief images can be formed from a laser-ablatable element having a laser-ablatable layer that is from about 300 to about 4,000 μm thickness. The laser-ablatable layer includes a film-forming material that is a laser-laser-ablatable material or the film-forming material has dispersed therein a laser-ablatable material. The laser-ablatable material is a polymeric material that when heated to 300° C. at a rate of 10° C./minute, loses at least 60% of its mass to form at least one predominant low molecular weight product. The laser-ablatable material also comprises at least 0.01 weight % of a depolymerization catalyst that is a Lewis acid or organometallic based catalyst. The element can be imaged by ablation at an energy of at least 1 J/cm2 to provide a relief image.
摘要翻译：柔版印刷版和其它浮雕图像可以由具有约300至约4,000μm厚度的激光可烧蚀层的激光可烧蚀元件形成。激光烧蚀层包括作为激光可激光材料的成膜材料，或者成膜材料中分散有激光可烧蚀材料。激光可烧蚀材料是一种聚合材料，当以10℃/分钟的速率加热至300℃时，其损失至少60％的质量以形成至少一种主要的低分子量产物。激光可烧蚀材料还包含至少0.01重量％的解聚催化剂，其是路易斯酸或有机金属基催化剂。该元件可以以至少1J / cm 2的能量消融成像，以提供浮雕图像。

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