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    • 3. 发明申请
    • POLYMER COMPOSITION FOR SELECTIVE SINTERING
    • 用于选择性烧结的聚合物组合物
    • WO2017220228A1
    • 2017-12-28
    • PCT/EP2017/058260
    • 2017-04-06
    • SABIC GLOBAL TECHNOLOGIES B.V.
    • BASHIR, ZahirGU, Hao
    • C08G63/183B29C67/00C08J9/24
    • The present invention relates to a polymer composition for production of shaped objects via selective laser sintering wherein the polymer composition comprises a thermoplastic material having: - a crystallisation half time of ≥ 30 s and ≤ 12 min at a supercooling of 50°C below the peak melt temperature, wherein the crystallisation half time t ½,c as determined via differential scanning calorimetry in accordance with ISO 11357-1 (2009); - a glass transition temperature T g of ≥ 50°C as determined in accordance with ISO 11357-2 (2013); - a peak melt temperature T p,m of ≥ 200°C as determined in accordance with ISO 11357-3 (2011), first heating run; - an extrapolated first heating run melt onset temperature T ei,m of ≥ 5°C above the extrapolated first cooling run crystallisation end temperature T ef,c as determined in accordance with ISO 11357-1 (2009), first heating and cooling run; and - a degree of crystallinity of ≥ 10.0 % as determined according to the formula (I), wherein: - D = degree of crystallinity of the thermoplastic material (%); - ΔH f = enthalpy of fusion of the thermoplastic material as determined in accordance with ISO 11357-3 (2011); - ΔH f,100 = enthalpy of fusion of the thermoplastic material in a 100% crystalline state. Such polymer composition has a continuous use temperature of ≥ 100°C, and a low change of molecular weight during exposure to selective laser sintering processing temperatures.
    • 本发明涉及用于通过选择性激光烧结制备成形物体的聚合物组合物,其中聚合物组合物包含热塑性材料,该热塑性材料具有: - 结晶半衰期≥30s且≤12min, 在低于峰值熔融温度50℃的过冷度下进行,其中根据ISO 11357-1(2009)通过差示扫描量热法测定的结晶半衰期t c1,c c。 - 根据ISO 11357-2(2013)测定的≥50℃的玻璃化转变温度T g; - 根据ISO 11357-3(2011)测定的≥200℃的峰值熔融温度T p,m,第一次加热试验; - 外推的第一次加热运行的熔化起始温度T in,m℃高于外推的第一次冷却运行结晶终止温度T off,c℃的≥5℃,如根据 ISO 11357-1(2009),第一次加热和冷却运行; 和 - 根据式(I)测定的结晶度≥10.0%,其中:-D =热塑性材料的结晶度(%); - ΔHf =热塑性材料的熔化焓,根据ISO 11357-3(2011)测定; -ΔHf,100 =热塑性材料在100%结晶状态下的熔化焓。 这种聚合物组合物具有≥100℃的连续使用温度和暴露于选择性激光烧结处理温度期间的低分子量变化。
    • 4. 发明申请
    • CYRSTALLINE POLYCARBONATE ARTICLES AND METHODS OF MAKING THE SAME
    • CYRSTALLINE POLYCARBONATE ARTICLES AND METHODS OF MATERING THE SAME
    • WO2016151475A1
    • 2016-09-29
    • PCT/IB2016/051584
    • 2016-03-21
    • SABIC GLOBAL TECHNOLOGIES B.V.
    • BASHIR, ZahirTHELAKKADAN, Abdul Salam
    • C08K5/098C08J7/02
    • C08K5/098C08J7/02C08L69/00G01N25/4866
    • In an embodiment, an article comprises a crystalline polycarbonate, wherein the article has a polycarbonate crystallinity of greater than or equal to 10 wt% based on the total weight of the polycarbonate. In another embodiment, a method of making an article comprises adding a crystalline polycarbonate powder into a cavity of a compression mold; wherein the crystalline polycarbonate powder has a crystallinity of greater than or equal to 10 wt% based on the total weight of the crystalline polycarbonate powder; compressing the crystalline polycarbonate powder in the cavity at a compression temperature of greater than or equal to 10°C less than the melting temperature of the crystalline polycarbonate powder (T comp ≥ T m - 10°C) and at a compression pressure of greater than or equal to 1 MPa; and removing the article from the cavity.
    • 在一个实施方案中,制品包含结晶聚碳酸酯,其中所述制品的聚碳酸酯结晶度基于聚碳酸酯的总重量大于或等于10重量%。 在另一个实施方案中,制备制品的方法包括将结晶聚碳酸酯粉末添加到压缩模具的空腔中; 其中所述结晶聚碳酸酯粉末具有基于所述结晶聚碳酸酯粉末的总重量大于或等于10重量%的结晶度; 在结晶聚碳酸酯粉末的熔融温度(Tcomp≥Tm-10℃)下压缩温度大于或等于10℃的压缩温度下压缩结晶聚碳酸酯粉末,压缩压力大于或等于 至1MPa; 并从空腔中取出物品。