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    • 6. 发明申请
    • METHOD FOR PRODUCING HYDROLYSIS-STABLE AMMONIUM NITRILES
    • 用于生产水解铵的亚硝酸盐
    • WO0212175A3
    • 2002-04-11
    • PCT/EP0108883
    • 2001-08-01
    • CLARIANT GMBHSCHREIBER MANFREDBORCHERS GEORGMOGCK OLIVERWEINELT FRANK
    • SCHREIBER MANFREDBORCHERS GEORGMOGCK OLIVERWEINELT FRANK
    • C11D3/395C07C253/30C07C253/32C07C255/24C07C255/25C07C303/32C07C303/42C07C309/31C11D3/39C11D7/54
    • C11D3/3925C07C253/32C07C255/25
    • The invention relates to a method for producing hydrolysis-stable ammonium nitriles by reacting a compound of formula (1), wherein R , R , and R are identical or different and represent linear or branched C1-C24-alkyl groups, C2-C24-alkenyl groups, substituted or non-substituted benzyl or C1-C4-alkoxy-C1-C4-alkyl groups, or wherein R and R , together with the nitrogen atom to which they are bonded, form a ring with 4 to 6 C-atoms which can be substituted with C1-C5 alkyl, C1-C5 alkoxy, C1-C5 alkanoyl, phenyl, amino, ammonium, cyano, cyanamino, chlorine or bromine and which can contain in addition to the nitrogen atom, instead of the carbon atoms, one or two oxygen or nitrogen atoms, a group N-R or a group R -N-R , wherein R6 is hydrogen, C1-C5-alkyl, C2-C5-alkenyl, C2-C5-alkinyl, phenyl, C7-C9-aralkyl, C5-C7-cycloalkyl, C1-C6-alkanoyl, cyanomethyl or cyan, R and R are hydrogen, C1-C4-alkyl, C1-C4-alkenyl, C1-C4-alkoxy-C1-C4-alkyl, phenyl or C1-C3-alkylphenyl, preferably hydrogen, methyl or phenyl, R especially meaning hydrogen when R does not mean hydrogen, and X represents an anion; with an alkaline or ammonium salt of an alkane sulfonate, paraffin sulfonate, aryl sulfonate, alcohol sulfate or fatty acid alkyl carboxylate in the presence of water, at a high temperature.
    • 本发明涉及一种方法,用于由式(1)其中R <1>,R <2>,R <3>是相同的或不同的并且是直链或支链的C1-C24-的化合物反应而制造水解稳定的铵腈 烷基,C2-C24链烯基,取代或未取代的苄基,或C1-C4烷氧基C1-C4烷基基团是或其中,R <1>和R <2>与氮原子一起连接形成一个其 形式环具有4至6个C原子,其可与C1-C5烷基,C1-C5烷氧基,C1-C5链烷酰基,苯基,氨基,铵基,氰基,cyanamino,氯或溴取代,并且除了该氮原子 NR <6>或一个基团R可含有<3> -NR <6>,而不是碳原子,一个或两个氧原子或氮原子,一个基团,其中R6是氢,C1-C5烷基,C2-C5链烯基,C2- C5炔基,苯基,C7-C9芳烷基,C5-C7环烷基,C1-C6链烷酰基,氰基甲基或氰基,R <4>和R <5>是氢,C1-C4烷基,C1-C4 一 lkenyl,C1-C4烷氧基C1-C4烷基,有苯基或C1-C3烷基苯基,优选氢,甲基或苯基,其中特别是R <4>是氢,当R <5>不为氢,和X 是阴离子,用烷烃磺酸在水在升高的温度下存在的碱金属或铵盐,石蜡磺酸盐,芳基磺酸盐,醇硫酸酯或Fettsäurealkylcarboxylats。