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    • 2. 发明授权
    • Magnetic recording medium
    • 磁记录介质
    • US5804283A
    • 1998-09-08
    • US968860
    • 1997-11-05
    • Hiroo InabaMasaki SuzukiNaoto AbeToshiyuki KitaharaSatoshi MatsubaguchiHiroaki Takano
    • Hiroo InabaMasaki SuzukiNaoto AbeToshiyuki KitaharaSatoshi MatsubaguchiHiroaki Takano
    • G11B5/70G11B5/702G11B5/738G11B5/68
    • G11B5/70G11B5/7022G11B5/738Y10S428/90Y10T428/24355Y10T428/24942Y10T428/24975Y10T428/265Y10T428/31609
    • A magnetic recording medium prepared by a process which comprises providing a nonmagnetic layer comprising a nonmagnetic powder and a binder on a nonmagnetic support, and then providing one or more magnetic layers containing at least a ferromagnetic powder and a binder on the nonmagnetic layer while the nonmagnetic layer is wet, wherein the thickness of the magnetic layer is from 0.07 to 0.20 .mu.m, the magnetic layer comprises a resin curable by a polyisocyanate as a binder, the nonmagnetic layer is a layer cured by a polyisocyanate, and the ratio N/Fe in the magnetic layer is from 0.010 to 0.090 as determined by an X-ray photoelectric spectrophotometer; and a magnetic recording medium comprising a nonmagnetic support having thereon a lower nonmagnetic layer comprising a nonmagnetic powder and a binder, and further thereon a magnetic layer comprising at least a ferromagnetic metal powder and a binder, wherein the magnetic layer has a thickness of from 0.07 to 0.20 .mu.m, the magnetic layer has a maximum magnetic flux density Bm of from 3,700 to 6,000 G as measured in an external magnetic field of 10 kOe, the magnetic layer has a coercive force Hc of from 2,000 to 3,000 Oe, the magnetic layer has a center line surface roughness Ra of from 1.0 to 3.0 nm, and the nonmagnetic support has a center line surface roughness of from 0.5 to 7.0 nm on the side thereof to which the lower non layer is provided.
    • 一种磁记录介质,其制备方法包括在非磁性载体上提供包含非磁性粉末和粘合剂的非磁性层,然后在非磁性层上提供至少含有铁磁性粉末和粘结剂的一个或多个磁性层,而非磁性 层是湿的,其中磁性层的厚度为0.07至0.20μm,磁性层包含可通过多异氰酸酯作为粘合剂固化的树脂,非磁性层是由多异氰酸酯固化的层,N / Fe 在磁性层中,由X射线光电分光光度计测定为0.010〜0.090; 以及包含非磁性载体的磁记录介质,其上具有包含非磁性粉末和粘合剂的下部非磁性层,并且还包括至少包含强磁性金属粉末和粘结剂的磁性层,其中所述磁性层的厚度为0.07 至0.20μm,磁性层的磁通密度Bm为10kOe的外部磁场中测定的3,700〜6,000G,磁性层的矫顽力Hc为2000〜3000Oe,磁性层 具有1.0至3.0nm的中心线表面粗糙度Ra,并且非磁性载体在其设置较低非层的一侧具有0.5至7.0nm的中心线表面粗糙度。
    • 4. 发明授权
    • Magnetic recording medium
    • 磁记录介质
    • US5455112A
    • 1995-10-03
    • US10846
    • 1993-01-29
    • Hiroo InabaKiyomi Ejiri
    • Hiroo InabaKiyomi Ejiri
    • C09C1/48C09D5/23C09D7/12G11B5/73G11B5/733G11B5/738B32B5/16G11B5/66
    • G11B5/738G11B5/733Y10S428/90Y10S428/928Y10T428/25Y10T428/256Y10T428/257Y10T428/259Y10T428/26Y10T428/265
    • A magnetic recording medium produced by providing a lower non-magnetic layer comprising a non-magnetic powder dispersed in a binder on a non-magnetic support followed by providing, while the lower non-magnetic layer is still wet, an upper magnetic layer comprising a ferromagnetic powder dispersed in a binder on the lower non-magnetic layer, wherein a mean thickness of the upper magnetic layer is 1.0 .mu.m or less and the non-magnetic powder in the lower non-magnetic layer comprises (A) a granular inorganic powder having a mean particle size of from 0.01 to 0.08 .mu.m, (B) a carbon black powder having a mean particle size of from 0.01 to 0.04 .mu.m and (C) a powder component having a larger mean particle size than the mean particle size of each of powders (A) and (B). The magnetic recording medium has good electromagnetic characteristics and has excellent running durability with little edge damage after repeated running.
    • 提供一种磁记录介质,其通过在非磁性载体上提供分散在粘合剂中的非磁性粉末的下部非磁性层,然后在下部非磁性层仍然是湿的同时提供包括 分散在下层非磁性层上的粘合剂中的铁磁性粉末,其中上磁性层的平均厚度为1.0μm以下,下部非磁性层中的非磁性粉末包含(A)粒状无机粉末 平均粒径为0.01〜0.08μm,(B)平均粒径为0.01〜0.04μm的炭黑粉末,(C)平均粒径大于平均粒径的粉末成分 的粉末(A)和(B)。 磁记录介质具有良好的电磁特性,具有优异的运行耐久性,反复运行后边缘损伤小。
    • 6. 发明授权
    • Magnetic recording medium
    • 磁记录介质
    • US5385779A
    • 1995-01-31
    • US102834
    • 1993-08-06
    • Toshihiko MiuraHiroo Inaba
    • Toshihiko MiuraHiroo Inaba
    • G11B5/70C09D5/23G11B5/708G11B5/716G11B5/73G11B5/738G11B5/84G11B5/00
    • G11B5/7085G11B5/738Y10S428/90Y10T428/25Y10T428/256
    • A magnetic recording medium is disclosed, comprising a nonmagnetic support having thereon a lower nonmagnetic layer comprising nonmagnetic particles dispersed in a binder and further having on the lower layer an upper magnetic layer comprising ferromagnetic metal particles comprising alpha iron crystals dispersed in a binder, wherein said upper magnetic layer has diffraction dots attributable to the ferromagnetic metal particles present on the magnetic layer surface when analyzed by reflection high-energy electron diffraction, the number of said diffraction dots is from 5 to 15 when counted in a 100.degree. range on a circular arc of diffraction dots caused by diffraction on a (211) plane of said ferromagnetic metal particles present on the magnetic layer surface.
    • 公开了一种磁记录介质,其包括非磁性载体,其上具有包含分散在粘合剂中的非磁性颗粒的下非磁性层,并且还在下层上具有包含分散在粘合剂中的包含α铁分子的铁磁性金属颗粒的上磁性层,其中所述 当通过反射高能电子衍射分析时,上磁性层具有归因于存在于磁性层表面上的强磁性金属颗粒的衍射点,当在圆弧上在100度范围内计数时,所述衍射点的数量为5至15 由在磁性层表面上存在的所述强磁性金属颗粒的(211)面衍射引起的衍射点。
    • 7. 发明授权
    • Magnetic recording medium
    • 磁记录介质
    • US5370932A
    • 1994-12-06
    • US15293
    • 1993-02-08
    • Hiroo InabaMasatoshi TakahashiKazuaki TagaKeiji Mori
    • Hiroo InabaMasatoshi TakahashiKazuaki TagaKeiji Mori
    • G11B5/716C09D5/23C09D127/04C09D127/06C09D175/06G11B5/73B32B5/16G11B5/66
    • G11B5/716Y10T428/12931Y10T428/25Y10T428/257Y10T428/265
    • A magnetic recording medium excellent in electromagnetic properties is disclosed, which comprises a non-magnetic support and at least two magnetic layers formed thereon, each of which is mainly composed of a magnetic substance and a binder, in which a first magnetic layer (a lower layer) has a coercive force of 450 to 660 Oe, a residual magnetic flux density (Br) of 1,950 gausses or more and a thickness of 1.5 to 5 .mu.m, a second magnetic layer (an upper layer) has a coercive force of 700 to 900 Oe, a residual magnetic flux density of 1,500 gausses or more and a thickness of 1.5 to 3 .mu.m, the difference in coercive force between the first magnetic layer and the second magnetic layer is 150 to less than 300 Oe, the difference in residual magnetic flux density between the first magnetic layer and the second magnetic layer is within 600 gausses, and the total thickness of magnetic layers on the non-magnetic support is 3 to 7 .mu.m.
    • 公开了一种电磁特性优异的磁记录介质,其包括非磁性载体和形成在其上的至少两个磁性层,它们各自主要由磁性物质和粘合剂组成,其中第一磁性层 层)的矫顽力为450〜660Oe,剩余磁通密度(Br)为1,950高斯或以上,厚度为1.5〜5μm,第2磁性层(上层)的矫顽力为700 至900Oe,剩余磁通密度为1500高斯或更大,厚度为1.5至3μm,第一磁性层和第二磁性层之间的矫顽力差为150至小于300Oe, 第一磁性层和第二磁性层之间的剩余磁通密度在600高斯内,非磁性载体上的磁性层的总厚度为3〜7μm。
    • 8. 发明授权
    • Magnetic recording medium
    • 磁记录介质
    • US5034271A
    • 1991-07-23
    • US184539
    • 1988-04-21
    • Takahito MiyoshiHiroo InabaKazuko HanaiYasuyuki Yamada
    • Takahito MiyoshiHiroo InabaKazuko HanaiYasuyuki Yamada
    • G11B5/702G11B5/71
    • G11B5/7022G11B5/71Y10S428/90Y10T428/25Y10T428/257Y10T428/30Y10T428/31609
    • An improved magnetic recording medium comprises a nonmagnetic support and a magnetic recording layer which comprises a ferromagnetic powder, a lubricant and an abrasive dispersed in a binder comprising a specific polyurethane resin and a specific vinyl chloride copolymer at a ratio (polyurethane resin:vinyl chloride copolymer) in the range of 15:85 to 90:10. The polyurethane resin has a polar group such as --COOM, --SO.sub.3 M, --OSO.sub.3 M and --PO(OM').sub.2, wherein M is hydrogen or an alkali metal atom, and M' is hydrogen, an alkali metal atom or a lower hydrocarbon group, one polar group being contained per 53,000 to 100,000 of the number-average molecular weight of the resin, and the vinyl chloride copolymer has one of the above-mentioned polar group, one polar group unit being contained per 10,000 to 100,000 of the number-average molecular weight of the copolymer. The recording layer contains a fatty acid ester lubricant having a low melting point, a carbon black having an average particle size of 90-150 .mu.m, and/or a .alpha.-alumina having a small average particle size.
    • 改进的磁记录介质包括非磁性载体和磁记录层,其包含分散在粘合剂中的铁磁性粉末,润滑剂和磨料,所述粘合剂包含特定聚氨酯树脂和特定氯乙烯共聚物(聚氨酯树脂:氯乙烯共聚物 )在15:85至90:10的范围内。 聚氨酯树脂具有极性基团,例如-COOM,-SO 3 M,-OSO 3 M和-PO(OM')2,其中M是氢或碱金属原子,M'是氢,碱金属原子或低级烃 基,树脂的数均分子量为53,000至100,000,包含一个极性基团,并且氯乙烯共聚物具有上述极性基团之一,每10,000至100,000个数中包含一个极性基团单元 - 共聚物的平均分子量。 记录层含有低熔点的脂肪酸酯润滑剂,平均粒径为90-150μm的炭黑和/或平均粒度小的α-氧化铝。
    • 9. 发明授权
    • Magnetic recording medium
    • 磁记录介质
    • US4861674A
    • 1989-08-29
    • US238067
    • 1988-08-30
    • Hiroo InabaAkira UshimaruNobuyuki YamamotoNoburo HibinoKenzo Iwamoto
    • Hiroo InabaAkira UshimaruNobuyuki YamamotoNoburo HibinoKenzo Iwamoto
    • G11B5/706C09D5/23G11B5/73G11B5/84
    • G11B5/84G11B5/7305Y10S428/90
    • A magnetic recording medium is disclosed, which comprises a non-magnetic support having coated thereon a magnetic layer, said non-magnetic support being a film substantially composed of polyethylene terephthalate and having a cutting index (Z) of 6 or less as defined by equation (1):Z=383.3-2.76A-2000B+840.DELTA.n (1)wherein A is the haze value, B is the surface orientation coefficient represented by {(n.sub.MD +n.sub.TD)/2}-n.sub.ZD, n.sub.MD is the refractive index in the machine direction, n.sub.TD is the refractive index in the transverse direction, n.sub.ZD is the refractive index in the thickness direction, and .DELTA.n is the difference of the refractive indices represented by n.sub.MD -n.sub.TD ; and said magnetic layer has yield elongation (L) of 10% or lower and requires energy (E) of 1.0 kg/mm.sup.2 or less to reach the yield point.
    • 公开了一种磁记录介质,其包括其上涂覆有磁性层的非磁性载体,所述非磁性载体是基本上由聚对苯二甲酸乙二醇酯组成的膜,其切割指数(Z)为6或更小,如式 (1):Z = 383.3-2.76A-2000B + 840 DELTA n(1)其中A是雾度值,B是由{(nMD + nTD)/ 2} -nZD表示的表面取向系数,nMD是折射率 指数在纵向上,nTD是横向的折射率,nZD是厚度方向的折射率,并且DELTA n是由nMD-nTD表示的折射率的差; 所述磁性层的屈服伸长率(L)为10%以下,能量(E)为1.0kg / mm 2以下,达到屈服点。