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    • 6. 发明授权
    • Purification of cyanuric acid
    • 纯化氰尿酸
    • US4963674A
    • 1990-10-16
    • US454653
    • 1989-12-21
    • Robert W. MasonThomas C. Parker
    • Robert W. MasonThomas C. Parker
    • C07D251/32
    • C07D251/32
    • A process for the purification of crude cyanuric acid containing aminotriazine compounds as impurities which comprises digesting the crude cyanuric acid in an aqueous solution containing low concentrations of a mineral acid. The mineral acid is, for example sulfuric acid, nitric acid, hydrochloric acid, or phosphoric acid. The digestion is operated at a temperature in the range of from about 120.degree. C. and about 220.degree. C. and autogenous pressure using a stoichiometric ratio of sulfuric acid to aminotriazine compounds of less than 1, to produce a slurry of purified cyanuric acid in an acid depleted ammonium sulfate solution.Purification of cyanuric acid by the process of the present invention permits a substantial reduction in the amounts of acid used in the digestion and the base required for ammonia stripping and neutralization of the spent acid from the digestion. This provides significant cost savings in the digestion and waste treatment methods.
    • 用于纯化含有氨基三嗪化合物的粗制氰尿酸化合物作为杂质的方法,其包括在含有低浓度无机酸的水溶液中消化粗制氰尿酸。 无机酸是例如硫酸,硝酸,盐酸或磷酸。 消化在约120℃至约220℃的温度范围内操作,使用硫酸与氨基三嗪化合物的化学计量比小于1的自生压力,以产生纯化的三聚氰酸浆液 一种贫酸的硫酸铵溶液。 通过本发明的方法纯化氰尿酸可以显着降低消化中使用的酸的量和氨脱除所需的碱和从消化中分离废酸。 这在消化和废物处理方法中节省了大量成本。