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    • 2. 发明申请
    • ELECTROLYTES AND METAL HYDRIDE BATTERIES
    • 电解液和金属氢化物电池
    • WO2016154162A1
    • 2016-09-29
    • PCT/US2016/023503
    • 2016-03-22
    • BASF CORPORATIONMENG, TiejunYOUNG, KwoWONG, DianaNEI, Jean
    • MENG, TiejunYOUNG, KwoWONG, DianaNEI, Jean
    • H01M10/0568H01M4/52H01M4/58H01M10/05H01M10/0567H01M10/0569H01M10/30
    • H01M10/345H01M2300/0045
    • Electrolyte compositions comprising a) an ionic liquid and b) a protic acid and/or an organic solvent are suitable for use in electrochemical cells, e.g. metal hydride batteries. The electrolyte compositions may replace the currently employed 30% by weight aqueous KOH. Suitable protic acids include carboxylic acids, mineral acids, sulfonic acids and the like. Suitable organic solvents include organic carbonates, ethers, glymes, ortho esters, polyalkylene glycols, esters, lactones, glycols, formates, sulfones, sulfoxides, amides, alcohols, ketones, nitro solvents, nitrile solvents and combinations thereof. Present batteries may achieve a nominal open-circuit voltage of > 1.2 V (volts) and up to about 6 V. The electrolyte compositions allow enlargement of the electrochemical window, thus allowing the use of further cathode active materials. Further cathode active materials include transition metals and their oxides, hydroxides and fluorides; for example, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Y, Zr, Nb, Mo, Tc, Ru, Rh, Pd, Ag, Cd, Lu, Hf, Ta, W, Re, Os, Ir, Pt and Au and their oxides, hydroxides, oxide/hydroxides and fluorides.
    • 包含a)离子液体和b)质子酸和/或有机溶剂的电解质组合物适用于电化学电池,例如, 金属氢化物电池。 电解质组合物可以代替目前使用的30重量%KOH水溶液。 合适的质子酸包括羧酸,无机酸,磺酸等。 合适的有机溶剂包括有机碳酸酯,醚,甘醇二酯,原酸酯,聚亚烷基二醇,酯,内酯,二醇,甲酸酯,砜,亚砜,酰胺,醇,酮,硝基溶剂,腈溶剂及其组合。 现有电池可以达到> 1.2V(伏特)和高达约6V的标称开路电压。电解质组合物允许扩大电化学窗口,从而允许使用另外的阴极活性材料。 其它阴极活性材料包括过渡金属及其氧化物,氢氧化物和氟化物; 例如Sc,Ti,V,Cr,Mn,Fe,Co,Ni,Cu,Zn,Y,Zr,Nb,Mo,Tc,Ru,Rh,Pd,Ag,Cd,Lu,Hf,Ta,W ,Re,Os,Ir,Pt和Au及其氧化物,氢氧化物,氧化物/氢氧化物和氟化物。
    • 9. 发明申请
    • ELECTROLYTES AND METAL HYDRIDE BATTERIES
    • 电解液和金属氢化物电池
    • WO2016077303A1
    • 2016-05-19
    • PCT/US2015/059883
    • 2015-11-10
    • BASF CORPORATION
    • YOUNG, KwoNEI, JeanWONG, DianaLI, WentaoWANG, Lixin
    • H01M10/34H01M10/26H01M4/38
    • H01M10/345H01M4/383H01M10/26H01M2300/0014H01M2300/0017
    • A metal hydride battery comprising an electrolyte composition comprising an ionic compound selected from the group consisting of protic acids, protic ammonium compounds, protic oxonium compounds, aprotic ammonium compounds, aprotic oxonium compounds, aprotic phosphonium compounds and alkali or alkali earth metal salts; or comprising an ionic compound selected from the group consisting of alkali or alkali earth metal hydroxides and alkali or alkali earth metal alkoxides and an organic solvent; or comprising an alkali metal hydroxide, water and one or more further components selected from the group consisting of organic solvents, further ionic compounds and additives; or comprising an ionic compound selected from the group consisting of carboxylate compounds and carboxylic acids. Ionic compounds include ionic liquids and salts. Metal hydride batteries comprising certain electrolyte compositions have a nominal open-circuit voltage of from about 1.5 V to about 5.0 V.
    • 一种金属氢化物电池,其包含电解质组合物,所述电解质组合物包含选自质子酸,质子铵化合物,质子氧化合物,非质子性铵化合物,非质子性氧化合物,非质子鏻化合物和碱金属或碱土金属盐的离子化合物; 或包含选自碱金属或碱土金属氢氧化物和碱金属或碱土金属醇盐和有机溶剂的离子化合物; 或包含碱金属氢氧化物,水和一种或多种选自有机溶剂,其它离子化合物和添加剂的其它组分; 或包含选自羧酸酯化合物和羧酸的离子化合物。 离子化合物包括离子液体和盐。 包含某些电解质组合物的金属氢化物电池具有约1.5V至约5.0V的标称开路电压。