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1. 发明申请

WO2005005319A3 CATHODE MATERIAL FOR LITHIUM BATTERY 审中-公开
标题翻译：锂电池阴极材料
公开(公告)号：WO2005005319A3
公开(公告)日：2005-06-02
申请号：PCT/US2004016303
申请日：2004-05-24
申请人： GEN MOTORS CORP
发明人： NAZRI GHOLAM-ABBAS , GARABEDIAN GREGORY CHARLES
IPC分类号： C01D15/00 , C01G20060101 , C01G1/02 , C01G53/00
CPC分类号： C01G53/42 , C01P2002/52 , C01P2002/54 , C01P2002/72 , C01P2002/74 , C01P2002/76 , C01P2002/88 , C01P2006/12 , C01P2006/40
摘要： A method is disclosed for synthesizing a crystalline metal oxide powder material containing two or more uniformly distributed metal elements. Crystalline, water containing, oxygen containing inorganic acid salts of the metals are heated to liquefy the salts. The apparent solution contains a uniform mixture of the metal elements. The water is removed from the liquid and the resulting powder calcined in air to decompose the acid salts to a mixed metal crystalline oxide. The method is particularly useful to make doped LiNi02 type crystals using hydrated nitrate or nitrite salts of Li, Ni and the dopant elements. Examples of useful salts are LiN03-H2O, Ni(N03)2 6H20, Co(N03)2 6H2O, Al(NO3)3 9H20, and Mg(N03)2 6H20.
摘要翻译：公开了一种合成含有两种或更多种均匀分布的金属元素的结晶金属氧化物粉末材料的方法。将含结晶水的金属的含氧无机酸盐加热以液化盐。表观溶液含有金属元素的均匀混合物。从液体中除去水并将所得粉末在空气中煅烧以将酸盐分解成混合的金属结晶氧化物。该方法特别适用于使用Li，Ni和掺杂元素的水合硝酸盐或亚硝酸盐制造掺杂的LiNiO 2型晶体。有用的盐的实例是LiNO 3·H 2 O，Ni（NO 3）2·6H 2 O，Co（NO 3）2·6H 2 O，Al（NO 3）3·9H 2 O和Mg（NO 3）2·6H 2 O.

2. 发明公开

EP1658235A4 CATHODE MATERIAL FOR LITHIUM BATTERY 审中-公开
标题翻译：锂电池材料阴极
公开(公告)号：EP1658235A4
公开(公告)日：2011-03-16
申请号：EP04753175
申请日：2004-05-24
申请人： GEN MOTORS CORP
发明人： NAZRI GHOLAM-ABBAS , GARABEDIAN GREGORY CHARLES
IPC分类号： C01D15/00 , C01G20060101 , C01G1/02 , C01G53/00
CPC分类号： C01G53/42 , C01P2002/52 , C01P2002/54 , C01P2002/72 , C01P2002/74 , C01P2002/76 , C01P2002/88 , C01P2006/12 , C01P2006/40

3. 发明专利

DE69301995T2 未知
公开(公告)号：DE69301995T2
公开(公告)日：1996-08-08
申请号：DE69301995
申请日：1993-09-14
申请人： GEN MOTORS CORP
发明人： WITHERSPOON ROMEO RICHARD , GARABEDIAN GREGORY CHARLES
IPC分类号： H01M4/20 , H01M4/56 , H01M4/62
摘要： In a preferred method, an electrode (10) for a lead-acid battery is prepared in a new continuous process without the conventional curing step. The general procedure for preparing electrodes (10) according to the invention includes preparing a mixture (paste) comprising an active material precursor and an inhibitor. The active material precursor includes lead oxides having at least 10% by weight lead oxide in the form of Pb3O4 (red lead), and a BET surface area of at least about 0.8 m /gram; desirably about 1.00 to 1.50 m /gram and preferably about 1.0 to 1.25 m /gram. The inhibitor prevents formation of tribasic lead sulphate and tetrabasic lead sulphate from the precursor material, except at elevated temperature and consists of hydroxyl-containing organic or inorganic compounds, such as glucose, fructose, sorlitol. The paste is applied to electrode grids (15) and is reacted at elevated temperatures for between about 5 and about 30 minutes, to form the active material (30) of the electrode (10) for both positive and negative electrodes. The electrodes (10) are then assembled into batteries and charged. Negative electrodes differ from the positive electrodes, mainly in the additives used.

4. 发明专利

DE69301995D1 未知
公开(公告)号：DE69301995D1
公开(公告)日：1996-05-02
申请号：DE69301995
申请日：1993-09-14
申请人： GEN MOTORS CORP
发明人： WITHERSPOON ROMEO RICHARD , GARABEDIAN GREGORY CHARLES
IPC分类号： H01M4/20 , H01M4/56 , H01M4/62
摘要： In a preferred method, an electrode (10) for a lead-acid battery is prepared in a new continuous process without the conventional curing step. The general procedure for preparing electrodes (10) according to the invention includes preparing a mixture (paste) comprising an active material precursor and an inhibitor. The active material precursor includes lead oxides having at least 10% by weight lead oxide in the form of Pb3O4 (red lead), and a BET surface area of at least about 0.8 m /gram; desirably about 1.00 to 1.50 m /gram and preferably about 1.0 to 1.25 m /gram. The inhibitor prevents formation of tribasic lead sulphate and tetrabasic lead sulphate from the precursor material, except at elevated temperature and consists of hydroxyl-containing organic or inorganic compounds, such as glucose, fructose, sorlitol. The paste is applied to electrode grids (15) and is reacted at elevated temperatures for between about 5 and about 30 minutes, to form the active material (30) of the electrode (10) for both positive and negative electrodes. The electrodes (10) are then assembled into batteries and charged. Negative electrodes differ from the positive electrodes, mainly in the additives used.

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