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    • 1. 发明申请
    • PROCESS FOR ENHANCING THE KINETICS OF HYDROGENATION/DEHYDROGENATION OF MA1H4 AND MBH4 METAL HYDRIDES FOR REVERSIBLE HYDROGEN STORAGE
    • 用于增强MA1H4和MBH4金属氢化物氢化反应动力学的方法,用于可逆氢储存
    • WO03045543A3
    • 2003-08-28
    • PCT/US0236913
    • 2002-11-18
    • GEN MOTORS CORP
    • BOUZIANE YEBKANAZRI GHOLAM-ABBAS
    • C01B3/00C01B6/24C01B3/04
    • C01B3/0005C01B6/24Y02E60/324
    • A process for enhancing the kinetics of hydrogenation/dehydrogenation of complex chemical hydrides using mechanomixing and/or mechanomilling. The system (10) includes a hydrogen source (12), from which plumbing (14) may be provided to a hydrogenation/dehydrogenation reaction vessel (16). The reaction vessel (16) receives a complex chemical hydride such as a hydride having the formula MBH4 where M is at least one selected from the group consisting of Na, Li and K, and where B is at least one selected from the group consisting of the elements in the third column of the periodic table (B, Al, Ga, In, Tl, Sc, Y, La, Ac). The complex chemical hydride is preferably in a solid phrase, but may be wet or in a liquid phase. The reaction vessel (16) is constructed and arranged to receive one or more mixing and/or milling devices (28), (29). The system includes a heating element (30) to supply heat to the complex chemical hydride to decompose the same.
    • 使用机械混合和/或机械加工增强复合化学氢化物氢化/脱氢动力学的方法。 系统(10)包括氢源(12),管道(14)可以从氢源(12)提供给氢化/脱氢反应容器(16)。 反应容器(16)接收复合化学氢化物,例如具有式MBH4的氢化物,其中M是选自Na,Li和K中的至少一种,其中B是选自由以下组成的组中的至少一种: 周期表第三列(B,Al,Ga,In,Tl,Sc,Y,La,Ac)中的元素。 复合化学氢化物优选为固体短语,但可以是湿的或液相的。 反应容器(16)被构造和布置成容纳一个或多个混合和/或研磨装置(28),(29)。 该系统包括加热元件(30),以向复合化学氢化物供应热量以分解它。