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1. 发明专利

JPS61207409A MANUFACTURE OF PENDANT ISOCYANATE GROUP-CONTAINING POLYMER 失效
公开(公告)号：JPS61207409A
公开(公告)日：1986-09-13
申请号：JP4952286
申请日：1986-03-06
申请人： GOODYEAR TIRE & RUBBER
发明人： SMITH ROBERT ALAN , PARKER DANE KENTON , COLVIN HOWARD ALLEN , WEINSTEIN ARTHUR HOWARD , PATTERSON DENNIS BRUCE , COTTMAN KIRKWOOD STORER
IPC分类号： C08F12/00 , C08F2/22 , C08F2/24 , C08F12/26 , C08F212/14 , C08F220/42 , C08F220/44 , C08F236/10 , C08G18/72

2. 发明公开

EP0805823A4 VAPOR PHASE SYNTHESIS OF RUBBERY POLYMERS 失效
标题翻译：橡胶聚合物在蒸汽相合成
公开(公告)号：EP0805823A4
公开(公告)日：1998-05-06
申请号：EP96930494
申请日：1996-08-02
申请人： GOODYEAR TIRE & RUBBER
发明人： CALDERON NISSIM , CASTNER KENNETH FLOYD , COLVIN HOWARD ALLEN , MUSE JOEL JR
IPC分类号： B01J8/10 , B01J8/24 , B01J8/36 , C08F2/06 , C08F2/34 , C08F4/64 , C08F4/70 , C08F36/04 , C08F136/04 , C08F136/06 , C08F136/08 , G09F13/28 , G09F21/06
CPC分类号： B01J8/1827 , B01J8/10 , B01J8/24 , B01J8/36 , B01J2208/00256 , B01J2208/00274 , B01J2219/00108 , B01J2219/182 , C08F36/04 , C08F136/04 , C08F136/06 , C08F136/08 , G09F13/28 , G09F21/06 , Y10S526/901 , Y10S526/903 , C08F2/34 , C08F4/7098 , C08F4/6421
摘要： By utilizing the vapor phase polymerisation techniques of the present invention, numerous distinct and highly beneficial advantages are realized. For instance, cis-1,4-polybutadiene and high cis-1,4-polybutadiene rubber having a consistent and controllable molecular weight can be easily and practically prepared without utilizing a solvent. The supported catalyst is mixed prior to its introduction into the reaction zone. The supported, preformed catalyst system is introduced into the reaction zone (11) by feeding the catalyst into the reactor via catalyst feed line (27) at point (28) which is in the upper portion of the reaction zone.

3. 发明专利

DE69917959T2 未知
公开(公告)号：DE69917959T2
公开(公告)日：2005-06-30
申请号：DE69917959
申请日：1999-03-10
申请人： GOODYEAR TIRE & RUBBER
发明人： COLVIN HOWARD ALLEN , SENYEK MICHAEL LESLIE
IPC分类号： B60C1/00 , C08F2/00 , C08F2/22 , C08F212/08 , C08F236/10 , C08L9/06
摘要： This invention discloses an emulsion styrene-butadiene rubber (SBR) that can be employed in manufacturing tire tread formulations that have rolling resistance and treadwear characteristics that are similar to those made with solution SBR but with improved traction characteristics. Thus, the emulsion SBR of this invention is superior in many respects for use in tire tread compounds to conventional solution SBR and conventional emulsion SBR. This invention more specifically discloses a styrene-butadiene rubber composition which is comprised of repeat units which are derived from styrene and 1,3-butadiene, wherein the styrene-butadiene rubber composition has a number average molecular weight as determined by thermal field flow fractionation which is within the range of about 50,000 to 150,000, and wherein the styrene-butadiene rubber has a light scattering to refractive index ratio which is within the range of 1.8 to 3.9. The subject invention further reveals a styrene-butadiene rubber composition which is comprised of repeat units which are derived from styrene and 1,3-butadiene, wherein a plot of log frequency versus storage modulus of the styrene-butadiene rubber composition crosses over a plot of log frequency versus loss modulus of the styrene-butadiene rubber composition at a log frequency within the range of 0.001 radians per second to 100 radians per second when conducted at 120 DEG C using parallel plate geometry in the dynamic oscillation frequency sweep of the styrene-butadiene rubber.

4. 发明专利

DE69917959D1 未知
公开(公告)号：DE69917959D1
公开(公告)日：2004-07-22
申请号：DE69917959
申请日：1999-03-10
申请人： GOODYEAR TIRE & RUBBER
发明人： COLVIN HOWARD ALLEN , SENYEK MICHAEL LESLIE
IPC分类号： B60C1/00 , C08F2/00 , C08F2/22 , C08F212/08 , C08F236/10 , C08L9/06
摘要： This invention discloses an emulsion styrene-butadiene rubber (SBR) that can be employed in manufacturing tire tread formulations that have rolling resistance and treadwear characteristics that are similar to those made with solution SBR but with improved traction characteristics. Thus, the emulsion SBR of this invention is superior in many respects for use in tire tread compounds to conventional solution SBR and conventional emulsion SBR. This invention more specifically discloses a styrene-butadiene rubber composition which is comprised of repeat units which are derived from styrene and 1,3-butadiene, wherein the styrene-butadiene rubber composition has a number average molecular weight as determined by thermal field flow fractionation which is within the range of about 50,000 to 150,000, and wherein the styrene-butadiene rubber has a light scattering to refractive index ratio which is within the range of 1.8 to 3.9. The subject invention further reveals a styrene-butadiene rubber composition which is comprised of repeat units which are derived from styrene and 1,3-butadiene, wherein a plot of log frequency versus storage modulus of the styrene-butadiene rubber composition crosses over a plot of log frequency versus loss modulus of the styrene-butadiene rubber composition at a log frequency within the range of 0.001 radians per second to 100 radians per second when conducted at 120 DEG C using parallel plate geometry in the dynamic oscillation frequency sweep of the styrene-butadiene rubber.

5. 发明专利

GB2370575B Modification of asphalt cement 未知
公开(公告)号：GB2370575B
公开(公告)日：2004-06-02
申请号：GB0127259
申请日：2001-11-13
申请人： GOODYEAR TIRE & RUBBER
发明人： COLVIN HOWARD ALLEN , MOORE EDWIN GRESHAM
IPC分类号： C08J11/22 , C08L9/00 , C08L95/00 , E01C7/26 , C04B26/26
摘要： This invention is based upon the discovery that a polydiene rubber that is comprised of repeat units that are derived from a conjugated diene monomer and sulfur can be used to improved the force ductility, elastic recovery, toughness and tenacity of asphalt cement. The polydiene rubber that is comprised of repeat units that are derived from a conjugated diene monomer and sulfur also exhibits excellent compatibility with asphalt. The repeat units in the polydiene rubber that are derived from sulfur are in the backbone of the polymer. These repeat units that are derived from sulfur typically contain from 2 to 8 sulfur atoms (-Sn-). The subject invention more specifically relates to a modified asphalt cement which is comprised of (i) from about 90 weight percent to about 99 weight percent asphalt; (ii) from about 1 weight percent to about 10 weight percent of a polydiene rubber that is comprised of repeat units that are derived from a conjugated diene monomer and sulfur. The present invention also reveals an asphalt concrete which is comprised of (A) from about 90 weight percent to about 99 weight percent of an aggregate and (B) from about 1 weight percent to about 10 weight percent of a modified asphalt cement which is comprised of (i) from about 90 weight percent to about 99 weight percent asphalt; (ii) from about 1 weight percent to about 10 weight percent of a polydiene rubber that is comprised of repeat units that are derived from a conjugated diene monomer and sulfur. The present invention also discloses a process for preparing a modified asphalt cement which comprises (1) blending from about 1 to about 10 parts by weight of a polydiene rubber that is comprised of repeat units that are derived from a conjugated diene monomer and sulfur into from about 90 to about 99 parts by weight of asphalt at a temperature which is within the range of about 130° to about 230° C. to produce a polymer-asphalt blend; and (2) mixing from about 0.1 to about 3 parts by weight of sulfur into the polymer-asphalt blend to produce the modified asphalt cement.

6. 发明专利

BR0200672A 未知
公开(公告)号：BR0200672A
公开(公告)日：2002-12-03
申请号：BR0200672
申请日：2002-03-08
申请人： GOODYEAR TIRE & RUBBER
发明人： THIELEN GEORGES MARCEL VICTOR , COLVIN HOWARD ALLEN
IPC分类号： B60C1/00 , C08F236/10 , C08K5/548 , C08L9/06 , C08L15/00

7. 发明专利

GB2370575A Modified asphalt cement composition 未知
公开(公告)号：GB2370575A
公开(公告)日：2002-07-03
申请号：GB0127259
申请日：2001-11-13
申请人： GOODYEAR TIRE & RUBBER
发明人： COLVIN HOWARD ALLEN , MOORE EDWIN GRESHAM
IPC分类号： C08J11/22 , C08L9/00 , C08L95/00 , E01C7/26 , C04B26/26
摘要： A modified asphalt cement is comprised of (i) 90 to 99 weight percent asphalt; (ii) 1 to 10 weight percent of a polydiene rubber comprised of repeat units derived from a conjugated diene monomer and sulfur. Also claimed is an asphalt concrete comprised of (A) 90 to 99 weight percent of an aggregate and (B) 1 to 10 weight percent of a modified asphalt cement comprised of (i) 90 to 99 weight percent asphalt; (ii) 1 to 10 weight percent of a polydiene rubber comprised of repeat units derived from a conjugated diene monomer and sulfur. Further disclosed is a process for preparing a modified asphalt cement which comprises (1) blending 1 to 10 parts by weight of a polydiene rubber comprised of repeat units derived from a conjugated diene monomer and sulfur into 90 to 99 parts by weight of asphalt at a temperature within the range of 130{ to 230{C to produce a polymer-asphalt blend; and (2) mixing 0.1 to 3 parts by weight of sulfur into the blend to produce the modified asphalt cement.

8. 发明专利

BR9900563A 未知
公开(公告)号：BR9900563A
公开(公告)日：2000-02-01
申请号：BR9900563
申请日：1999-02-09
申请人： GOODYEAR TIRE & RUBBER
发明人： STEININGER CLITES JEAN , COLVIN HOWARD ALLEN , FIEDLER RONALD DAVID
IPC分类号： C08F2/06 , C08F297/04 , C08L95/00 , C08L35/00
摘要： This invention discloses a process for synthesizing a styrene-butadiene polymer which comprises the steps of: (1) continuously charging 1,3-butadiene monomer, an organolithium compound, a polar modifier and an organic solvent into a first polymerization zone, (2) allowing the 1,3-butadiene monomer to polymerize in said first polymerization zone to a conversion of at least 90 percent to produce a living polymer solution, (3) continuously withdrawing said living polymer solution from said first polymerization zone, (4) continuously charging divinyl benzene and the living polymer solution being withdrawn from the first polymerization zone into a second polymerization zone, (5) allowing the divinyl benzene monomer to react with the living polybutadiene chains in said second polymerization zone to produce a solution of living divinylbenzene modified butadiene polymer, (6) continuously withdrawing the solution of said divinylbenzene modified butadiene polymer from the second polymerization zone, (7) continuously charging styrene and the living divinylbenzene modified butadiene polymer being withdrawn from the second polymerization zone into a third polymerization zone, (8) allowing the styrene to polymerize in the third polymerization zone to produce a solution of styrene-butadiene polymer having a number average molecular weight which is within the range of 30,000 to 85,000 and (9) continuously withdrawing the solution of styrene-butadiene polymer from the third polymerization zone.

9. 发明专利

FR2774992A1 未知
公开(公告)号：FR2774992A1
公开(公告)日：1999-08-20
申请号：FR9901571
申请日：1999-02-10
申请人： GOODYEAR TIRE & RUBBER
发明人： STEININGER CLITES JEAN , COLVIN HOWARD ALLEN , FIEDLER RONALD DAVID
IPC分类号： C08F2/06 , C08F297/04 , C08L95/00 , C08F236/06 , C04B26/26
摘要： This invention discloses a process for synthesizing a styrene-butadiene polymer which comprises the steps of: (1) continuously charging 1,3-butadiene monomer, an organolithium compound, a polar modifier and an organic solvent into a first polymerization zone, (2) allowing the 1,3-butadiene monomer to polymerize in said first polymerization zone to a conversion of at least 90 percent to produce a living polymer solution, (3) continuously withdrawing said living polymer solution from said first polymerization zone, (4) continuously charging divinyl benzene and the living polymer solution being withdrawn from the first polymerization zone into a second polymerization zone, (5) allowing the divinyl benzene monomer to react with the living polybutadiene chains in said second polymerization zone to produce a solution of living divinylbenzene modified butadiene polymer, (6) continuously withdrawing the solution of said divinylbenzene modified butadiene polymer from the second polymerization zone, (7) continuously charging styrene and the living divinylbenzene modified butadiene polymer being withdrawn from the second polymerization zone into a third polymerization zone, (8) allowing the styrene to polymerize in the third polymerization zone to produce a solution of styrene-butadiene polymer having a number average molecular weight which is within the range of 30,000 to 85,000 and (9) continuously withdrawing the solution of styrene-butadiene polymer from the third polymerization zone.

10. 发明专利

AU6951096A Vapor phase synthesis of rubbery polymers 未知
公开(公告)号：AU6951096A
公开(公告)日：1997-03-19
申请号：AU6951096
申请日：1996-08-02
申请人： GOODYEAR TIRE & RUBBER
发明人： CALDERON NISSIM , CASTNER KENNETH FLOYD , COLVIN HOWARD ALLEN , MUSE JOEL JR
IPC分类号： B01J8/10 , B01J8/24 , B01J8/36 , C08F2/06 , C08F2/34 , C08F4/64 , C08F4/70 , C08F36/04 , C08F136/04 , C08F136/06 , C08F136/08 , G09F13/28 , G09F21/06
摘要： By utilizing the vapor phase polymerization techniques of the present invention, numerous distinct and highly beneficial advantages are realized. For instance, cis-1,4-polyisoprene rubber and high cis-1,4-polybutadiene rubber having a consistent and controllable molecular weight can be easily and practically prepared without utilizing a solvent. The subject invention more specifically discloses a method for vapor phase polymerizing isoprene into cis-1,4-polyisoprene in a process comprising the steps of: (1) charging into a reaction zone said isoprene and a preformed catalyst system which is made by reacting an organoaluminum compound with titanium tetrachloride, preferably in the presence of at least one ether; wherein the isoprene is maintained in the vapor phase in said reaction zone by a suitable combination of temperature and pressure; (2) allowing said isoprene to polymerize into cis-1,4-polyisoprene at a temperature within the range of about 35 DEG C. to about 70 DEG C.; and (3) withdrawing said cis-1,4-polyisoprene from said reaction zone. It has been determined that gel formation can be reduced by conducting the polymerization of isoprene monomer in the presence of a diarylamine, such as para-styrenated diphenylamine.

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