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    • 5. 发明授权
    • Transparent thermoplastic polyurethanes having low haze and good processability, methods of making the same, and uses therefor
    • 具有低雾度和良好加工性的透明热塑性聚氨酯,其制备方法及其用途
    • US08497341B2
    • 2013-07-30
    • US12358356
    • 2009-01-23
    • Henricus PeerlingsFaisal ShafiqMarkus Broich
    • Henricus PeerlingsFaisal ShafiqMarkus Broich
    • C08G18/32C08G18/73
    • C08G18/3215C08G18/3206C08G18/44C08G18/664C08G18/6674C08G18/73
    • Light-stable, thermoplastic polyurethanes with good processability and having an ASTM D-1003 haze value of less than 10%, the polyurethane prepared by a process comprising: reacting: (a) a diisocyanate component comprising 1,6-hexamethylene diisocyanate; (b) a chain extension component consisting of (b1) 1,4-di(β-hydroxyethyl)hydroquinone and (b2) at least one chain extender selected from the group consisting of diols having a 2 or 3 carbon atom chain length between the two OH groups, in a molar ratio of chain extender (b1) to chain extender (b2) of 10:1 to 1:4; and (c) at least one polyol component having a number average molecular weight of 450 to 10000 g/mol, and an average number of Zerewitinoff-active hydrogen atoms of at least 1.8 to at most 3.0; wherein the ratio of isocyanate groups in component (a) to isocyanate-reactive groups in components (b) and (c) is 0.9:1 to 1.1:1.
    • 具有良好加工性并且具有小于10%的ASTM D-1003雾度值的轻稳定的热塑性聚氨酯,通过包括以下方法制备的聚氨酯制备:(a)包含1,6-六亚甲基二异氰酸酯的二异氰酸酯组分; (b)由(b1)1,4-二(β-羟乙基)氢醌和(b2)至少一种增链剂组成的链延伸组分,所述链增链剂选自二者或二者之间具有2或3个碳原子链长的二醇 两个OH基,扩链剂(b1)与扩链剂(b2)的摩尔比为10:1至1:4; 和(c)数均分子量为450〜10000g / mol,Zerewitinoff活性氢原子的平均数为至少1.8〜3.0的至少一种多元醇成分, 其中组分(a)中异氰酸酯基与组分(b)和(c)中异氰酸酯反应性基团的比例为0.9:1至1.1:1。
    • 6. 发明申请
    • THERMOPLASTIC POLYURETHANES AND THEIR USE
    • 热塑性聚氨酯及其用途
    • US20090192274A1
    • 2009-07-30
    • US12358360
    • 2009-01-23
    • Henricus PeerlingsJuergen WinklerFaisal ShafiqMarkus Broich
    • Henricus PeerlingsJuergen WinklerFaisal ShafiqMarkus Broich
    • C08L75/04
    • C08G18/4018C08G18/3206C08G18/485C08G18/664C08G18/6674C08L75/04C08L75/06C08L83/00
    • Thermoplastic polyurethanes and molding compositions containing the same having improved surface resistance (writing and scratch resistance) and good industrial processability, and the use thereof, such polyurethanes prepared by reacting: (a) one or more organic diisocyanates; (b) a chain extender comprising at least one low molecular weight polyol having on average at least 1.8 and not more than 3.0 Zerewitinoff-active hydrogen atoms and a number-average molecular weight Mn of 60 to 400 g/mol; and (c) at least one polyol component having a number-average molecular weight Mn of 450 to 10,000 g/mol and on average from at least 1.8 to not more than 3.0 Zerewitinoff-active hydrogen atoms; wherein the ratio of the number of isocyanate groups in component (a) to the number of isocyanate-reactive groups in components (b) and (c) is 0.9:1 to 1.1:1; in the presence of (d) a mixture of polyorganosiloxanes of the general formula (R2SiO)n, in an amount of 0.4 to 10 wt. % based on the thermoplastic polyurethane, wherein each R independently represents an organic hydrocarbon radical having 1 to 27 carbon atoms which can be linear and/or branched, and n represents an integer of 3 to 6000, wherein the mixture consists of (d1) 0.2 to 2 wt. %, based on the thermoplastic polyurethane, of one or more polyorganosiloxanes (R2SiO)n wherein n=3 to 300 and (d2) 0.2 to 8 wt. %, based on the thermoplastic polyurethane, of one or more polyorganosiloxanes (R2SiO)n wherein n=1000 to 6000.
    • 热塑性聚氨酯和含有该组合物的模塑组合物具有改善的表面电阻(书写和耐刮擦性)和良好的工业加工性能,以及其用途,通过以下方法制备的聚氨酯:(a)一种或多种有机二异氰酸酯; (b)含有至少一种至少一种低分子量多元醇的扩链剂,其平均具有至少1.8并且不超过3.0的齐维诺芬 - 活性氢原子,数均分子量Mn为60-400g / mol; 和(c)至少一种数均分子量Mn为450〜10,000g / mol,平均从至少1.8以上3.0以下的三烯乙基活性氢原子的多元醇成分; 其中组分(a)中异氰酸酯基数与组分(b)和(c)中异氰酸酯反应性基团数目的比例为0.9:1至1.1:1; 在(d)通式(R2SiO)n的聚有机硅氧烷的混合物存在下,其量为0.4-10wt。 %,其中每个R独立地表示可以是直链和/或支链的具有1至27个碳原子的有机烃基,n表示3至6000的整数,其中该混合物由(d1)0.2 至2重量% %,基于热塑性聚氨酯,一种或多种聚有机硅氧烷(R2SiO)n,其中n = 3至300和(d2)0.2至8wt。 %,基于热塑性聚氨酯,一种或多种聚有机硅氧烷(R2SiO)n,其中n = 1000至6000。