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    • 1. 发明授权
    • Highly homogeneous spinel Li.sub.1+X Mn.sub.2-X O.sub.4 intercalation
compounds and method for preparing same
    • 高均相尖晶石Li1 + XMn2-XO4插层化合物及其制备方法
    • US5792442A
    • 1998-08-11
    • US665396
    • 1996-06-18
    • Vesselin ManevTitus Faulkner
    • Vesselin ManevTitus Faulkner
    • C01G45/00H01M4/131H01M4/50H01M4/505H01M4/62H01M10/052H01M10/36C01G45/12
    • H01M4/505C01G45/1242H01M4/131H01M4/623C01P2002/32C01P2002/72C01P2002/77C01P2006/40H01M10/052Y02P70/54
    • A novel method of preparing a spinel Li.sub.1+X Mn.sub.2-X O.sub.4 intercalation compound with low lattice distortion and a highly ordered and homogeneous structure for 4 V secondary lithium and lithium ion cells is provided. The method of preparing the spinel Li.sub.1+X Mn.sub.2-X O.sub.4 intercalation compound comprises mixing at least one manganese compound with at least one lithium compound and firing the mixture at three different temperature ranges with corresponding gas flow rates to form the spinel Li.sub.1+X Mn.sub.2-X O.sub.4 intercalation compounds. The spinel Li.sub.1+X Mn.sub.2-X O.sub.4 intercalation compounds have a mean X value of between about 0.01 and 0.05 and a full width at half maximum of the x-ray diffraction peaks at a diffraction angle 2.theta. of planes (400) and (440) using CuK.alpha..sub.1 rays of between about 0.10.degree. and 0.15.degree.. The spinel Li.sub.1+X Mn.sub.2-X O.sub.4 intercalation compounds may be used in the positive electrodes of secondary lithium and lithium ion cells to provide cells having high specific capacities and long cycling lives.
    • 提供了一种制备具有低晶格畸变的尖晶石Li1 + XMn2-XO4插层化合物和用于4 V二次锂和锂离子电池的高度有序和均匀结构的新方法。 制备尖晶石Li1 + XMn2-XO4插层化合物的方法包括将至少一种锰化合物与至少一种锂化合物混合,并在三种不同的温度范围内以相应的气体流速烧制该混合物以形成尖晶石Li1 + XMn2-XO4插层 化合物。 尖晶石Li1 + XMn2-XO4插层化合物的平均X值在平面(400)和(440)的衍射角2θ处的x射线衍射峰的平均X值为大约0.01和0.05之间的全宽,使用 约0.10°至0.15°之间的CuKα1射线。 尖晶石Li1 + XMn2-XO4插层化合物可用于二次锂离子电池和锂离子电池的正电极,以提供具有高比容量和长循环寿命的电池。
    • 2. 发明授权
    • Highly homogeneous spinel Li.sub.1+X Mn.sub.2-X O.sub.4+Y intercalation
compounds and method for preparing same
    • 高均相尖晶石Li1 + XMn2-XO4 + Y插层化合物及其制备方法
    • US5766800A
    • 1998-06-16
    • US867160
    • 1997-06-02
    • Vesselin ManevTitus Faulkner
    • Vesselin ManevTitus Faulkner
    • C01B31/02C01G45/00H01M4/131H01M4/50H01M4/505H01M10/052H01M10/36C01G45/12
    • H01M4/505C01G45/1242H01M4/131C01P2002/32C01P2002/72C01P2002/74C01P2006/12C01P2006/40H01M10/052
    • A novel method of preparing a spinel Li.sub.1+X Mn.sub.2-X O.sub.4+Y intercalation compound with low lattice distortion and a highly ordered and homogeneous structure for 4 V secondary lithium and lithium ion cells is provided. The method of preparing the spinel Li.sub.1+X Mn.sub.2-X O.sub.4+Y intercalation compound comprises providing a spinel Li.sub.1+X Mn.sub.2-X O.sub.4 intercalation compound having a lithium to manganese mole ratio of between about 1.02:2 and 1.1:2 and firing the spinel at different temperature ranges with corresponding gas flow rates to form the spinel Li.sub.1+X Mn.sub.2-X O.sub.4+Y intercalation compounds. The spinel Li.sub.1+X Mn.sub.2-X O.sub.4+Y intercalation compounds have a mean X value of between about 0.01 and 0.05, a mean Y value of between about -0.02 and 0.04 and a full width at half maximum of the x-ray diffraction peaks at a diffraction angle 2.theta. of planes (400) and (440) using CuK.alpha..sub.1 rays of between about 0.08.degree. and 0.13.degree.. The spinel Li.sub.1+X Mn.sub.2-X O.sub.4+Y intercalation compounds may be used in the positive electrodes of secondary lithium and lithium ion cells to provide cells having high specific capacities and long cycling lives.
    • 提供了一种制备具有低晶格畸变的尖晶石Li1 + XMn2-XO4 + Y插层化合物和用于4 V二次锂和锂离子电池的高度有序和均匀结构的新方法。 制备尖晶石Li1 + XMn2-XO4 + Y插层化合物的方法包括提供锂/锰摩尔比在约1.02:2至1.1:2之间的尖晶石Li1 + XMn2-XO4插层化合物,并在不同温度下烧制尖晶石 范围与相应的气体流速形成尖晶石Li1 + XMn2-XO4 + Y插层化合物。 尖晶石Li1 + XMn2-XO4 + Y插入化合物的平均X值在约0.01和0.05之间,平均Y值在约-0.02和0.04之间,并且x射线衍射峰的全宽度在 使用约0.08和0.13之间的CuKα1射线的平面(400)和(440)的衍射角2θ。 尖晶石Li1 + XMn2-XO4 + Y插层化合物可用于二次锂离子电池和锂离子电池的正电极,以提供具有高比容量和长循环寿命的电池。
    • 3. 发明授权
    • Multiple-doped oxide cathode material for secondary lithium and
lithium-ion batteries
    • 用于二次锂和锂离子电池的多重掺杂氧化物阴极材料
    • US6040089A
    • 2000-03-21
    • US31849
    • 1998-02-27
    • Vesselin ManevTitus FaulknerWayne BarnetteYuan Gao
    • Vesselin ManevTitus FaulknerWayne BarnetteYuan Gao
    • H01M4/131H01M4/50H01M4/505H01M10/052H01M10/36
    • H01M4/505H01M4/131H01M10/052
    • The present invention provides a positive electrode material for lithium and lithium-ion secondary cells which exhibits good cycleability, reversible specific capacity, and structural stability. The positive electrode material comprises a lithium multi metal oxide having a spinel structure and described by the general formula:Li.sub.1+X Mn.sub.2-Y M.sub.m.sbsb.1.sup.1 M.sub.m.sbsb.2.sup.2 . . . M.sub.m.sbsb.k.sup.k O.sub.4+Zwherein M.sup.1, M.sup.2, . . . M.sup.k are at least two cations different than lithium or manganese, selected from the group consisting of alkaline earth metals, transition metals, B, Al, Si, Ga and Ge;X, Y, m.sub.1,m.sub.2, . . . m.sub.k are numbers between 0 and 0.2;m.sub.1, m.sub.2 and Y are greater than 0;Z is a number between -0.1 and 0.2; andwherein the metals M.sup.1, M.sup.2, . . . M.sup.k and the corresponding values m.sub.1, m.sub.2, . . . m.sub.k satisfy the following equation and inequality: ##EQU1## wherein V.sub.1, V.sub.2, . . . V.sub.k are the corresponding valence states of the cations M.sup.1, M.sup.2, . . . M.sup.k.
    • 本发明提供一种锂离子二次电池用正极材料,其具有良好的循环性,可逆的比容量和结构稳定性。 正极材料包括具有尖晶石结构并由通式Li1 + XMn2-YMm11Mm22描述的锂多金属氧化物。 。 。 MmkkO4 + Z其中M1,M2,...。 。 。 Mk是选自碱金属,过渡金属,B,Al,Si,Ga和Ge中的至少两种不同于锂或锰的阳离子; X,Y,m1,m2。 。 。 mk是0到0.2之间的数字; m1,m2和Y大于0; Z是-0.1和0.2之间的数字; 并且其中金属M1,M2,...。 。 。 Mk和相应的值m1,m2。 。 。 mk满足以下等式和不等式:其中V1,V2,...。 。 。 Vk是阳离子M1,M2的相应的价态。 。 。 Mk
    • 8. 发明授权
    • Highly homogeneous spinel Li.sub.1+x Mn.sub.2-x O.sub.4 intercalation
compounds and method for preparing same
    • 高均匀尖晶石Li1 + xMn2-xO4插层化合物及其制备方法
    • US6114064A
    • 2000-09-05
    • US867190
    • 1997-06-02
    • Vesselin ManevTitus Faulkner
    • Vesselin ManevTitus Faulkner
    • C01G45/00H01M4/131H01M4/50H01M4/505H01M4/62H01M10/052H01M10/36
    • H01M4/505C01G45/1242H01M4/131H01M4/623C01P2002/32C01P2002/72C01P2002/77C01P2006/40H01M10/052Y02P70/54
    • A novel method of preparing a spinel Li.sub.1+x Mn.sub.2-x O.sub.4 intercalation compound with low lattice distortion and a highly ordered and homogeneous structure for 4 V secondary lithium and lithium ion cells is provided. The method of preparing the spinel Li.sub.1+x Mn.sub.2-x O.sub.4 intercalation compound comprises mixing at least one manganese compound with at least one lithium compound and firing the mixture at three different temperature ranges with corresponding gas flow rates to form the spinel Li.sub.1+x Mn.sub.2-x O.sub.4 intercalation compounds. The spinel Li.sub.1+x Mn.sub.2-x O.sub.4 intercalation compounds have a mean X value of between about 0.01 and 0.05 and a full width at half maximum of the x-ray diffraction peaks at a diffraction angle 2.theta. of planes (400) and (440) using CuK.alpha..sub.1 rays of between about 0.10.degree. and 0.15.degree.. The spinel Li.sub.1+x Mn.sub.2-x O.sub.4 intercalation compounds may be used in the positive electrodes of secondary lithium and lithium ion cells to provide cells having high specific capacities and long cycling lives.
    • 提供了一种制备具有低晶格畸变的尖晶石Li1 + xMn2-xO4插层化合物和用于4V二次锂和锂离子电池的高度有序和均匀结构的新方法。 制备尖晶石Li1 + xMn2-xO4插层化合物的方法包括将至少一种锰化合物与至少一种锂化合物混合,并在三种不同的温度范围内以相应的气体流速烧结该混合物以形成尖晶石Li1 + xMn2-xO4插层 化合物。 尖晶石Li1 + xMn2-xO4插入化合物的平均X值在平面(400)和(440)的衍射角2θ处的X射线衍射峰的平均X值为约0.01和0.05之间的全宽,使用 约0.10°至0.15°之间的CuKα1射线。 尖晶石Li1 + xMn2-xO4插层化合物可用于二次锂离子电池和锂离子电池的正电极,以提供具有高比容量和长循环寿命的电池。
    • 9. 发明授权
    • Highly homogeneous spinal Li.sub.1+x Mn.sub.2-x O.sub.4+y intercalation
compounds and method for preparing same
    • 高度均匀的脊髓Li1 + xMn2-xO4 + y插层化合物及其制备方法
    • US5718877A
    • 1998-02-17
    • US665408
    • 1996-06-18
    • Vesselin ManevTitus Faulkner
    • Vesselin ManevTitus Faulkner
    • C01B31/02C01G45/00H01M4/131H01M4/50H01M4/505H01M10/052H01M10/36C01G45/12
    • H01M4/505C01G45/1242H01M4/131C01P2002/32C01P2002/72C01P2002/74C01P2006/12C01P2006/40H01M10/052
    • A novel method of preparing a spinel Li.sub.1+X Mn.sub.2-X O.sub.4+Y intercalation compound with low lattice distortion and a highly ordered and homogeneous structure for 4 V secondary lithium and lithium ion cells is provided. The method of preparing the spinel Li.sub.1+X Mn.sub.2-X O.sub.4+Y intercalation compound comprises providing a spinel Li.sub.1+X Mn.sub.2-X O.sub.4 intercalation compound having a lithium to manganese mole ratio of between about 1.02:2 and 1.1:2 and firing the spinel at different temperature ranges with corresponding gas flow rates to form the spinel Li.sub.1+X Mn.sub.2-X O.sub.4+Y intercalation compounds. The spinel Li.sub.1+X Mn.sub.2-X O.sub.4+Y intercalation compounds have a mean X value of between about 0.01 and 0.05, a mean Y value of between about -0.02 and 0.04 and a full width at half maximum of the x-ray diffraction peaks at a diffraction angle 2.theta. of planes (400) and (440) using CuK.alpha..sub.1 rays of between about 0.08.degree. and 0.13.degree.. The spinel Li.sub.1+X Mn.sub.2-X O.sub.4+Y intercalation compounds may be used in the positive electrodes of secondary lithium and lithium ion cells to provide cells having high specific capacities and long cycling lives.
    • 提供了一种制备具有低晶格畸变的尖晶石Li1 + XMn2-XO4 + Y插层化合物和用于4 V二次锂和锂离子电池的高度有序和均匀结构的新方法。 制备尖晶石Li1 + XMn2-XO4 + Y插层化合物的方法包括提供锂/锰摩尔比在约1.02:2至1.1:2之间的尖晶石Li1 + XMn2-XO4插层化合物,并在不同温度下烧制尖晶石 范围与相应的气体流速形成尖晶石Li1 + XMn2-XO4 + Y插层化合物。 尖晶石Li1 + XMn2-XO4 + Y插入化合物的平均X值在约0.01和0.05之间,平均Y值在约-0.02和0.04之间,并且x射线衍射峰的全宽度在 使用约0.08和0.13之间的CuKα1射线的平面(400)和(440)的衍射角2θ。 尖晶石Li1 + XMn2-XO4 + Y插层化合物可用于二次锂离子电池和锂离子电池的正电极,以提供具有高比容量和长循环寿命的电池。