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    • 5. 发明申请
    • VINYL CYCLOHEXANEDIOL CONTAINING RESIN COMPOSITIONS
    • 含有环己烷的环氧树脂含有树脂组合物
    • WO98036009A1
    • 1998-08-20
    • PCT/US1998/002708
    • 1998-02-13
    • C08F16/02C08G63/553
    • C08G63/553C08F16/02Y10T428/249921Y10T428/31786
    • A copolymer containing vinyl-3,4-cyclohexanediol and at least one monomer selected from acrylic acid, methacrylic acid, alkyl acrylate, alkyl methacrylate, styrene, acrylonitrile, butadiene, isoprene, vinyl acetate, maleic anhydride, ethylene, vinyl chloride, vinylidene dichloride, methyl styrene, vinyl toluene, acrylic and methacrylic acid, vinyl acetate, maleic anhydride, fumarate esters, maleate esters, vinylidene difluoride, vinyl fluoride, acrylic or methacrylic esters of the formula (I): H2C=CHCOOR or H2C=CCH3COOR, where R is an aromatic or aliphatic hydrocarbon group containing 20 or fewer carbons and optionally containing oxygen, sulfur, or phosphorus, and mixtures thereof. A resin composition containing vinyl-3,4-cyclohexanediol, at least one carboxylic acid or ester thereof or anhydride, and optionally a polyol or diol other than vinyl-3,4-cyclohexanediol. A process for preparing this resin composition which involves mixing in a nitrogen atmosphere vinyl-3,4-cyclohexanediol, at least one carboxylic acid or ester thereof or anhydride, and optionally a polyol or diol other than vinyl-3,4-cyclohexanediol to form a mixture and heating the mixture to about 180 DEG -290 DEG C until the desired level of polymerization is reached to form the resin composition. A copolymer containing the vinyl-3,4-cyclohexanediol containing resin composition and at least one monomer selected from acrylic acid, methacrylic acid, alkyl acrylate, alkyl methacrylate, stryrene, acrylonitrile, butadiene, isoprene, vinyl acetate, maleic anhydride, ethylene or mixtures thereof.
    • 含有乙烯基-3,4-环己二醇和至少一种选自丙烯酸,甲基丙烯酸,丙烯酸烷基酯,甲基丙烯酸烷基酯,苯乙烯,丙烯腈,丁二烯,异戊二烯,乙酸乙烯酯,马来酸酐,乙烯,氯乙烯,二氯乙烯的单体的共聚物 甲基苯乙烯,乙烯基甲苯,丙烯酸和甲基丙烯酸,乙酸乙烯酯,马来酸酐,富马酸酯,马来酸酯,亚乙烯基二氟化物,氟乙烯,式(I)的丙烯酸或甲基丙烯酸酯:H 2 C = CHCOOR或H 2 C = CCH 3 COOR,其中 R是含有20个或更少碳原子并且任选地含有氧,硫或磷的芳族或脂族烃基及其混合物。 含有乙烯基-3,4-环己二醇,至少一种羧酸或其酯或酸酐的树脂组合物,以及任选的乙烯基-3,4-环己二醇以外的多元醇或二醇。 一种制备该树脂组合物的方法,该方法包括在氮气氛中将乙烯基-3,4-环己二醇,至少一种羧酸或其酯或酸酐,以及任选的除乙烯基-3,4-环己二醇以外的多元醇或二醇混合形成 混合物并将混合物加热至约180℃-290℃,直到达到所需的聚合水平以形成树脂组合物。 含有乙烯基-3,4-环己二醇的树脂组合物和至少一种选自丙烯酸,甲基丙烯酸,丙烯酸烷基酯,甲基丙烯酸烷基酯,苯乙烯,丙烯腈,丁二烯,异戊二烯,乙酸乙烯酯,马来酸酐,乙烯或其混合物的共聚物的共聚物 它们。