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1. 发明授权

EP1197581B1 DLC FILM, DLC-COATED PLASTIC CONTAINER, AND METHOD AND APPARATUS FOR MANUFACTURING DLC-COATED PLASTIC CONTAINER 有权
标题翻译： DLC膜，制造这样的集装箱DLC镀覆塑料容器和方法及装置
公开(公告)号：EP1197581B1
公开(公告)日：2006-10-25
申请号：EP00919156.0
申请日：2000-04-21
申请人： MITSUBISHI SHOJI PLASTICS CORPORATION , Hokkai Can Co., Ltd , Kirin Brewery Company, Limited
发明人： Yamashita, Yuuji , Kage, Tsuyoshi, Mitsubishi Shoji Plastics Corp. , Mori, Shigeki
IPC分类号： C23C16/26 , C08J7/06 , B65D1/00
CPC分类号： C23C16/045 , C23C16/26
摘要： A plastic container is coated with DLC film as a desirable oxygen barrier so that it is suitable for containing oxygen-sensitive or carbonated beverage. A coating device comprises an outer electrode arranged outside a plastic container (5), an inner electrode (11) arranged inside the plastic container (5), a pipe (12) through which carbon source gas is supplied to the plastic container (5) pumped to a low pressure, and a high-frequency oscillator (9) for applying voltage between the outer electrode and the inner electrode (11) after supplying the source gas to generate a plasma for depositing DLC film on the inner wall of the plastic container (5). The outer electrode includes a bottom electrode (4) arranged along the bottom of the plastic container (5) and a wall electrode (3) arranged along the inner wall of the plastic container. The bottom electrode (4) is located below half the complete height of the plastic container (5).

2. 发明公开

EP0492043A3 Method for recycling treatment of refuse of plastic molded articles and apparatus therefor 失效
标题翻译：循环处理塑料成型制品及其装置的方法
公开(公告)号：EP0492043A3
公开(公告)日：1992-09-02
申请号：EP91110679.7
申请日：1991-06-27
申请人： TAIYO ELECTRIC INDUSTRY CO., LTD , MITSUBISHI SHOJI PLASTICS CORPORATION
发明人： Kashiwagi, Hidehiro
IPC分类号： B29B17/02
CPC分类号： B08B9/083 , B03B9/061 , B29B17/02 , B29B2017/0234 , B29B2017/0289 , B29K2023/06 , B29K2027/06 , B29K2067/00 , B29K2105/065 , B29K2711/12 , B29L2031/7158 , B29L2031/744 , Y02W30/524 , Y02W30/525 , Y02W30/622 , Y10S241/38
摘要： The invention relates to a method for recycling treatment of refuse of plastic molded articles, e.g. polyethylene terephthalate bottles, and comprises immersing the refuse into hot water of 70-100°C while agitating to detach and remove bottom coverings of dissimilar plastics, detaching paper labels on the plastic articles by steam injection, breaking the detached labels and the plastics bodies into fragments, separating the mixture by wind-force separating to remove most of the labels, further separating the plastics bodies and residual labels by flying separating to obtain the plastics bodies only, cleaning the fragments of plastics bodies by ultrasonic energy to remove all impurities, and preparing the purified plastics bodies as chip or pellet plastic material. An apparatus for performing the method is characterized by comprising a hot water tank (2) and push impellers (3) for immersing and agitating the refuse in hot water to detach and remove the coverings, a steam injection machine (11) and an agitator (12) for injecting steam against the labels to detach them, a wind-force separator (17) and a flying separator (18) for separating out the labels completely to obtain plastics bodies only, the former having guide plates (17a) and a blower (16), the latter having a flying rotary bar (20) with fin members. The push impellers are of a square drum having vane-like projections.

3. 发明公开

EP1273523A1 PLASTIC CONTAINER FOR LIQUID CONTAINING VOLATILE ORGANIC SUBSTANCE 审中-公开
标题翻译： KUNSTSTOFFBEHÄLTERFÜRFLÜCHTIGE有机物质物质FLÜSSIGKEITEN
公开(公告)号：EP1273523A1
公开(公告)日：2003-01-08
申请号：EP00935496.0
申请日：2000-05-31
申请人： MITSUBISHI SHOJI PLASTICS CORPORATION
发明人： HAMA, Kenichi , KAGE, Tsuyoshi
IPC分类号： B65D1/00 , B65D85/00 , B65D85/72 , B32B1/02 , B32B9/00 , C23C16/27
CPC分类号： C23C16/045 , B65D1/0215 , C23C16/26
摘要： A plastic container for a liquid material containing a volatile organic substance having a DLC (diamond-like carbon) film formed on the inner surface thereof, characterized in that the DLC film has a specific composition, density and thickness, and the container exhibits flavor-barrier property for a fragrant or smelling organic substance and gas-barrier property for a volatile organic compound. Such barrier properties of the container are achieved by employing a DLC film having respectively appropriate composition, density and thickness. The container is suitable for filling a volatile organic substance such as an agricultural chemical, a cosmetic, a seasoning or an aromatic material.
摘要翻译：一种用于含有在其内表面上形成有DLC（类金刚石碳）膜的挥发性有机物质的液体材料的塑料容器，其特征在于，所述DLC膜具有特定的组成，密度和厚度，用于挥发性有机化合物的芳香或嗅觉有机物质的阻隔性和气体阻隔性。通过采用具有适当组成，密度和厚度的DLC膜来实现容器的这种阻挡性能。容器适用于填充农药，化妆品，调味料或芳香族物质等挥发性有机物质。

4. 发明公开

EP1258234A1 PLASTIC CONTAINER FOR LIQUID MEDICINE 无效
标题翻译： KUNSTSTOFFBEHÄLTERFÜRFLÜSSIGEMEDIKAMENTE
公开(公告)号：EP1258234A1
公开(公告)日：2002-11-20
申请号：EP01906205.8
申请日：2001-02-22
申请人： MITSUBISHI SHOJI PLASTICS CORPORATION
发明人： HAMA, Kenichi, MITSUBISHI SHOJI PLASTICS CORP. , KAGE, Tsuyoshi, MITSUBISHI SHOJI PLASTICS CORP.
IPC分类号： A61J1/00 , B65D1/00 , C23C16/26
CPC分类号： B65D1/0215 , A61J1/00 , B29K2003/00 , B65D23/02 , C23C16/045 , C23C16/26 , Y10T428/1352 , Y10T428/1379 , Y10T428/30 , Y10T428/3154 , Y10T428/31544
摘要： A plastic container for liquid medicine, which, concerning the effective components of liquid medicine, is capable of prevention of deterioration in quality due to mixing of oxygen and water vapor, prevention of variation in concentration due to water volatilization and moisture absorption, etc. A plastic container for liquid medicine, which is a plastic container internally coated with DLC (diamond-like carbon) film wherein water vapor permeability is 0-0.006 g/container/day and oxygen permeability is 0-0.011 ml/container/day, such properties being obtained by optimizing the three conditions, composition, density and film thickness of the DLC film.
摘要翻译：一种用于液体药物的塑料容器，其涉及液体药物的有效成分，能够防止由于氧气和水蒸气的混合引起的质量劣化，防止由于水挥发和吸湿等引起的浓度变化等。液体药物塑料容器，其是内部涂覆有DLC（类金刚石碳）膜的塑料容器，其中水蒸气透过度为0-0.006g /容器/天，氧透过度为0-0.011ml /容器/天，这些性质通过优化DLC膜的三种条件，组成，密度和膜厚度获得。

5. 发明公开

EP1652961A1 METHOD OF MANUFACTURING GAS BARRIER FILM COATED PLASTIC CONTAINER 审中-公开
标题翻译： VERFAHREN ZUR HERSTELLUNG EINES MIT EINEM GASBARRIEREFILM BESCHICHTETENKUNSTSTOFFBEHÄLTERS
公开(公告)号：EP1652961A1
公开(公告)日：2006-05-03
申请号：EP04747572.8
申请日：2004-07-15
申请人： MITSUBISHI SHOJI PLASTICS CORPORATION , Youtec Co. Ltd. , Kirin Brewery Company, Ltd.
发明人： TAKEMOTO, Keishu , KAGE, Tsuyoshi , KOBAYASHI, Takumi , SHIRAKURA, Akira
IPC分类号： C23C16/02 , C23C16/509 , B65D23/02
CPC分类号： C23C16/045
摘要： A method of manufacturing a gas barrier film coated plastic container with high gas-barrier properties by solving a problem in a conventional method wherein the formation of a gas barrier film is obstructed by water molecules adsorbed in the plastic container and the container with reduced gas-barrier properties is manufactured. The method is characterized by comprising the steps of decreasing a pressure inside the plastic container or decreasing a pressure to the entire part of the plastic container, flowing dry gas as leak gas when vacuum is released to fill the inside of the container with the dry gas for drying the plastic container, replacing the gas inside the plastic container with a material gas or a material gas-containing gas, and plasmatizing the material gas to form the gas barrier film on the inner surface of the plastic container by a CVD method.
摘要翻译：通过解决常规方法中的阻气膜的形成被吸附在塑料容器中的水分子和具有降低气体阻挡层的容器阻碍的常规方法的问题，制造具有高阻气性的阻气膜涂覆塑料容器的方法，制造阻隔性能。该方法的特征在于包括以下步骤：减小塑料容器内部的压力或降低塑料容器的整个部分的压力，当释放真空时将干燥气体作为泄漏气体流动，以用干燥气体填充容器的内部用于干燥塑料容器，用原料气体或含原料气体的气体代替塑料容器内部的气体，并通过CVD方法在材料气体的等离子体化处理以在塑料容器的内表面上形成阻气膜。

6. 发明公开

EP1493839A1 PLASMA CVD FILM FORMING APPARATUS AND METHOD FOR MANUFACTURING CVD FILM COATING PLASTIC CONTAINER 审中-公开
标题翻译：等离子体CVD膜生产装置和一种用于生产塑料容器CVD薄膜包衣
公开(公告)号：EP1493839A1
公开(公告)日：2005-01-05
申请号：EP03745987.2
申请日：2003-04-09
申请人： MITSUBISHI SHOJI PLASTICS CORPORATION , Youtec Co. Ltd.
发明人： HAMA, Kenichi, C/O MITSUBISHI SHOJI PLASTICS CORP. , KAGE, Tsuyoshi, C/O MITSUBISHI SHOJI PLASTICS CORP , TAKEMOTO, Keishu, C/O MITSUBISHI SHOJI PLAST. CORP , KOBAYASHI, Takumi, C/O YOUTEC CO., LTD
IPC分类号： C23C16/505 , C08J7/00 , B65D23/02 , B65D23/08
CPC分类号： C23C16/26 , C23C16/045 , C23C16/50 , C23C16/505
摘要： The restriction that the outer electrode of a conventional CVD film forming apparatus has to have a hollow structure including a hollow which is for accommodating a container and has a shape generally similar to the outer shape of the container is eliminated. A plasma CVD film forming apparatus is characterized in that a container outside gas is supplied into the space defined between the inner wall of an outer electrode and the outer surface of a container spaced from the inner wall, the plasma thereby produced from the container outside gas in forming a film by CVD serves as a conductor and transmits high-frequency to the outer wall of the container, a state is brought about in which the inner wall of the outer electrode is equivalently in contact with the outer surface of the plastic container, and a uniform self-bias voltage is applied to the inner wall of the container.

7. 发明公开

EP1400456A1 MANUFACTURING DEVICE FOR DLC FILM COATED PLASTIC CONTAINER; DLC FILM COATED PLASTIC CONTAINER, AND METHOD OF MANUFACTURING THE DLC FILM COATED PLASTIC CONTAINER 审中-公开
标题翻译：设备技术与DLC膜镀覆塑料容器和方法的研究DLC膜镀覆塑料容器制作DLC膜镀覆塑料容器PRODUCING
公开(公告)号：EP1400456A1
公开(公告)日：2004-03-24
申请号：EP01941260.0
申请日：2001-06-26
申请人： MITSUBISHI SHOJI PLASTICS CORPORATION , Youtec Co. Ltd.
发明人： HAMA, Kenichi , KAGE, Tsuyoshi , KOBAYASHI, Takumi
IPC分类号： B65D1/00 , B65D1/24 , B65D25/04 , B65D25/34 , C08J7/06 , C23C16/27 , C23C16/511
CPC分类号： C23C16/26 , C23C16/045 , C23C16/517 , Y10T428/13 , Y10T428/30
摘要： The present invention provides a manufacturing apparatus, a method of manufacturing a DLC film coated container and a DLC film coated container which make it possible to form a high-quality DLC film with good productivity on the outer wall surface or the inner wall surface of a container by a film forming mechanism obtained by effectively combining a high-frequency capacitive coupling type discharge system and a microwave discharge system which is different from the film forming mechanism of each method.
The manufacturing apparatus (100) of the present invention is an apparatus which forms a DLC film on the outer wall surface of a plastic container (1), and is equipped with a grounded vacuum chamber (2) for housing the plastic container (1), a high-frequency bias electrode (4) which is provided inside the vacuum chamber (2) via an insulating body (3) at a position in contact with the inner wall surface of the plastic container (1) or near the inner wall surface, a microwave supply means (10) which generates a source gas plasma inside the vacuum chamber (2) by introducing microwaves inside the vacuum chamber (2), a high-frequency output supply means (13) connected to the high-frequency bias electrode (4) to generate a self-bias voltage at the outer wall surface of the plastic container (1), and a source gas supply means (18) which introduces a source gas inside the vacuum chamber (2).
摘要翻译：本发明提供的制造装置，制造DLC薄膜包衣容器和DLC薄膜包衣容器的方法，其使得能够形成高品质的DLC电影与外壁表面上良好的生产率或的内壁面由通过有效地综合高频电容耦合型放电系统和一个微波放电系统中的所有这是从每个方法的成膜机理不同而获得的成膜机理容器。本发明的制造装置（100）是形成DLC薄膜上的塑料容器（1）的外壁表面上，并配有一接地的真空室（2），用于容纳所述塑料的装置容器（1），其通过在绝缘本体中提供的真空腔室（2）内部的高频偏压电极（4）全部（3）在接触与塑料容器的内壁表面的位置（1）或近的内壁面，微波供给装置（10），其通过在真空室内部导入微波生成真空腔室（2）内的源气体的等离子体（2），连接到高的高频输出供给装置（13） - 频率偏置电极（4），以产生在所述塑料容器（1）的外壁表面的自偏置电压，以及一个源气体供应装置（18），其引入所述真空腔室内部的气体源（2）。

8. 发明公开

EP1357042A1 PRODUCTION DEVICE FOR DLC FILM-COATED PLASTIC CONTAINER AND PRODUCTION METHOD THEREFOR 审中-公开
标题翻译： HERSTELLUNGSVORRICHTUNGFÜRMIT DLC-FILM BESCHICHTETENKUNSTSTOFFBEHÄLTERUND HERSTELLUNGSVERFAHRENDAFÜR
公开(公告)号：EP1357042A1
公开(公告)日：2003-10-29
申请号：EP00987732.5
申请日：2000-12-25
申请人： MITSUBISHI SHOJI PLASTICS CORPORATION , Youtec Co. Ltd.
发明人： HAMA, Kenichi, c/o Mitsubishi Shoji Plastics Corp. , KAGE, Tsuyoshi, c/o Mitsubishi Shoji Plastics Corp , KOBAYASHI,Takumi, c/o Youtec Co., Ltd. , ARAKI, Tomoyuki, c/o Youtec Co., Ltd.
IPC分类号： B65D1/00 , C08J7/06 , C23C16/27
CPC分类号： H01J37/32082 , C23C16/045 , C23C16/26 , H01J37/32532 , Y10S427/106
摘要： A production device for a DLC film-coated plastic container and a production method therefor, capable of forming DLC (diamond-like carbon) films simultaneously on the inner surfaces of a plurality of plastic containers, and reducing variations in film thickness. A production device for DLC film-coated plastic containers, for forming a plurality of DLC films simultaneously, characterized by comprising a columnar external electrode (3) having housing spaces in which a plurality of plastic containers (7a-7d) can be disposed in parallel and independently, internal electrodes (9a-9d) respectively disposed in the housed containers (7a-7d), a matching box (14) connected to the external electrode (3) and impedance-matching a high-frequency load, and a high-frequency power supply (15) connected to the matching box.
摘要翻译：一种用于DLC薄膜包衣的塑料容器的制造装置及其制造方法，能够在多个塑料容器的内表面上同时形成DLC（类金刚石碳）膜，并减少膜厚度的变化。一种用于DLC膜涂塑料容器的制造装置，用于同时形成多个DLC膜，其特征在于包括具有容纳空间的柱状外部电极（3），多个塑料容器（7a-7d）可以平行设置在该容纳空间中分别设置在容纳容器（7a-7d）中的内部电极（9a-9d），与外部电极（3）连接并匹配高频负载的匹配盒（14）频率电源（15）连接到匹配盒。

9. 发明公开

EP1197581A1 DLC FILM, DLC-COATED PLASTIC CONTAINER, AND METHOD AND APPARATUS FOR MANUFACTURING DLC-COATED PLASTIC CONTAINER 有权
标题翻译： DLC膜，制造这样的集装箱DLC镀覆塑料容器和方法及装置
公开(公告)号：EP1197581A1
公开(公告)日：2002-04-17
申请号：EP00919156.0
申请日：2000-04-21
申请人： MITSUBISHI SHOJI PLASTICS CORPORATION , Hokkai Can Co., Ltd , Kirin Brewery Company, Limited , Yamashita, Yuuji , Kage, Tsuyoshi
发明人： Yamashita, Yuuji , Kage, Tsuyoshi, Mitsubishi Shoji Plastics Corp. , Mori, Shigeki
IPC分类号： C23C16/26 , C08J7/06 , B65D1/00
CPC分类号： C23C16/045 , C23C16/26
摘要： (57) Abstract: A plastic container is coated with DLC film as a desirable oxygen barrier so that it is suitable for containing oxygen-sensitive or carbonated beverage. A coating device comprises an outer electrode arranged outside a plastic container (5), an inner electrode (11) arranged inside the plastic container (5), a pipe (12) through which carbon source gas is supplied to the plastic container (5) pumped to a low pressure, and a high-frequency oscillator (9) for applying voltage between the outer electrode and the inner electrode (11) after supplying the source gas to generate a plasma for depositing DLC film on the inner wall of the plastic container (5). The outer electrode includes a bottom electrode (4) arranged along the bottom of the plastic container (5) and a wall electrode (3) arranged along the inner wall of the plastic container. The bottom electrode (4) is located below half the complete height of the plastic container (5).
摘要翻译：（57）摘要：一种塑料容器，涂覆有DLC膜作为一种理想的氧阻隔所以没有它适合于含氧敏感或碳酸饮料。涂布装置包括：在塑料容器内设置的塑料容器（5）内电极（11）的外侧布置外电极（5），通过该碳源气体被供给到塑料容器的配管（12）（5）供应源气体以生成用于在塑料容器的内壁沉积DLC电影等离子体后泵至低压，并为外电极与所述内电极（11）之间施加电压的高频率振荡器（9）（5）。外侧电极包括：（4）沿所述塑料容器（5）和（3）沿所述塑料容器的内壁布置在壁电极的底部布置在底部电极。底部电极（4）位于所述塑料容器（5）的一半的整个高度的下方。

10. 发明公开

EP0492043A2 Method for recycling treatment of refuse of plastic molded articles and apparatus therefor 失效
标题翻译： Verfahren und Vorrichtung zur Wiederverwendung von geformtenKunststoffartikelnabfällen。
公开(公告)号：EP0492043A2
公开(公告)日：1992-07-01
申请号：EP91110679.7
申请日：1991-06-27
申请人： TAIYO ELECTRIC INDUSTRY CO., LTD , MITSUBISHI SHOJI PLASTICS CORPORATION
发明人： Kashiwagi, Hidehiro
IPC分类号： B29B17/02
CPC分类号： B08B9/083 , B03B9/061 , B29B17/02 , B29B2017/0234 , B29B2017/0289 , B29K2023/06 , B29K2027/06 , B29K2067/00 , B29K2105/065 , B29K2711/12 , B29L2031/7158 , B29L2031/744 , Y02W30/524 , Y02W30/525 , Y02W30/622 , Y10S241/38
摘要： The invention relates to a method for recycling treatment of refuse of plastic molded articles, e.g. polyethylene terephthalate bottles, and comprises immersing the refuse into hot water of 70-100°C while agitating to detach and remove bottom coverings of dissimilar plastics, detaching paper labels on the plastic articles by steam injection, breaking the detached labels and the plastics bodies into fragments, separating the mixture by wind-force separating to remove most of the labels, further separating the plastics bodies and residual labels by flying separating to obtain the plastics bodies only, cleaning the fragments of plastics bodies by ultrasonic energy to remove all impurities, and preparing the purified plastics bodies as chip or pellet plastic material. An apparatus for performing the method is characterized by comprising a hot water tank (2) and push impellers (3) for immersing and agitating the refuse in hot water to detach and remove the coverings, a steam injection machine (11) and an agitator (12) for injecting steam against the labels to detach them, a wind-force separator (17) and a flying separator (18) for separating out the labels completely to obtain plastics bodies only, the former having guide plates (17a) and a blower (16), the latter having a flying rotary bar (20) with fin members. The push impellers are of a square drum having vane-like projections.
摘要翻译：本发明涉及一种用于再循环处理塑料模制品的垃圾的方法。聚对苯二甲酸乙二醇酯瓶，并且包括将垃圾浸入70-100℃的热水中，同时搅拌以分离和除去不同塑料的底部覆盖物，通过蒸汽注射将塑料制品上的纸标签分开，将分离的标签和塑料体分解成碎片，通过风力分离分离混合物以去除大多数标签，通过飞行分离进一步分离塑料体和残留标签，以仅获得塑料体，通过超声能量清洁塑料体的碎片以除去所有杂质，以及将纯化的塑料体作为芯片或颗粒塑料材料制备。一种用于执行该方法的装置的特征在于包括一个热水箱（2）和推动式叶轮（3），用于将垃圾浸入和搅拌热水中以分离和去除覆盖物;蒸汽注射机（11）和搅拌器 12），用于将蒸汽注射到标签上以将其分离;风力分离器（17）和飞散分离器（18），用于完全分离标签以仅获得塑料体，前者具有导板（17a）和鼓风机（16），后者具有带翅片构件的飞行旋转杆（20）。推动叶轮是具有叶片状突起的方形鼓。

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