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1. 发明专利

JP2009223159A Display element 有权
标题翻译：显示元件
公开(公告)号：JP2009223159A
公开(公告)日：2009-10-01
申请号：JP2008069447
申请日：2008-03-18
申请人： Konica Minolta Holdings Inc , National Institute For Materials Science , コニカミノルタホールディングス株式会社 , 独立行政法人物質・材料研究機構
发明人： HAKII TAKESHI , HISAMITSU SATOSHI , HIGUCHI MASAYOSHI
IPC分类号： G02F1/155 , C08G79/00 , G02F1/19 , G09F9/30
摘要： PROBLEM TO BE SOLVED: To provide a display element that is driven with a simple member construction and at a low voltage and has high display contrast and white display reflectance. SOLUTION: In the display element having an electrolyte containing a compound represented by general formula (A) or general formula (B) and a white scattering material between facing electrodes, at least one of the facing electrodes is formed by solidifying a polymer compound including a bis(terpyridine) derivative, a metal ion and a counter anion. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供以简单的构件结构驱动并且在低电压下具有高显示对比度和白色显示反射率的显示元件。解决方案：在具有含有由通式（A）或通式（B）表示的化合物的电解质和在相对电极之间的白色散射材料的显示元件中，至少一个相对电极通过使聚合物包括双（三联吡啶）衍生物，金属离子和抗衡阴离子的化合物。版权所有（C）2010，JPO＆INPIT

2. 发明专利

JP2008162982A Method for producing cyclic phenylazomethine 有权
标题翻译：生产环丙苯甲醛的方法
公开(公告)号：JP2008162982A
公开(公告)日：2008-07-17
申请号：JP2006356392
申请日：2006-12-28
申请人： National Institute For Materials Science , 独立行政法人物質・材料研究機構
发明人： HIGUCHI MASAYOSHI , SHOMURA AKIRA , DIRK KURTH
IPC分类号： C07D257/02 , C07B61/00
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a cyclic phenylazomethine introducing multiple functional groups into a compound.
SOLUTION: The method for producing the cyclic phenylazomethine comprises a process wherein a dehydrocondensation reaction is conducted between a phenylenediamine derivative of formula (1) and a dibenzoylbenzene compound of formula (2) to prepare a chain intermediate product, which is then subjected to dehydrocyclization reaction with a diaminophenyl compound of formula (3).
COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：待解决的问题：提供一种在化合物中引入多个官能团的环状苯基偶氮甲碱的制备方法。解决方案：环状苯基偶氮甲碱的制备方法包括在式（1）的苯二胺衍生物与式（2）的二苯甲酰苯化合物之间进行脱氢反应以制备链中间产物的方法，然后将其进行与式（3）的二氨基苯基化合物脱氢环化反应。版权所有（C）2008，JPO＆INPIT

3. 发明专利

JP2012153714A Terpyridine type monomer, and, method for producing the same 有权
标题翻译：特里吡啶型单体及其制备方法
公开(公告)号：JP2012153714A
公开(公告)日：2012-08-16
申请号：JP2012099729
申请日：2012-04-25
申请人： National Institute For Materials Science , 独立行政法人物質・材料研究機構
发明人： HIGUCHI MASAYOSHI , OTSUKA TAKENORI , KURTH DIRK G
IPC分类号： C07D213/61 , C08G61/12
摘要： PROBLEM TO BE SOLVED: To provide a terpyridine type monomer suitable for synthesizing polymers capable of more strongly coordinating metals, and to provide a method for producing the same.SOLUTION: The terpyridine type monomer represented by formula (1), wherein, Xand Xare each an identical or different halogen element; R is a spacer selected from the group consisting of formula (3) to formula (6); the spacer is directly bound to the terpyridyl substituent (A) represented by formula (1) and to X, is directly not bound to the halogen element except X; Rand Rare each identical or different H, aryl or alkyl.
摘要翻译：要解决的问题：提供适于合成能够更强配位金属的聚合物的三联吡啶型单体，并提供其制备方法。解决方案：由式（1）表示的三联吡啶型单体，其中，X 1 和X 2 相同或不同的卤素元素; R是选自式（3）至式（6）的间隔基; 间隔物直接与式（1）表示的三联吡啶基取代基（A）和X 2 直接结合，除了X 2 ; R 1 和R 2 分别是相同或不同的H，芳基或烷基。版权所有（C）2012，JPO＆INPIT

4. 发明专利

JP2007127573A Annular polymer material for sensing metal, and metallic ion detecting element 有权
标题翻译：用于传感金属和金属离子检测元件的环形聚合物材料
公开(公告)号：JP2007127573A
公开(公告)日：2007-05-24
申请号：JP2005321913
申请日：2005-11-07
申请人： National Institute For Materials Science , 独立行政法人物質・材料研究機構
发明人： HIGUCHI MASAYOSHI , SHOMURA AKIRA , KURTH DIRK G
IPC分类号： G01N27/30 , C08G73/00 , G01N27/416 , G01N27/48
摘要： PROBLEM TO BE SOLVED: To provide a polymer material having function capable of capturing and detecting metallic ions, and to provide an element that uses the same. SOLUTION: This metallic ion sensing annular polymer material 100, containing imine and a benzene ring detects electrochemically the metallic ions of a microamount, by measuring the redox potential of the polymer material due to coordination (formation of complex) of the metal ion with the imine. The polymer material is formed into a square, as shown in structure 110, in a repetition unit n=2, where symbol Z represents cis-type imine. The polymer material is formed into a triangle, as shown in structure 120, in the repetition unit n=3, where symbol E represents the trans-type imine. The structure 120 is a mixture, that has the cis-type imine and trans-type imine mixed at 1:1 ratio. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供具有能够捕获和检测金属离子的功能的聚合物材料，并提供使用该金属离子的元素。解决方案：通过测量由于金属离子的配位（形成复合物）而导致的聚合物材料的氧化还原电位，含有亚胺和苯环的金属离子感测环状聚合物材料100电化学地检测微量的金属离子与亚胺。如结构110所示，聚合物材料在重复单元n = 2中形成正方形，其中符号Z表示顺式亚胺。聚合物材料在重复单元n = 3中形成为如结构120所示的三角形，其中符号E表示反式亚胺。结构120是具有按1:1比例混合的顺式亚胺和反式亚胺的混合物。版权所有（C）2007，JPO＆INPIT

5. 发明专利

JP2007112769A Terpyridine type monomer, bis-terpyridine type monomer and method for producing the same 有权
标题翻译：三烯类型单体，双 - 吡啶类单体及其制备方法
公开(公告)号：JP2007112769A
公开(公告)日：2007-05-10
申请号：JP2005308290
申请日：2005-10-24
申请人： National Institute For Materials Science , 独立行政法人物質・材料研究機構
发明人： HIGUCHI MASAYOSHI , OTSUKA TAKENORI , KURTH DIRK G
IPC分类号： C07D213/61
摘要： PROBLEM TO BE SOLVED: To obtain a monomer for synthesizing a polymer firmly coordinatable with a metal and to provide a method for producing the same.
SOLUTION: The terpyridine type monomer is represented by formula (1) (X
1 and X
2 are each a halogen element; R is a benzene ring-containing spacer).
COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：获得用于合成与金属牢固配合的聚合物的单体，并提供其制备方法。解决方案：三吡啶型单体由式（1）表示（X 1 和X 2 各自为卤素元素; R为含苯环的间隔基）。版权所有（C）2007，JPO＆INPIT

6. 发明专利

JP2012188517A Organic/metal hybrid polymer which contains metal whose coordination number is 4 and bisphenanthroline derivative, ligand thereof, and method for producing the same 有权
标题翻译：有机/金属混合聚合物，其中包含协调数为4的金属和双酚衍生物，其配体及其生产方法
公开(公告)号：JP2012188517A
公开(公告)日：2012-10-04
申请号：JP2011052269
申请日：2011-03-10
申请人： National Institute For Materials Science , 独立行政法人物質・材料研究機構
发明人： HIGUCHI MASAYOSHI , HOSSAIN MD DELWAR
IPC分类号： C08G79/00 , C07D519/00
摘要： PROBLEM TO BE SOLVED: To provide an organic/metal hybrid polymer which uses a metal having four coordinations, such as Cu and Pt, differently from a usual one having six coordinations.SOLUTION: Ligands in whose structures phenanthroline derivatives are each provided at both ends of a spacer site are used. Each phenanthroline has a coordination number of 2, and a complex is formed with such a ligand and a metal having four coordinations at a ratio of 1:1 to form a desired organic/metal hybrid polymer which is represented, for example, by the structural formula.
摘要翻译：要解决的问题：提供使用具有四个配位的金属如Cu和Pt的有机/金属杂化聚合物，与具有六个配位的通常的不同。解决方案：使用其结构菲咯啉衍生物的配体分别设置在间隔部位的两端。每个菲咯啉的配位数为2，与这样的配位体和以1:1的比例具有四个配位的金属形成络合物以形成所需的有机/金属杂化聚合物，例如由结构式。版权所有（C）2013，JPO＆INPIT

7. 发明专利

JP2012017265A Electrochromic complex compound and electrochromic element using the same 有权
标题翻译：电致复合化合物和使用该化合物的电致发光元件
公开(公告)号：JP2012017265A
公开(公告)日：2012-01-26
申请号：JP2010153792
申请日：2010-07-06
申请人： National Institute For Materials Science , Sumitomo Chemical Co Ltd , 住友化学株式会社 , 独立行政法人物質・材料研究機構
发明人： HIGUCHI MASAYOSHI , AKASAKA YUME , TANAKA KENTA
IPC分类号： C07D213/22 , C07F15/02 , C09K9/02 , G02F1/15
摘要： PROBLEM TO BE SOLVED: To provide a polymer material easily controllable of the change to a contrast color by a potential control, and readily processible; and an electrochromic element using the same.SOLUTION: The complex compound comprises a salt containing a ligand having a structure represented by formula (1) and a metal ion selected from iron, cobalt, vanadium, chromium, manganese and nickel.
摘要翻译：要解决的问题：通过电位控制提供容易控制对比度颜色变化的聚合物材料，并且易于加工; 和使用其的电致变色元件。络合物包含含有具有式（1）所示结构的配体和选自铁，钴，钒，铬，锰和镍的金属离子的盐。版权所有（C）2012，JPO＆INPIT

8. 发明专利

JP2010254778A Electrically conductive polyrotaxane 有权
标题翻译：电导电聚氨酯
公开(公告)号：JP2010254778A
公开(公告)日：2010-11-11
申请号：JP2009105010
申请日：2009-04-23
申请人： National Institute For Materials Science , 独立行政法人物質・材料研究機構
发明人： IKEDA TAICHI , HIGUCHI MASAYOSHI , KURTH DIRK G
IPC分类号： C08G61/12 , C07D495/04
CPC分类号： C07D495/04 , C08G61/126 , C08G2261/124 , C08G2261/13 , C08G2261/1424 , C08G2261/3223 , C08G2261/364 , C08G2261/43 , C08G2261/51
摘要： PROBLEM TO BE SOLVED: To provide an electrically conductive polyrotaxane without losing a cyclic molecule.
SOLUTION: The electrically conductive polyrotaxane includes electron-accepting cyclic molecule per repeating unit. In the electrically conductive polyrotaxane, the electron-accepting cyclic molecule interacts with a π-conjugated oligomer molecule. The electrically conductive polyrotaxane is a polymer of rotaxane comprising the π-conjugated oligomer and the electron-accepting cyclic molecule.
COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：待解决的问题：提供导电性聚轮烷而不会失去环状分子。＆lt; P＆gt;解决方案：导电性聚轮烷包含每个重复单元的电子接受环状分子。在导电性聚轮烷中，受电子环状分子与π-共轭低聚物分子相互作用。导电性聚轮烷是包含π共轭低聚物和电子接受环状分子的轮烷的聚合物。版权所有（C）2011，JPO＆INPIT

9. 发明专利

JP2008162967A Method for synthesizing asymmetric bis (terpyridine) compound 有权
标题翻译：用于合成不对称双（三环）化合物的方法
公开(公告)号：JP2008162967A
公开(公告)日：2008-07-17
申请号：JP2006355963
申请日：2006-12-28
申请人： National Institute For Materials Science , 独立行政法人物質・材料研究機構
发明人： HAN FU SHE , HIGUCHI MASAYOSHI , DIRK KURTH
IPC分类号： C07D213/64 , C07D213/84
摘要： PROBLEM TO BE SOLVED: To provide a new method for synthesizing an asymmetric bis(terpyridine) compound in large degree of freedom in the designing of a molecular structure and functional groups and in their syntheses without needing complicated multistage reactions. SOLUTION: This method for synthesizing the asymmetric bis(terpyridine) compound comprises coupling a terpyridine compound 1 in the presence of a boron compound 2 and further coupling a terpyridine compound 3. COPYRIGHT: (C)2008,JPO&INPIT

10. 发明专利

JP2012188519A Organic/fluorescent metal hybrid polymer and ligand thereof 有权
标题翻译：有机/荧光金属混合聚合物及其配体
公开(公告)号：JP2012188519A
公开(公告)日：2012-10-04
申请号：JP2011052361
申请日：2011-03-10
申请人： National Institute For Materials Science , 独立行政法人物質・材料研究機構
发明人： HIGUCHI MASAYOSHI , SATO TAKASHI
IPC分类号： C09K11/06 , C07D213/22
摘要： PROBLEM TO BE SOLVED: To provide an organic/metal hybrid polymer whose fluorescence can be lost and restored by simple treatments.SOLUTION: The organic/metal hybrid polymer is represented by formula 1, wherein L is an ion of a rare earth metal such as Eu; X is a spacer; and at least one of A1 and A2 and at least one of A3 and A4 are carboxyl. The polymer substantially loses its fluorescence upon exposure to an atmosphere of HCl gas or the like and the fluorescence is restored by exposing the polymer to a triethylamine atmosphere or the like. This cycle can be repeated many times.

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