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    • 1. 发明专利
    • A fuel oil composition
    • 燃油组合物
    • JP2010116496A
    • 2010-05-27
    • JP2008291170
    • 2008-11-13
    • Nippon Oil Corp新日本石油株式会社
    • SUZUKI YUJIKOYAMA SHIGERUOBATA KEN
    • C10L1/04C10L1/02C10L1/196
    • PROBLEM TO BE SOLVED: To provide an A fuel oil composition excellent in both combustion property and low temperature fluidity without deteriorating the low temperature fluidity of the fuel oil, by using a base material made of a paraffin component having a high cetane number and a cetane index, but poor low temperature fluidity.
      SOLUTION: This A fuel oil composition is obtained by compounding a base material α the paraffin content of which is ≥95 vol.% with a base material β the aromatic content of which is ≥30 vol.%, so as to satisfy following formulas (1) and (2): 42.21-(A-B)×2.05≤X≤82.21-(A-B)×2.05 (1); 17.79+(A-B)×2.05≤Y≤57.79+(A-B)×2.05 (2); wherein A is a cloud point in gradual cooling (°C) of the base material α, B is a cloud point in gradual cooling (°C) of the base material β, X is a compounding percentage (vol.%) of the base material α, Y is a compounding percentage (vol.%) of the base material β, and 0
    • 要解决的问题:为了提供燃烧特性和低温流动性优异的A燃料油组合物,而不会降低燃料油的低温流动性,通过使用由具有高十六烷值的石蜡组分制成的基材 和十六烷指数,但低温流动性差。 解决方案:该燃料油组合物通过将石蜡含量≥95体积%的基材α与芳族化合物含量≥30体积%的基材β混合,从而满足 以下公式(1)和(2):42.21-(AB)×2.05≤X≤82.21-(AB)×2.05(1); 17.79+(A-B)×2.05≤Y≤57.79+(A-B)×2.05(2); 其中,A是基材α的逐渐冷却(℃)的浊点,B是基材β的逐渐冷却(℃)的浊点,X是基材的配合比例(体积%) 材料α,Y是基材β的配合比(体积%),0
    • 2. 发明专利
    • Gas oil base and gas oil composition
    • 气体油基和气油组成
    • JP2009275113A
    • 2009-11-26
    • JP2008127615
    • 2008-05-14
    • Nippon Oil Corp新日本石油株式会社
    • KOYAMA SHIGERUHAMAMATSU TATSUOONO HIDEKIIGUCHI YASUTOSHIIKI SUGURU
    • C10L1/04C10G3/00C10L1/192
    • C10G3/00C10G2300/1014C10G2300/1018C10G2300/202C10L1/08C10L1/143C10L1/1824C10L1/19C10L1/191C10L1/1973C10L1/224C10L10/14Y02E50/13Y02P30/20
    • PROBLEM TO BE SOLVED: To provide a gas oil base which is obtained by using a raw material containing an oxygen-containing hydrocarbon compound derived from animal and vegetable oils and excels in life cycle CO
      2 discharging properties, oxidation stability, and low-temperature flowability, and to provide a gas oil composition.
      SOLUTION: The gas oil base is a hydrocarbon fraction obtained by subjecting to hydrogenation treatment an oil to be treated which contains an oxygen-containing hydrocarbon compound derived from animal and vegetable oils, an aliphatic hydrocarbon compound, and a sulfur-containing hydrocarbon compound in the presence of hydrogen, and has a content of normal paraffins of not less than 90 mass% and an average value of (B
      n-1 /A
      n ) [wherein A
      n (unit: mass%) is the total paraffin content at a specified carbon number n (wherein 10≤n≤20 and n is an even number) in the hydrocarbon fraction; B
      n-1 (unit: mass%) is the total paraffin content at a carbon number n-1; and the ratio of B
      n-1 to A
      n is taken as (B
      n-1 /A
      n )] in 10≤n≤20 of not less than 0.30.
      COPYRIGHT: (C)2010,JPO&INPIT
    • 待解决的问题:提供一种瓦斯油基料,其通过使用含有源自动植物油的含氧烃化合物的原料而获得,并且具有优异的寿命周期CO 2 性能,氧化稳定性和低温流动性,并提供瓦斯油组合物。 解决方案:瓦斯油基料是通过氢化处理获得的烃馏分,该油馏分含有来自动植物油,脂族烃化合物和含硫烃的含氧烃化合物 化合物,并且具有不小于90质量%的正构链烷烃的含量和(B n-1 / A n )的平均值[ 其中A n (单位:质量%)是烃馏分中特定碳数n(其中10≤n≤20且n是偶数)的总链烷烃含量; B n-1 (单位:质量%)是碳数n-1的总链烷烃含量; 将B n-1 与A n 的比值取为(B n-1 / A n )]为10≤n≤20,不小于0.30。 版权所有(C)2010,JPO&INPIT
    • 3. 发明专利
    • Gas oil composition
    • 气油组成
    • JP2009161669A
    • 2009-07-23
    • JP2008001290
    • 2008-01-08
    • Nippon Oil Corp新日本石油株式会社
    • KOYAMA SHIGERUIGUCHI YASUTOSHIIKI SUGURU
    • C10L1/08C10G3/00
    • C10G3/00C10G3/50C10G45/02C10G2300/1014C10G2300/1018C10G2300/1033C10G2300/202C10G2300/301C10G2300/304C10G2300/307C10G2400/06Y02P30/20
    • PROBLEM TO BE SOLVED: To provide a gas oil composition comprising a low-environmental load type gas oil base material and produced from a triglyceride-containing hydrocarbon which is a component derived from animal and vegetable oil and fat as a raw material.
      SOLUTION: The gas oil composition is produced by hydrogenating oil to be treated prepared by mixing a sulfur-containing hydrocarbon compound with the component derived from animal and vegetable oil and fat to become 1 mass ppm to 2 mass% sulfur content under a prescribed condition through 2 stages and mixing the resultant hydrogenated low-environmental load type gas oil base material with hydrogenated refined oil in a specific ratio and further adding 10-1000 mass ppm low temperature flowability improving agent and has ≤360°C 90% recovered temperature, ≥45°C ignition point, cetane number of ≥50, ≤-5°C cold filter plugging point, ≤10 ppmv sulfur content, ≤1 mass% oxygen content, ≤0.01 mass% triglyceride content, ≤3.5 mass% aliphatic alkyl ester content, ≤0.13 mgKOH/g total acid value and ≤0.12 mgKOH/g increase of acid value after oxidation stability test.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 解决的问题:提供一种包含低环境负荷型瓦斯油基础材料并由作为原料的动植物油脂肪成分的含甘油三酯烃生成的瓦斯油组合物。 解决方案:通过将含硫烃化合物与源自动植物油和脂肪的成分混合而制成的待处理油进行氢化,从而成为1质量ppm〜2质量%的硫含量, 规定条件通过2阶段,并将所得的氢化低环境负荷型瓦斯油基料与特定比例的氢化精制油混合,并进一步加入10-1000质量ppm的低温流动性改进剂,并具有≤360℃90%回收温度 ,≥45°C点火点,十六烷值≥50,≤-5°C冷滤器堵塞点,≤10ppmv硫含量≤1质量%氧含量≤0.01质量%甘油三酯含量≤3.5质量%脂肪族烷基 酯含量,≤0.13mgKOH / g总酸值和≤0.12mgKOH / g氧化稳定性试验后酸值增加。 版权所有(C)2009,JPO&INPIT
    • 4. 发明专利
    • Process for producing hydrocarbon oil
    • 生产油料油的工艺
    • JP2009001722A
    • 2009-01-08
    • JP2007165543
    • 2007-06-22
    • Nippon Oil Corp新日本石油株式会社
    • IKI SUGURUHATANAKA SHIGETOIGUCHI YASUTOSHIKOYAMA SHIGERUONO HIDEKI
    • C10G3/00C10G65/02
    • C10G3/50C10G3/42C10G45/02C10G65/043C10G2300/1014C10G2300/1018Y02P30/20
    • PROBLEM TO BE SOLVED: To provide a process for producing a hydrocarbon oil which enables obtaining a hydrocarbon oil having a sufficiently reduced oxygen content, low temperature performance and oxidation stability as a fuel oil for practical purposes in producing a hydrocarbon oil from a raw material oil containing an oxygen-containing hydrocarbon compound and furthermore is effective in the point of the reduction in the cost of equipment and the consumption of energy, and the production efficiency. SOLUTION: The process for producing a hydrocarbon oil comprises performing the hydrogenation deoxygenation and hydrogenation isomerization of a raw material oil containing an oxygen-containing hydrocarbon compound in the presence of hydrogen and a first hydrogenation catalyst so as for an oxygen content removal ratio to come to 5-80 mass% in a first reaction zone to obtain a first product oil and then performing the hydrogenation deoxygenation of the first product oil obtained in the first step in the presence of hydrogen and a second hydrogenation catalyst in a second reaction zone arranged in series with the first reaction zone to obtain a second product oil. COPYRIGHT: (C)2009,JPO&INPIT
    • 解决的问题:提供一种烃油的制造方法,其能够获得具有充分降低的氧含量,低温性能和氧化稳定性的烃油作为燃料油,用于从 含有含氧烃化合物的原料油,并且在降低设备成本和能量消耗以及生产效率方面是有效的。 解决方案:烃油的制造方法包括在氢气和第一氢化催化剂的存在下进行含有含氧烃化合物的原料油的氢化脱氧和氢化异构化,以使氧含量除去率 在第一反应区中达到5-80质量%,得到第一产物油,然后在第二反应区中在氢和第二氢化催化剂的存在下,对第一步中获得的第一产物油进行氢化脱氧 与第一反应区串联排列以获得第二产品油。 版权所有(C)2009,JPO&INPIT
    • 5. 发明专利
    • Light oil composition
    • 轻油组合物
    • JP2008303345A
    • 2008-12-18
    • JP2007153670
    • 2007-06-11
    • Nippon Oil Corp新日本石油株式会社
    • KOYAMA SHIGERUIGUCHI YASUTOSHIIKI SUGURUONO HIDEKITAKAHASHI SHINYATABATA KATSUMI
    • C10L1/00C10L1/08
    • C10L1/026C10G3/46C10G3/47C10G3/49C10G3/50C10G2300/1014C10G2300/1018C10G2300/1033C10G2300/202C10G2300/203C10G2300/301C10G2300/307C10G2300/4006C10G2300/4012C10G2300/4018C10G2400/04C10G2400/06C10L1/08Y02E50/13Y02P30/20
    • PROBLEM TO BE SOLVED: To provide a light oil composition comprising an environmental low load type light oil base material produced using animal/vegetable oils and fats and hydrocarbon containing triglyceride as a component derived from animal/vegetable oils and fats as raw materials, having life cycle CO
      2 exhaust properties and oxidation stability, and reducing environmental pollutants such as dioxins in an exhaust gas.
      SOLUTION: The light oil composition comprises 20 to 80 vol% of a light oil base material produced by bringing animal/vegetable oils and fats and/or a component derived from animal/vegetable oils and fats as the oil to be treated into contact with a catalyst containing a metal(s) carried on a porous inorganic oxide in the presence of hydrogen under the conditions where hydrogen pressure is 2 to 13 MPa, a liquid space speed is 0.1 to 3.0 h
      -1 , a hydrogen-oil ratio is 150 to 1,500NL/L and reaction temperature is 150 to 480°C, and in which 90 vol% distillate temperature is ≤360°C, a sulfur content is ≤10 massppm and an oxygen content is ≤1 mass%. In the light oil composition, 90 vol% distillate temperature is ≤360°C, the whole aromatic content is ≤15 vol%, a cetane index is ≥45, a sulfur content is ≤10 mass%, an oxygen content is ≤1 mass%, a fatty acid alkyl ester content is ≤3.5 mass%, an acid value is ≤0.13 mgKOH/g, a methanol content is ≤0.01 mass%, a triglyceride content is ≤0.01 mass%, and also, the increasing amount of the acid value after an oxidation stabilization test is ≤0.12 mgKOH/g.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供一种轻油组合物,其包含使用动物/植物油和脂肪制备的环境低负荷型轻油基料和含有甘油三酸酯的烃作为源自动植物油和脂肪的成分 具有生命周期CO 2 排气性能和氧化稳定性,并减少废气中的二恶英等环境污染物。 解决方案:轻油组合物包含20至80体积%的轻油基料,其通过将来自动物/植物油和脂肪的动物/植物油和脂肪和/或作为待处理的油的植物油和/ 在氢气存在下,在氢气压力为2〜13MPa,液体空间速度为0.1〜3.0h -1的情况下,与含有载持于多孔无机氧化物上的金属的催化剂接触, >,氢 - 油比为150〜1500NL / L,反应温度为150〜480℃,馏出温度为390℃时,硫含量为≤10质量ppm,氧含量为 ≤1质量%。 在轻油组成中,90体积%馏出物温度≤360℃,全芳烃含量≤15体积%,十六烷值≥45,硫含量≤10质量%,氧含量≤1质量% %,脂肪酸烷基酯含量≤3.5质量%,酸值≤0.13mgKOH/ g,甲醇含量≤0.01质量%,甘油三酯含量≤0.01质量%,并且, 氧化稳定化试验后的酸值≤0.12mgKOH/ g。 版权所有(C)2009,JPO&INPIT
    • 6. 发明专利
    • Gas oil composition
    • 气油组成
    • JP2007308575A
    • 2007-11-29
    • JP2006138363
    • 2006-05-17
    • Nippon Oil Corp新日本石油株式会社
    • KOYAMA SHIGERUIGUCHI YASUTOSHISUGANO HIDEAKIIKI SUGURU
    • C10L1/08C10G3/00C11C3/12
    • Y02P30/20
    • PROBLEM TO BE SOLVED: To provide a gas oil composition which contains an environmental low load type gas oil base material produced from triglyceride-containing hydrocarbons comprising animal or vegetable oils or fats and/or animal or vegetable oils or fats-originated components as raw materials, and is excellent in life cycle CO 2 exhaust characteristics and in all of fuel cost, exhaust gas characteristics and oxidation stability. SOLUTION: This gas oil composition having a 90% distillation temperature of ≤360°C, a total aromatic content of ≤15 vol.%, a cetane index of ≥45, a sulfur content of ≤5 mass ppm, an oxygen content of ≤1 mass%, a triglyceride content of ≤0.01 mass%, an acid value of ≤0.13 mgKOH, an acid value-increasing amount of 0.12 mgKOH/g after an oxidation stability test, and a monocyclic naphthene content of ≥10 vol.% is produced by mixing a gas oil base material obtained by contacting animal or vegetable oils or fats and/or animal or vegetable fats or fats-originated components with a periodic table group 8 element catalyst carried on a porous inorganic oxide in the presence of hydrogen, with a hydrogenated refined oil refined from crude oil or the like in a ratio of 50 to 70 vol.%:30 to 50 vol.%. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供一种含有由含有动物或植物油或脂肪和/或动物或植物油或脂肪来源的组分的含甘油三酯的烃生产的环境低负荷型瓦斯油基础油的瓦斯油组合物 作为原料,并且在生命周期CO 2 排气特性和燃料成本,废气特性和氧化稳定性方面均优异。 解决方案:该汽油组合物具有90%蒸馏温度≤360℃,总芳烃含量≤15体积%,十六烷指数≥45,硫含量≤5质量ppm,氧气 含量≤1质量%,甘油三酯含量≤0.01质量%,酸值≤0.13mgKOH,氧化稳定性试验后酸值增加量为0.12mgKOH / g,单环烷烃含量≥10体积% 通过将动物或植物油或脂肪和/或动物或植物脂肪或脂肪来源的成分与通过在多孔无机氧化物上承载的周期表第8族元素催化剂接触而获得的瓦斯油基料混合, 氢,与原油等以50〜70体积%:30〜50体积%的比例精制而成的氢化精制油。 版权所有(C)2008,JPO&INPIT
    • 9. 发明专利
    • Gas oil composition
    • 气油组成
    • JP2009040855A
    • 2009-02-26
    • JP2007206460
    • 2007-08-08
    • Nippon Oil Corp新日本石油株式会社
    • KOYAMA SHIGERUIGUCHI YASUTOSHIIKI SUGURU
    • C10L1/08C10G3/00C10G47/00
    • Y02P30/20
    • PROBLEM TO BE SOLVED: To provide a gas oil composition comprising a low-environmental load type gas oil base material produced from a triglyceride-containing hydrocarbon which is a component derived from an animal and vegetable oil and fat as a raw material and exhibiting excellent life-cycle CO 2 emission characteristics and oxidation stability and further excellent member stability. SOLUTION: The gas oil composition is produced by mixing 95-30 vol.% of a gas oil base material with 5-70 vol.% of a petroleum-based hydrotreated oil. The gas oil base material is obtained by mixing 10-90 vol.% of the low-environmental load type gas oil base material with 90-10 vol.% of a hydrocracked gas oil fraction. The low-environmental load type gas oil base material is produced by bringing an oil to be treated into contact with a catalyst comprising a prescribed porous inorganic oxide and an active metal in the presence of hydrogen under prescribed reaction conditions. The oil to be treated is prepared by mixing the animal and vegetable oil and fat and/or the component derived from the animal and vegetable oil and fat with a sulfur-containing hydrocarbon compound. The gas oil composition has ≤360°C 90% recovered temperature, ≤10 mass ppm sulfur content, ≤1 mass% oxygen content, ≤3.5 mass% content of a fatty acid alkyl ester, ≤0.13 mgKOH/g total acid value, ≤0.01 mass% methanol content, ≤0.01 mass% glyceride content and ≤-5°C cold filter plugging point. COPYRIGHT: (C)2009,JPO&INPIT
    • 解决问题的方法:提供一种瓦斯油组合物,其包含由作为原料的动植物油和脂肪成分的含甘油三酸酯烃生成的低环境负荷型瓦斯油基料,以及 表现出优异的生命周期CO 2 发射特性和氧化稳定性,并且进一步优异的构件稳定性。 解决方案:瓦斯油组合物通过将95-30体积%的瓦斯油基础材料与5-70体积%的石油基加氢处理油混合来制备。 通过将10-90体积%的低环境负荷型瓦斯油基料与90-10体积%的加氢裂化瓦斯油馏分混合,得到瓦斯油基料。 低环境负荷型瓦斯油基材是在规定的反应条件下,在氢的存在下使被处理油与包含规定的多孔无机氧化物和活性金属的催化剂接触而制造的。 待处理的油通过将动植物油和脂肪和/或源自动植物油脂的成分与含硫烃化合物混合来制备。 瓦斯油组合物具有≤360℃90%回收温度,≤10质量ppm硫含量,≤1质量%氧含量,≤3.5质量%脂肪酸烷基酯含量≤0.13mgKOH/ g总酸值≤ 0.01质量%甲醇含量,≤0.01质量%甘油酯含量和≤-5℃冷滤芯堵塞点。 版权所有(C)2009,JPO&INPIT
    • 10. 发明专利
    • Light oil composition
    • 轻油组合物
    • JP2007332359A
    • 2007-12-27
    • JP2007129120
    • 2007-05-15
    • Nippon Oil Corp新日本石油株式会社
    • IGUCHI YASUTOSHISUGANO HIDEAKIKOYAMA SHIGERUIKI SUGURU
    • C10L1/08C10G3/00C10G45/04C10G45/08C10G45/64C10G65/02
    • Y02P30/20
    • PROBLEM TO BE SOLVED: To provide a light oil composition which comprises an environmentally friendly light oil base material produced using an animal/vegetable oil and fat and a triglyceride-containing hydrocarbon derived from an animal/vegetable oil, and is excellent in life cycle CO 2 effluence, flammability, and high temperature restart. SOLUTION: The light oil composition comprises a distillate fraction having a ratio of 0.20 or more of isoparaffin versus normal paraffin at a content of 10-70% by volume, has a specific property, and has a ratio of 0.60 or higher of isoparaffin versus normal paraffin, wherein the distillate fraction is produced as follows: an animal/vegetable oil and fat and/or an animal/vegetable oil and fat-derived component is mixed with a sulfur-containing hydrocarbon compound to get a sulfur content of 1-2% by mass, brought into contact with a specific sulfide catalyst under a specific condition, and further hydrogenated with a catalyst under a specific condition to produce the distillate fraction, where the catalyst contains one or more metals selected from elements belonging to the group 6A and the group 8 in the periodic table supported on a carrier containing a crystalline molecular sieve. COPYRIGHT: (C)2008,JPO&INPIT
    • 解决问题的方法:提供一种轻油组合物,其包含使用动植物油脂和来自动植物油的含甘油三酯的环境友好的轻油基础物质, 生命周期CO 2 流出,可燃性和高温重启。 解决方案:轻油组合物包含异构烷烃的比例为0.20以上的馏出物​​馏分与含有10-70体积%的正链烷烃的馏出物馏分具有特定的性质,并且比率为0.60以上 异链烷烃相对于正链烷烃,其中馏出物馏分如下生产:将动物/植物油脂和/或动物/植物油和脂肪衍生的组分与含硫烃化合物混合以获得1的硫含量 -2质量%,在特定条件下与特定的硫化物催化剂接触,并且在特定条件下用催化剂进一步氢化以产生馏出物馏分,其中催化剂含有一种或多种选自属于该组的元素的金属 6A和周期表中的基团8负载在含有结晶分子筛的载体上。 版权所有(C)2008,JPO&INPIT