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    • 3. 发明专利
    • Defoaming agent
    • 缺陷剂
    • JP2011025235A
    • 2011-02-10
    • JP2010147411
    • 2010-06-29
    • Shin-Etsu Chemical Co Ltd信越化学工業株式会社
    • YAMAGUCHI HIROMASAKOIKE NORIYUKITAKEWAKI KAZUYUKI
    • B01D19/04
    • PROBLEM TO BE SOLVED: To provide a silicone-based defoaming agent having an excellent defoaming or foam-controlling effect on organic solvents. SOLUTION: The defoaming agent contains as the effective defoaming component a perfluoropolyether-modified polysiloxane represented by general formula (1), (wherein Rf is a 1-10C linear or branched perfluoroalkyl group; X is a fluorine atom or a trifluoromethyl group; Q is a 1-12C divalent organic group; R 1 , R 2 , and R 3 are each independently a 1-10C alkyl or an aryl group; a, b, c, and d are each independently an integer of 0-200, provided that the sum of a, b, c, and d is 1 or larger; e is an integer of 0 or 1; and z is an integer of 5-100). COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:提供对有机溶剂具有优异的消泡或泡沫控制效果的硅氧烷基消泡剂。 解决方案:消泡剂含有由通式(1)表示的全氟聚醚改性聚硅氧烷作为有效消泡组分,其中Rf为1-10C直链或支链全氟烷基; X为氟原子或三氟甲基 ; Q为1-12C二价有机基团; R 1为SP 1,R SP 2,R SP 3各自独立地为1-10C烷基或 芳基; a,b,c和d各自独立地为0-200的整数,条件是a,b,c和d的和为1或更大; e为0或1的整数;以及 z为5-100的整数)。 版权所有(C)2011,JPO&INPIT
    • 5. 发明专利
    • Defoamant composition
    • 缺失组合物
    • JP2010279889A
    • 2010-12-16
    • JP2009134710
    • 2009-06-04
    • Shin-Etsu Chemical Co Ltd信越化学工業株式会社
    • TAKEWAKI KAZUYUKITAKADA YUKOITAGAKI AKINARI
    • B01D19/04C08K3/36C08L83/06
    • PROBLEM TO BE SOLVED: To provide a defoamant composition which exhibits high defoaming performance, dispersibility and paintability to various coating liquids. SOLUTION: The defoamant composition comprises: organic acid ester-modified organopolysiloxane (A) shown by general formula (1) (wherein R 1 s are each a hydroxyl group or a 1-18C monovalent hydrocarbon group independently; R 2 s are each an organic acid ester-modified group shown by general formula (2) (wherein R 3 is a 1-21C monovalent hydrocarbon group independently), R 1 , a hydrogen atom or a 1-4C alkoxy group independently); and 0.1-30 pts.mass silica fine powder (B) (on condition that the total amount of the (A) component and the (B) component is 100 pts.mass). COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:提供一种对各种涂料液体具有高消泡性能,分散性和可涂布性的消泡剂组合物。 解泡剂:消泡剂组合物包含:通式(1)所示的有机酸酯改性的有机聚硅氧烷(A)(其中R 1〜S 1各自为羟基或1-18元一价烃 独立地为R 2为各通式(2)所示的有机酸酯改性基团(其中R 3 独立地为1-21C一价烃基) ,R 1,独立的氢原子或1-4C烷氧基); 和0.1-30质量份二氧化硅细粉(B)(在(A)成分和(B)成分的总量为100质量份的条件下)。 版权所有(C)2011,JPO&INPIT
    • 6. 发明专利
    • Oil compound for defoamer and defoamer composition
    • 用于防腐剂和防腐剂组合物的油性化合物
    • JP2013215633A
    • 2013-10-24
    • JP2012072948
    • 2012-03-28
    • Shin-Etsu Chemical Co Ltd信越化学工業株式会社
    • TAKEWAKI KAZUYUKIMATSUI CHINAMISAKURAI TAKATO
    • B01D19/04
    • B01D19/0409C11D9/36G01N24/087
    • PROBLEM TO BE SOLVED: To provide a silicone-based oil compound for a defoamer, which has good initial defoaming property even in alkaline foaming liquids, is reduced in time degradation and has excellent in defoaming performance.SOLUTION: An oil compound for a defoamer includes (A) substantially hydrophobic organopolysiloxane having a viscosity of 10 to 100,000 mm/s at 25°C, and (B) finely divided silica that has undergone surface hydrophobization treatment. In the spectra measured bySi-CP/MAS-NMR for the oil compound, among peaks due to SiO(Q) units on a silica surface, a ratio [(Q2+Q3)/Q4] between the total area (Q2+Q3) of a peak area Q2 of a Si atom having two unreacted silanol groups and a peak area Q3 of a Si atom having one unreacted silanol group and a peak area Q4 of a Si atom having no unreacted silanol group is 70/30 to 20/80.
    • 要解决的问题:为了提供即使在碱性发泡液中也具有良好的初始消泡性的消泡剂用硅氧烷类油性化合物,其时效降低,消泡性能优异。解决方案:消泡剂用油性化合物包括 (A)在25℃下具有10至100,000mm / s粘度的基本上疏水的有机聚硅氧烷,和(B)经过表面疏水化处理的细碎二氧化硅。 在油化合物的Si-CP / MAS-NMR测定的光谱中,由于二氧化硅表面上的SiO(Q)单元的峰值,总面积(Q2 + Q3)之间的比率[(Q2 + Q3)/ Q4] 具有两个未反应的硅烷醇基的Si原子的峰面积Q2和具有一个未反应的硅烷醇基的Si原子的峰面积Q3和没有未反应的硅烷醇基的Si原子的峰面积Q4为70/30至20/80 。
    • 8. 发明专利
    • Defoaming agent composition
    • 缺陷剂组合物
    • JP2005137963A
    • 2005-06-02
    • JP2003374362
    • 2003-11-04
    • Shin Etsu Chem Co Ltd信越化学工業株式会社
    • IKEDA TERUKITAKEWAKI KAZUYUKI
    • B01D19/04
    • PROBLEM TO BE SOLVED: To provide a defoaming agent composition excellent in defoaming properties and internal addition stability and causing no repellency.
      SOLUTION: This defoaming agent composition contains 100 pts. mass of an oil compound (1) containing 100 pts. mass of a hydrophobic organopolysiloxane with a viscosity at 25°C of 10-100,000 mm
      2 /s and 2-30 pts. mass of fine powdery silica, 20-100 pts. mass of a polyoxyalkylene modified organopolysiloxane (2), 10-100 pts. mass of an organopolysiloxane with a viscosity at 25°C of 5-5,000 mm
      2 /s having at least two olefinic unsaturated groups in one molecule thereof (3), 1-100 pts. mass of a nonionic surfactant (4), 0-100 pts. mass of a polyoxyalkylene polymer (5) with an average molecular weight of 500-5,000 and 60-1,000 pts. mass of water (6) per 100 pts. mass of the sum total amount of all components (1), (2), (3), (4) and (5).
      COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:提供消泡性和内部添加稳定性优异且不排斥性的消泡剂组合物。

      解决方案:该消泡剂组合物含有100个点。 含有100个油的化合物(1)的质量。 在25℃下的粘度为10-100,000mm 2 /秒/秒的疏水性有机聚硅氧烷的质量为2-30个。 质量细粉二氧化硅,20-100磅。 聚氧化烯改性的有机聚硅氧烷(2)的质量为10-100个。 质量的在25℃下的粘度为5-5,000mm的分子中具有至少两个烯属不饱和基团的化合物(3),1-100重量份的有机聚硅氧烷。 质量的非离子表面活性剂(4),0-100份。 质量的聚氧化烯聚合物(5)的平均分子量为500-5,000和60-1,000点。 水质量(6)每100点。 所有组分(1),(2),(3),(4)和(5)的总和总量的质量。 版权所有(C)2005,JPO&NCIPI

    • 9. 发明专利
    • Defoaming agent
    • 缺陷剂
    • JP2008079559A
    • 2008-04-10
    • JP2006265073
    • 2006-09-28
    • Shin Etsu Chem Co Ltd信越化学工業株式会社
    • IKEDA TERUKITAKEWAKI KAZUYUKI
    • C13B20/06B01D19/04
    • PROBLEM TO BE SOLVED: To provide a defoaming agent exhibiting superior defoaming effects, even under strongly basic conditions, preferably, a defoaming agent for sugar manufacturing process.
      SOLUTION: The defoaming agent containing a propylene glycol fatty acid ester, containing at least 35 mass% of propylene glycol monocaprylic acid monooleic acid ester, preferably, a defoaming agent containing (A) 100 pts.mass of the propylene glycol fatty acid ester and (B) 0-100 pts.mass of a glycerol fatty acid ester; a sugar manufacturing method including a clarifying process with quicklime, wherein the defoaming agent is added to a treated liquid in at least one step of the clarifying process; and a sugar manufacturing method including a sucrose recovery step by the Steffen method, wherein the defoaming agent is added to the treated liquid in at least one step of the recovery process.
      COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:即使在强碱性条件下,优选提供用于制糖过程的消泡剂,也提供具有优异消泡作用的消泡剂。 解决方案:含有丙二醇脂肪酸酯的消泡剂含有至少35质量%的丙二醇单辛酸单油酸酯,优选含有(A)100质量份丙二醇脂肪酸的消泡剂 酯和(B)0-100重量份的甘油脂肪酸酯; 一种糖生产方法,包括生石灰的澄清过程,其中在澄清过程的至少一个步骤中将消泡剂加入到处理过的液体中; 以及糖制造方法,其包括通过Steffen法的蔗糖回收步骤,其中在回收过程的至少一个步骤中将消泡剂加入到处理过的液体中。 版权所有(C)2008,JPO&INPIT
    • 10. 发明专利
    • Granular silicone defoaming agent composition and powdery detergent composition
    • 颗粒硅酮缺陷剂组合物和粉末洗涤剂组合物
    • JP2008024760A
    • 2008-02-07
    • JP2006196374
    • 2006-07-19
    • Shin Etsu Chem Co Ltd信越化学工業株式会社
    • IKEDA TERUKITAKEWAKI KAZUYUKI
    • C11D3/37B01D19/04C11D3/20
    • PROBLEM TO BE SOLVED: To provide a granular silicone defoaming agent composition capable of efficiently suppressing foams in washing (including rinsing) and also high in preservation stability in a detergent composition, and to provide such a powdery detergent composition containing the above defoaming agent composition. SOLUTION: The granular silicone defoaming agent composition comprises (A) a silicone defoaming agent, (B) an excipient material, (C) organowaxes and (D) either one or both of a polyoxyalkylene-modified organosiloxane with a melting point of 35°C or higher and a siloxane-polyoxyalkylene block copolymer with a melting point of 35°C or higher. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供能够有效地抑制洗涤(包括漂洗)中的泡沫并且在洗涤剂组合物中保存稳定性高的颗粒状硅氧烷消泡剂组合物,并提供含有上述消泡剂的粉末洗涤剂组合物 代理成分。 解决方案:粒状硅氧烷消泡剂组合物包含(A)硅氧烷消泡剂,(B)赋形剂材料,(C)有机丝和(D)聚氧化烯改性的有机硅氧烷中的一种或两种,熔点为 35℃以上,熔点35℃以上的硅氧烷 - 聚氧化烯嵌段共聚物。 版权所有(C)2008,JPO&INPIT