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91. 发明授权

US08900755B2 Lithium super-battery with a chemically functionalized disordered carbon cathode 有权
标题翻译：具有化学官能化无序碳阴极的锂超级电池
公开(公告)号：US08900755B2
公开(公告)日：2014-12-02
申请号：US12924211
申请日：2010-09-23
申请人： Chenguang Liu , Aruna Zhamu , David Neff , Bor Z. Jang
发明人： Chenguang Liu , Aruna Zhamu , David Neff , Bor Z. Jang
IPC分类号： H01M4/13 , H01M4/587 , H01G11/06 , H01G11/38 , H01G11/50 , H01M10/0525 , H01M4/485 , H01M4/58 , H01M4/02
CPC分类号： H01M4/587 , H01G11/06 , H01G11/38 , H01G11/50 , H01M4/485 , H01M4/5825 , H01M10/0525 , H01M2004/021 , Y02E60/122 , Y02E60/13
摘要： An electrochemical energy storage device, lithium super-battery, comprising a positive electrode, a negative electrode, a porous separator disposed between the two electrodes, and a lithium-containing electrolyte in physical contact with the two electrodes, wherein the positive electrode comprises a disordered carbon material having a functional group that reversibly reacts with a lithium atom or ion. The disordered carbon material is selected from a soft carbon, hard carbon, polymeric carbon or carbonized resin, meso-phase carbon, coke, carbonized pitch, carbon black, activated carbon, or partially graphitized carbon. In a preferred embodiment, a lithium super-battery having a functionalized disordered carbon cathode and a Li4Ti5O12 anode exhibits a gravimetric energy ˜5-10 times higher than those of conventional supercapacitors and a power density ˜10-30 times higher than those of conventional lithium-ion batteries. This device has the best properties of both the lithium ion battery and the supercapacitor.
摘要翻译：一种电化学蓄电装置，锂超级电池，包括正极，负极，设置在两个电极之间的多孔隔板和与两个电极物理接触的含锂电解质，其中正极包括无序的具有与锂原子或离子可逆地反应的官能团的碳材料。无序碳材料选自软碳，硬碳，聚合碳或碳化树脂，中间相碳，焦炭，碳化沥青，炭黑，活性炭或部分石墨化碳。在优选实施例中，具有官能化无序碳阴极和Li 4 Ti 5 O 12阳极的锂超级电池显示比常规超级电容器高约5-10倍的重量能量，并且功率密度比传统锂电池高10〜30倍电池。该器件具有锂离子电池和超级电容器的最佳性能。

92. 发明申请

US20140342249A1 Lithium secondary batteries containing lithium salt-ionic liquid solvent electrolyte 有权
标题翻译：锂二次电池含锂离子液体溶剂电解质
公开(公告)号：US20140342249A1
公开(公告)日：2014-11-20
申请号：US13986576
申请日：2013-05-16
申请人： Hui He , Bor Z Jang , Yanbo Wang , Aruna Zhamu
发明人： Hui He , Bor Z Jang , Yanbo Wang , Aruna Zhamu
IPC分类号： H01M10/056 , H01M10/052 , H01M12/08
CPC分类号： H01M10/056 , H01M4/485 , H01M4/581 , H01M4/5815 , H01M10/052 , H01M10/0567 , H01M10/0568 , H01M10/0569 , H01M10/4235 , H01M12/08 , H01M2004/021 , Y02E60/122 , Y02E60/128 , Y02T10/7011
摘要： A rechargeable lithium metal or lithium-ion cell comprising a cathode having a cathode active material and/or a conductive supporting structure, an anode having an anode active material and/or a conductive supporting nano-structure, a porous separator electronically separating the anode and the cathode, a highly concentrated electrolyte in contact with the cathode active material and the anode active material, wherein the electrolyte contains a lithium salt dissolved in an ionic liquid solvent with a concentration greater than 3 M. The cell exhibits an exceptionally high specific energy, a relatively high power density, a long cycle life, and high safety with no flammability.
摘要翻译：一种可再充电的锂金属或锂离子电池，包括具有阴极活性材料和/或导电支撑结构的阴极，具有负极活性材料和/或导电支撑纳米结构的阳极，阴极，与阴极活性材料和阳极活性材料接触的高浓度电解质，其中电解质含有溶解在浓度大于3M的离子液体溶剂中的锂盐。电池表现出特别高的比能，功率密度相对较高，循环寿命长，安全性高，无易燃性。

93. 发明授权

US08871296B2 Method for producing conducting and transparent films from combined graphene and conductive nano filaments 有权
标题翻译：从组合石墨烯和导电纳米丝生产导电和透明薄膜的方法
公开(公告)号：US08871296B2
公开(公告)日：2014-10-28
申请号：US13815730
申请日：2013-03-14
申请人： Aruna Zhamu , Yi-jun Lin , Bor Z. Jang
发明人： Aruna Zhamu , Yi-jun Lin , Bor Z. Jang
IPC分类号： C23C16/26 , C23C18/00 , B05D5/12 , B05D7/12 , B05D1/02 , H01B13/00
CPC分类号： H01B13/0036 , B05D1/02 , B05D5/12 , B05D7/12 , B22F1/0025 , B22F7/04 , B22F2007/042 , C22C26/00 , C23C16/26 , H01L31/1884 , H01L51/0021 , H01L51/0048 , H01L51/444 , Y02E10/50 , Y10S427/101
摘要： A method of producing a transparent and conductive film, comprising (a) forming aerosol droplets of a first dispersion comprising a first conducting nano filaments in a first liquid; (b) forming aerosol droplets of a second dispersion comprising a graphene material in a second liquid; (c) depositing the aerosol droplets of a first dispersion and the aerosol droplets of a second dispersion onto a supporting substrate; and (d) removing the first liquid and the second liquid from the droplets to form the film, which is composed of the first conducting nano filaments and the graphene material having a nano filament-to-graphene weight ratio of from 1/99 to 99/1, wherein the film exhibits an optical transparence no less than 80% and sheet resistance no higher than 300 ohm/square.
摘要翻译：一种制造透明导电膜的方法，包括（a）在第一液体中形成包含第一导电纳米长丝的第一分散体的气溶胶滴; （b）在第二液体中形成包含石墨烯材料的第二分散体的气溶胶液滴; （c）将第一分散体的气溶胶液滴和第二分散体的气溶胶液滴沉积到支撑基底上; 和（d）从液滴中除去第一液体和第二液体以形成由第一导电纳米丝和石墨烯材料组成的膜，其具有1/99至99的纳米线 - 石墨烯重量比 / 1，其中所述膜显示不小于80％的光学透明度和不高于300欧姆/平方的薄层电阻。

94. 发明申请

US20140242275A1 Process for producing unitary graphene materials 有权
标题翻译：生产单一石墨烯材料的方法
公开(公告)号：US20140242275A1
公开(公告)日：2014-08-28
申请号：US13815349
申请日：2013-02-25
申请人： Aruna Zhamu , Mingchao Wang , Lucy Fu , Bor Z. Jang
发明人： Aruna Zhamu , Mingchao Wang , Lucy Fu , Bor Z. Jang
IPC分类号： C01B31/04
CPC分类号： C01B31/0469 , C01B31/0423 , C01B32/19 , C01B32/225
摘要： A process for producing a unitary graphene material, comprising: (a) preparing a graphene oxide (GO) gel having GO molecules dissolved in a fluid medium wherein the GO molecules contain higher than 20% by weight of oxygen; (b) dispensing and depositing a layer of GO gel onto a surface of a substrate to form a layer of deposited GO gel thereon, wherein the dispensing and depositing procedure includes shear-induced thinning; (c) removing the fluid medium from the deposited GO gel to form a GO layer having an inter-plane spacing d002 of 0.4 nm to 1.2 nm as determined by X-ray diffraction; and (d) heat treating the GO layer to form the unitary graphene material at a heat treatment temperature higher than 100° C. to an extent that d002 is decreased to a value of 0.3354 nm to 0.4 nm and the oxygen content is decreased to less than 5% by weight.
摘要翻译：一种制备单一石墨烯材料的方法，包括：（a）制备具有溶解在其中GO分子含有高于20重量％的氧的流体介质中的GO分子的氧化石墨烯（GO）凝胶; （b）将GO凝胶层分配并沉积到基底表面上以在其上形成沉积的GO凝胶层，其中分配和沉积步骤包括剪切诱导的稀化; （c）通过X射线衍射测定，从沉积的GO凝胶中除去流体介质以形成具有0.4nm至1.2nm的平面间距d002的GO层; 和（d）热处理GO层以在高于100℃的热处理温度下形成单一石墨烯材料，直到d002降低到0.3354nm至0.4nm的值，并且氧含量降低到更低超过5重量％。

95. 发明申请

US20140235123A1 Highly conducting and transparent film and process for producing same 审中-公开
标题翻译：高导电透明膜及其制造方法
公开(公告)号：US20140235123A1
公开(公告)日：2014-08-21
申请号：US13815316
申请日：2013-02-21
申请人： Yi-jun Lin , Aruna Zhamu , Bor Z. Jang
发明人： Yi-jun Lin , Aruna Zhamu , Bor Z. Jang
IPC分类号： H01B1/04 , H01B13/00
CPC分类号： H01B1/04 , B82Y30/00 , G06F3/041 , G06F2203/04103 , Y10T428/31678 , Y10T442/10
摘要： An optically transparent and electrically conductive film composed of metal nanowires or carbon nanotubes combined with pristine graphene with a metal nanowire-to-graphene or carbon nanotube-to-graphene weight ratio from 1/99 to 99/1, wherein the pristine graphene is single-crystalline and contains no oxygen and no hydrogen, and the film exhibits an optical transparence no less than 80% and sheet resistance no higher than 300 ohm/square. This film can be used as a transparent conductive electrode in an electro-optic device, such as a photovoltaic or solar cell, light-emitting diode, photo-detector, touch screen, electro-wetting display, liquid crystal display, plasma display, LED display, a TV screen, a computer screen, or a mobile phone screen.
摘要翻译：由金属纳米线或碳纳米管与原始石墨烯组合的光学透明和导电膜，其中金属纳米线对石墨烯或碳纳米管与石墨烯的重量比为1/99至99/1，其中原始石墨烯为单一不含氧而不含氢，膜的光学透明度不低于80％，薄层电阻不高于300欧姆/平方。该膜可以用作电光装置中的透明导电电极，例如光伏或太阳能电池，发光二极管，光电检测器，触摸屏，电润湿显示器，液晶显示器，等离子体显示器，LED 显示，电视屏幕，电脑屏幕或手机屏幕。

96. 发明授权

US08753740B2 Submicron-scale graphitic fibrils, methods for producing same and compositions containing same 有权
标题翻译：亚微米级石墨原纤维，其制造方法和含有它们的组合物
公开(公告)号：US08753740B2
公开(公告)日：2014-06-17
申请号：US12592970
申请日：2009-12-07
申请人： Aruna Zhamu , Bor Z. Jang
发明人： Aruna Zhamu , Bor Z. Jang
IPC分类号： B32B1/00
CPC分类号： H01G11/38 , C01B32/20 , D01D5/423 , D01F9/12 , D01F11/12 , Y02E60/13 , Y10T428/2918
摘要： The present invention provides a submicron-scaled graphitic fibril having a diameter or thickness less than 1 μm, wherein the fibril is free of continuous thermal carbon overcoat, free of continuous hollow core, and free of catalyst. The fibril is obtained by splitting a micron-scaled carbon fiber or graphite fiber along the fiber axis direction. The diameter or thickness is preferably less than 500 nm and can be greater or less than 100 nm. These graphitic fibrils exhibit exceptionally high electrical conductivity, thermal conductivity, elastic modulus, and strength. The present invention also provides several products that contain submicron graphitic fibrils: (a) paper, thin-film, mat, and web products; (b) rubber or tire products; (c) energy conversion or storage devices, such as fuel cells, lithium-ion batteries, and supercapacitors; (d) adhesives, inks, coatings, paints, lubricants, and grease products; (e) heavy metal ion scavenger; (f) absorbent (e.g., to recover spill oil); (g) sensors; (h) friction and brake components; (i) radiation-shield components; and (j) nanocomposite materials.
摘要翻译：本发明提供直径或厚度小于1μm的亚微米级石墨原纤，其中原纤维不含连续的热碳外涂层，不含连续的中空芯，并且不含催化剂。原纤维通过沿纤维轴线方向分裂微米级碳纤维或石墨纤维而获得。直径或厚度优选小于500nm，并且可以大于或小于100nm。这些石墨纤维表现出特别高的导电性，导热性，弹性模量和强度。本发明还提供了几种含有亚微米石墨原纤的产品：（a）纸，薄膜，垫和网产品; （b）橡胶或轮胎产品; （c）燃料电池，锂离子电池和超级电容器等能量转换或存储装置; （d）粘合剂，油墨，涂料，涂料，润滑剂和油脂产品; （e）重金属离子清除剂; （f）吸收剂（例如，以回收溢油）; （g）传感器; （h）摩擦和制动部件; （i）辐射屏蔽部件; 和（j）纳米复合材料。

97. 发明授权

US08728679B2 Laminated exfoliated graphite composite-metal compositions for fuel cell flow field plate or bipolar plate applications 有权
标题翻译：用于燃料电池流场板或双极板应用的层压剥离石墨复合金属组合物
公开(公告)号：US08728679B2
公开(公告)日：2014-05-20
申请号：US11807379
申请日：2007-05-29
申请人： Aruna Zhamu , Jinjun Shi , Jiusheng Guo , Bor Z. Jang
发明人： Aruna Zhamu , Jinjun Shi , Jiusheng Guo , Bor Z. Jang
IPC分类号： H01M8/24 , B32B7/02
CPC分类号： H01M8/0228 , H01M8/0206 , H01M8/0213 , H01M8/0226 , Y10T428/24942
摘要： An electrically conductive laminate composition for fuel cell flow field plate or bipolar plate applications. The laminate composition comprises at least a thin metal sheet having two opposed exterior surfaces and a first exfoliated graphite composite sheet bonded to the first of the two exterior surfaces of the metal sheet wherein the exfoliated graphite composite sheet comprises: (a) expanded or exfoliated graphite and (b) a binder or matrix material to bond the expanded graphite for forming a cohered sheet, wherein the binder or matrix material is between 3% and 60% by weight based on the total weight of the first exfoliated graphite composite sheet. Preferably, the first exfoliated graphite composite sheet further comprises particles of non-expandable graphite or carbon in the amount of between 3% and 60% by weight based on the total weight of the non-expandable particles and the expanded graphite. Further preferably, the laminate comprises a second exfoliated graphite composite sheet bonded to the second surface of the metal sheet to form a three-layer laminate. Surface flow channels and other desired geometric features can be built onto the exterior surfaces of the laminate to form a flow field plate or bipolar plate. The resulting laminate has an exceptionally high thickness-direction conductivity and excellent resistance to gas permeation.
摘要翻译：一种用于燃料电池流场板或双极板应用的导电层压组合物。所述层叠组合物至少包括具有两个相对的外表面的薄金属片和与所述金属片的两个外表面中的第一外表面结合的第一剥离石墨复合片，其中所述剥离石墨复合片包括：（a）膨胀或剥离的石墨和（b）粘合剂或基质材料，以结合用于形成粘结片材的膨胀石墨，其中基于第一剥离石墨复合片材的总重量，粘合剂或基质材料为3重量％至60重量％。优选地，基于不可膨胀颗粒和膨胀石墨的总重量，第一剥离石墨复合片材还包含不可膨胀石墨或碳的颗粒，其量为3重量％至60重量％。进一步优选地，层压体包括结合到金属板的第二表面的第二剥离石墨复合片，以形成三层层压体。可以在层压板的外表面上形成表面流动通道和其它期望的几何特征，以形成流场板或双极板。所得到的层压体具有非常高的厚度方向导电性和优异的耐气体渗透性。

98. 发明申请

US20130213677A1 Surface-mediated cell-driven power tools and methods of operating same 有权
公开(公告)号：US20130213677A1
公开(公告)日：2013-08-22
申请号：US13385350
申请日：2012-02-16
申请人： Aruna Zhamu , Guorong Chen , Wei Xiong , Bor Z. Jang , Yanbo Wang , Qing Fang
发明人： Aruna Zhamu , Guorong Chen , Wei Xiong , Bor Z. Jang , Yanbo Wang , Qing Fang
IPC分类号： B25F5/00
CPC分类号： B25F5/00 , H01G11/06 , H01G11/50 , H01M4/133 , H01M6/5033 , H01M10/0525 , H01M10/465 , H01M12/005 , H01M14/00 , H01M16/00 , H01M2220/30 , H02M3/1582 , Y02B70/1483 , Y02E60/122 , Y02E60/13 , Y02P70/54
摘要： A portable power tool comprises an electric motor, actuator, or light-emitting hardware and a rechargeable power source connected to the electric motor, actuator, or light-emitting hardware, wherein the power source contains at least a surface-mediated cell (SMC). The power tools include, but are not limited to, impact driver, air compressor, alligator shear, angle grinder, band saw, belt sander, biscuit joiner, ceramic tile cutter tile saw, chainsaw, circular saw, concrete saw, cold saw, crusher, diamond blade, diamond tools, disc sander, drill, floor sander, grinding machine, heat gun, impact wrench, jackhammer, jointer, jigsaw, lathe, miter saw, nail gun, needle scaler, torque wrench, powder-actuated tools, power wrench, radial arm saw, random orbital sander, reciprocating saw, rotary reciprocating saw, rotary tool, sabre saw, sander, scroll saw, steel cut off saw, table saw, thickness planer, trimmer, wall chaser, wood router, or flashlight.

99. 发明授权

US08501307B2 Recompressed exfoliated graphite articles 有权
公开(公告)号：US08501307B2
公开(公告)日：2013-08-06
申请号：US11899009
申请日：2007-09-04
申请人： Aruna Zhamu , Jinjun Shi , Jiusheng Guo , Bor Z. Jang
发明人： Aruna Zhamu , Jinjun Shi , Jiusheng Guo , Bor Z. Jang
IPC分类号： B32B9/00 , H01B1/04 , H01B1/06
CPC分类号： H01B1/04
摘要： This invention provides an electrically conductive, less anisotropic, recompressed exfoliated graphite article comprising a mixture of (a) expanded or exfoliated graphite flakes; and (b) particles of non-expandable graphite or carbon, wherein the non-expandable graphite or carbon particles are in the amount of between about 3% and about 70% by weight based on the total weight of the particles and the expanded graphite flakes combined; wherein the mixture is compressed to form the article having an apparent bulk density of from about 0.1 g/cm3 to about 2.0 g/cm3. The article exhibits a thickness-direction conductivity typically greater than 50 S/cm, more typically greater than 100 S/cm, and most typically greater than 200 S/cm. The article, when used in a thin foil or sheet form, can be a useful component in a sheet molding compound plate used as a fuel cell separator or flow field plate. The article may also be used as a current collector for a battery, supercapacitor, or any other electrochemical cell.

100. 发明申请

US20130190956A1 Surface-mediated cell-powered vehicles and methods of operating same 有权
标题翻译：表面介导的细胞动力车辆和操作方法
公开(公告)号：US20130190956A1
公开(公告)日：2013-07-25
申请号：US13374894
申请日：2012-01-23
申请人： Aruna Zhamu , Guorong Chen , Xiqing Wang , Bor Z. Jang , Yanbo Wang , Qing Fang
发明人： Aruna Zhamu , Guorong Chen , Xiqing Wang , Bor Z. Jang , Yanbo Wang , Qing Fang
IPC分类号： B60L11/18 , B62D61/06 , B62D61/02 , B64D27/02 , B60W20/00 , B61C7/04 , B63H21/17 , B62M6/40 , G06F19/00
CPC分类号： B61C7/04 , B60L11/1811 , B60L2200/26 , B60W20/00 , B62M6/90 , B63H21/17 , B64D2041/005 , Y02T10/7011 , Y02T10/7016 , Y02T10/7072 , Y02T30/16 , Y02T30/40 , Y02T90/127 , Y02T90/14 , Y02T90/36
摘要： This invention provides a vehicle powered by a surface-mediated cell (SMC)-based power source, comprising a vehicle frame, at least a wheel supporting the frame or a propeller connected to the frame, a drive unit connected to the wheel or propeller, and a power source electrically connected to the drive unit, wherein the power source contains at least a surface-mediated cell. The vehicle can be a micro-EV (using the SMC for the stop-start function), HEV, plug-in HEV, all-electric vehicle, power-assisted bicycle, scooter, motorcycle, tricycle, automobile, wheelchair, fork lift, golf cart, specialty vehicle, bus, truck, train, rapid-transit vehicle, boat, or air vehicle. The ultra-high power density enables the SMC to provide pulsed power or increased current demands when the vehicle is accelerating or hill-climbing. The SMC also enables the power source to recuperate the braking energy when the vehicle decelerates, brakes, or simply moves down-hill.
摘要翻译：本发明提供了一种由基于表面介质单元（SMC）的电源供电的车辆，其包括车架，至少一个支撑框架的轮子或连接到该框架的螺旋桨，连接到车轮或螺旋桨的驱动单元，以及电连接到所述驱动单元的电源，其中所述电源至少包含表面介导的单元。车辆可以是微型EV（使用SMC进行停止启动功能），HEV，插电式HEV，全电动车，动力辅助自行车，踏板车，摩托车，三轮车，汽车，轮椅，叉车，高尔夫球车，特种车辆，公共汽车，卡车，火车，快速运输车辆，船只或机动车辆。超高功率密度使SMC能够在车辆加速或爬坡时提供脉冲功率或增加电流需求。当车辆减速，制动或简单地向下移动时，SMC还使电源能够恢复制动能量。

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