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    • 94. 发明授权
    • Extrusion coatable polyester film having an aminofunctional silane
primer, and extrusion coated laminates thereof
    • 具有氨基官能硅烷底漆的挤出可涂覆聚酯薄膜及其挤出涂布层压材料
    • US4939035A
    • 1990-07-03
    • US240701
    • 1988-09-06
    • Howard W. Swofford
    • Howard W. Swofford
    • B29C47/04B29C55/12B29K67/00B29L9/00B32B27/36C08J7/04
    • C08J7/042C08J2367/02C08J2479/00C08J2483/02Y10T428/273Y10T428/31663Y10T428/31667Y10T428/31786
    • Oriented polyester film primer coated with a hydrolyzed aminosilane IS disclosed. The aminosilanes in the unhydrolyzed state have the formula:(R.sup.1).sub.a Si(R.sup.2).sub.b (R.sup.3).sub.cwherein R.sup.1 is a functional group with at least one primary amino group; R.sup.2 is a hydrolyzeable group such as a lower alkoxy group, an acetoxy group, or a halide; and R.sup.3 is a nonreactive, nonhydrolyzeable group such as a lower alkyl or a phenyl group; with (a) being greater than or equal to 1; (b) being greater than or equal to 1; (c) being greater than or equal to zero; and with a+b+c=4. The preferred silane is N-beta-(aminoethyl)-gamma-aminopropyltrimethoxysilane having the formula:H.sub.2 N(CH.sub.2).sub.2 NH(CH.sub.2).sub.3 Si(OCH.sub.3).sub.3.The hydrolyzed aminosilane is applied to the film as an aqueous solution at any suitable stage during manufacture of the film, i.e., before or during the stretching operation, or it may also be applied to the finished film. The resultant primed polyester film is found to exhibit excellent adhesion to other polymeric materials and can be readily laminated to other polymeric films.
    • 公开了涂覆有水解氨基硅烷的定向聚酯薄膜底漆。 未水解状态的氨基硅烷具有下式:(R1)aSi(R2)b(R3)c其中R1是具有至少一个伯氨基的官能团; R2是可水解基团,例如低级烷氧基,乙酰氧基或卤化物; R3是非反应性的非水解性基团,例如低级烷基或苯基; (a)大于或等于1; (b)大于或等于1; (c)大于或等于零; 并且a + b + c = 4。 优选的硅烷是具有下式的N-β-(氨基乙基) - γ-氨基丙基三甲氧基硅烷:H 2 N(CH 2)2 NH(CH 2)3 Si(OCH 3)3。 水解的氨基硅烷作为水溶液在制造薄膜期间的任何合适的阶段,即在拉伸操作之前或期间,作为水溶液施加,或者也可以施加到成品薄膜上。 发现所得的底漆聚酯膜对其它聚合物材料表现出优异的粘附性,并且可以容易地层压到其它聚合物膜上。
    • 97. 发明授权
    • Accumulator extrusion head for producing striped parisons
    • 用于生产条纹型坯的蓄能器挤压头
    • US4874305A
    • 1989-10-17
    • US266689
    • 1988-11-03
    • Paul E. McGillFrank J. Pitigliano
    • Paul E. McGillFrank J. Pitigliano
    • B29C47/04B29C47/20B29C47/70
    • B29C47/062B29C47/20B29C47/28B29C47/54B29C47/702B29C47/0023B29C47/0033
    • An accumulator extrusion head assembly for producing a parison having at least one stripe extending longitudinally thereof comprises an extrusion head body member having an opening extending inwardly from a nozzle outlet end and a mandrel positioned in the body member to define a generally annular extrusion chamber terminating in an annular outlet nozzle. An annular ram is mounted in the extrusion chamber and has a forward end positioned for reciprocation toward and away from the outlet nozzle. A first supply extruder is connected to the body member through first passages for supplying a first extrusion material to the annular extrusion chamber. A second supply extruder is also connected to the body member through second passages for supplying a second extrusion material to the annular extrusion chamber. The second passages include a supply outlet in the forward end of the ram for providing a radially continuous stripe of the second extrusion material to the annular extrusion chamber and, a connecting passage for maintaining a flow connection between the second extruder and the supply outlet during reciprocation of the ram.
    • 一种用于生产具有沿其纵向延伸的至少一个条纹的型坯的型坯的蓄压器挤压头组件包括具有从喷嘴出口端向内延伸的开口的挤出头本体构件和位于主体构件中的心轴,以限定终止于 环形出口喷嘴。 环形冲头安装在挤压室中,并且具有定位成朝向和远离出口喷嘴往复运动的前端。 第一供应挤出机通过用于将第一挤出材料供应到环形挤出室的第一通道连接到主体构件。 第二供应挤出机还通过用于将第二挤出材料供应到环形挤出室的第二通道连接到主体构件。 所述第二通道包括在所述柱塞的前端中的供应出口,用于将所述第二挤出材料的径向连续的条带提供给所述环形挤压室,以及连接通道,用于在往复运动期间保持所述第二挤出机与所述供应出口之间的流动连接 的公羊