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    • 91. 发明授权
    • Electrostatic dissipative blends of PVC, polyetheramides and an impact
modifier
    • PVC,聚醚酰胺和抗冲改性剂的静电消散共混物
    • US5298558A
    • 1994-03-29
    • US888927
    • 1992-06-02
    • Francis R. SullivanElaine A. MertzelCraig L. Shoemaker
    • Francis R. SullivanElaine A. MertzelCraig L. Shoemaker
    • C08L27/06C08L33/24C08L35/00C08L35/06C08L51/04C08L55/00C08L55/02C08L71/00C08L71/02C08L77/00C08L87/00C08L101/00C09K3/16B32B1/08C08L67/02
    • C08L27/06C08L101/00C08L55/02C08L87/005Y10S524/91Y10T428/1379
    • The present invention relates to electrostatic dissipative impact modified polymeric compositions comprising an effective amount of a chain extended block copolymer, polyvinyl halide and no more than 10 weight parts of a polymeric impact modifier per 100 weight parts of polyvinyl chloride. The chain extended block copolymer is formed from reacting a di-functional polyether with a chain extender which is a condensate selected from the group consisting of polyundecanolactam, polydodecanolactam, poly(11-aminoundecanoic acid) and (12-aminododecanoic acid). The compounds further comprise a heat distortion modifier which does not interfere with ESD properties and is selected from the group consisting of styrene-acrylonitrile copolymer, alpha methyl styrene-styrene-acrylonitrile terpolymer, a polymer of alpha methyl styrene-styrene-N-cyclohexyl maleimide, N-phenylmaleimide, imidized polymethyl methacrylate, post-chlorinated polyvinyl chloride, styrene-maleic anhydride polymer, imidized styrene-maleic anhydride polymer, acrylic-imide copolymer, acrylonitrile-methylmethacrylate copolymer, acrylonitrile-acrylate-polybutadiene graft copolymer, alpha methyl styrene-methylmethacrylate-acrylonitrile terpolymer, alpha-methyl styrene-styrene-methylmethacrylate terpolymer, alpha methyl styrene-methylmethacrylate copolymer, alpha methyl styrene-acrylonitrile copolymer, alpha methyl styrene-methylmethacrylate graft copolymer on polyacrylate rubber, polycarbonate, and brominated polycarbonate.
    • 本发明涉及静电消散冲击改性聚合物组合物,其包含有效量的链延长嵌段共聚物,聚卤乙烯和每100重量份聚氯乙烯不超过10重量份聚合抗冲改性剂。 链延长嵌段共聚物由二官能聚醚与扩链剂反应形成,扩链剂是选自聚十一内酰胺,聚十二内酰胺,聚(11-氨基十一烷酸)和(12-氨基十二烷酸)的缩合物。 所述化合物还包含不干扰ESD性质的热变形改性剂,其选自苯乙烯 - 丙烯腈共聚物,α-甲基苯乙烯 - 苯乙烯 - 丙烯腈三元共聚物,α甲基苯乙烯 - 苯乙烯-N-环己基马来酰亚胺 N-苯基马来酰亚胺,酰亚胺化聚甲基丙烯酸甲酯,后氯化聚氯乙烯,苯乙烯 - 马来酸酐聚合物,酰亚胺化苯乙烯 - 马来酸酐聚合物,丙烯酰胺共聚物,丙烯腈 - 甲基丙烯酸甲酯共​​聚物,丙烯腈 - 丙烯酸酯 - 聚丁二烯接枝共聚物,α-甲基苯乙烯 - 甲基丙烯酸甲酯 - 丙烯腈三元共聚物,α-甲基苯乙烯 - 苯乙烯 - 甲基丙烯酸甲酯三元共聚物,α-甲基苯乙烯 - 甲基丙烯酸甲酯共​​聚物,α-甲基苯乙烯 - 丙烯腈共聚物,α-甲基苯乙烯 - 甲基丙烯酸甲酯接枝共聚物,聚丙烯酸酯橡胶,聚碳酸酯和溴化聚碳酸酯。
    • 92. 发明授权
    • Electrically conductive quaternary ammonium and metal salt coating
composition
    • 导电季铵盐和金属盐涂料组合物
    • US5268407A
    • 1993-12-07
    • US910602
    • 1992-07-08
    • Naohito HayashiYuji Kawamura
    • Naohito HayashiYuji Kawamura
    • B41M5/00B41M5/50B41M5/52C08K3/16C08K3/22C08K3/24C08K5/18C08L33/04C08L33/14C08L33/24C08L33/26C09D5/24C09K3/16D21H19/20G03G7/00C08J5/10C08K5/04C08K5/09C08L27/00
    • G03G7/004C08K5/18C09D5/24
    • The present invention is an electrically conductive coating composition comprising, as indispensable components, a quaternary ammonium polymer and a polyvalent metal salt. As the quaternary ammonium polymer there can be preferably used a polymer containing at least 30 weight % of quaternary ammonium monomer unit such as 2-methacryloyloxyethyltrimethylammonium chloride or 2-methacryloyloxyethyltrimethylammonium methylsulfate. As the polyvalent metal salt there can be used sulfate, hydrochloride, nitrate or the like of at least one polyvalent metal selected from the group consisting of iron, copper, cobalt, calcium, zinc, lead, nickel, manganese, aluminum, magnesium, titanium, cadmium, chromium, barium and tin. The electrically conductive coating composition of the present invention is extremely excellent in water retention characteristics and therefore has sufficient electric conductivity under circumstances of low humidity even at low coating weight. Thus, according to the present electrically conductive coating composition there can be obtained an electrostatic recording paper which can be used under circumstances of low humidity without thickening the conductive layer.
    • 本发明是包含季铵聚合物和多价金属盐作为不可或缺的成分的导电性涂料组合物。 作为季铵聚合物,可优选使用含有至少30重量%的季铵单体单元如2-甲基丙烯酰氧基乙基三甲基氯化铵或2-甲基丙烯酰氧基乙基三甲基甲基硫酸铵的聚合物。 作为多价金属盐,可以使用选自铁,铜,钴,钙,锌,铅,镍,锰,铝,镁,钛中的至少一种多价金属的硫酸盐,盐酸盐,硝酸盐等 ,镉,铬,钡和锡。 本发明的导电性涂料组合物的保水特性极其优异,因此即使在低涂层重量的情况下也具有足够的导电性。 因此,根据本发明的导电涂料组合物,可以获得可以在低湿度的情况下使用而不使导电层增厚的静电记录纸。