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    • 138. 发明授权
    • Device and method for measuring relative concentration changes in gas stream components
    • 用于测量气流分量相对浓度变化的装置和方法
    • US3793158A
    • 1974-02-19
    • US3793158D
    • 1971-02-05
    • DOW CHEMICAL CO
    • HAMILTON C
    • G01N27/416G01N27/46
    • G01N27/4162
    • A device for detecting and measuring fluctuations on a continuous basis and at most any concentration level, in a flowing gas stream, of a reactive component such as, oxygen, chlorine, bromine, iodine, sulfur dioxide, sulfur trioxide, hydrogen sulfide, carbon monoxide and compatible mixtures thereof utilizes as the detecting element a concentration cell made from two electrodes formed of substantially identical metal, a reference electrode and a sample electrode, at least the latter being foraminous in nature, an aqueous electrolyte containing a mobile soluble ion, the electrolyte contacting substantial areas of both electrodes, a substantially constant atmosphere or a lack of any atmosphere around the reference electrode, an enclosed zone around the sample electrode and means for bringing the gas stream to and from the enclosed zone. No impressed voltage or amperage is applied. The small potential difference across the electrodes generated by chemical equilibrium shifts in the concentration cell caused by fluctuations in the gas stream composition are measured by a sensitive Wheatstone bridge or a microammeter or other sensitive detection means.
    • 用于检测和测量流动气流中的反应组分如氧,氯,溴,碘,二氧化硫,三氧化硫,硫化氢,一氧化碳的连续基础和至多任何浓度水平的波动的装置 其兼容的混合物作为检测元件使用由基本上相同的金属,参考电极和样品电极形成的两个电极制成的浓度单元,至少后者在本质上是多孔的,含有可移动的可溶性离子的水性电解质,电解质 接触两个电极的大部分区域,基本上恒定的气氛或在参比电极周围没有任何气氛,围绕样品电极的封闭区域和用于使气流进入和离开封闭区域的装置。 不施加电压或电流强度。 通过敏感的惠斯通电桥或微电表或其他敏感检测手段测量由气流组成中的波动引起的浓度池中化学平衡移动产生的电极间的电位差小。