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11. 发明申请

US20170137935A1 METHOD FOR GROWING VERTICALLY ORIENTED SINGLE-WALLED CARBON NANOTUBES WITH THE SAME ELECTRONIC PROPERTIES AND FOR REPRODUCING SINGLE-WALLED CARBON NANOTUBES WITH THE SAME ELECTRONIC PROPERTIES 审中-公开
公开(公告)号：US20170137935A1
公开(公告)日：2017-05-18
申请号：US15321861
申请日：2015-06-24
申请人： TECHNISCHE UNIVERSITÄT DRESDEN
发明人： Viktor BEZUGLY , Eugenia BEZUGLY , Vyacheslav KHAVRUS , Denis KRYLOV , Gianaurelio CUNIBERTI
IPC分类号： C23C16/26 , C23C16/50 , C23C16/455
CPC分类号： C23C16/26 , B82Y30/00 , B82Y40/00 , C01B32/158 , C01B32/174 , C01B2202/02 , C01B2202/08 , C01B2202/22 , C01B2202/36 , C23C16/455 , C23C16/50 , Y10S977/751 , Y10S977/842 , Y10S977/932
摘要： The present invention relates to a method of reproducing at least one single-walled carbon nanotube (3) having predefined electronic properties or a plurality of single-walled carbon nanotube (3) having the same electronic properties. A dispersion (2) is produced for this purpose and carbon nanotubes (3) contained in the dispersion are processed into fragments (6) by energy input. These fragments (6) are applied to and oriented on a carrier (7). The fragments (6) are subsequently extended by chemical vapor deposition and the originally present carbon nanotubes (3) are thus reproduced.

12. 发明授权

US09643944B2 Nucleophilic substitution of carbon nanotubes 有权
公开(公告)号：US09643944B2
公开(公告)日：2017-05-09
申请号：US13753396
申请日：2013-01-29
申请人： NATIONAL RESEARCH COUNCIL OF CANADA
发明人： Benoit Simard , Jingwen Guan
IPC分类号： C07D301/27 , B82Y30/00 , B82Y40/00 , C01B31/02 , C08F8/02 , C08F257/02 , C08F265/04 , C08F281/00 , C08F291/00 , C08F293/00 , C08F297/00 , C09C1/44 , C07C29/132
CPC分类号： C07D301/27 , B82Y30/00 , B82Y40/00 , C01B32/174 , C01B2202/02 , C01B2202/28 , C01P2004/13 , C07C29/132 , C08F8/02 , C08F257/02 , C08F265/04 , C08F281/00 , C08F291/00 , C08F293/005 , C08F297/00 , C09C1/44 , Y10S977/847 , C08F220/18 , C08F212/08
摘要： Compounds are attached to carbon nanotubes (CNT) by a process which comprises: subjecting surface treated CNTs which have been treated to induce negatively charged surface groups thereon, to nucleophilic substitution reaction with a compound carrying a functional group capable of reacting with the negatively charged groups on the CNT surface, whereby the compound chemically bonds to the CNT. The surface CNT treatment may be reduction. The compounds which are bonded to the CNT may be epoxy resins, bonded directly or through a spacer group. Bi-functional CNTs, grafted to both epoxy resins and other polymers such as polystyrene, are also made by this process.

13. 发明授权

US09617158B2 Cohesive assembly of carbon and its application 有权
公开(公告)号：US09617158B2
公开(公告)日：2017-04-11
申请号：US14106364
申请日：2013-12-13
申请人： YAZAKI CORPORATION
发明人： Satyabrata Raychaudhuri , Yongan Yan , Leonid Grigorian
IPC分类号： H01G11/36 , C01B31/02 , H01G11/38 , H01G11/86 , H01M4/04 , H01M4/133 , H01M4/62 , H01M4/86 , H01M10/0525 , H01M8/0234 , H01G9/00 , H01M4/66 , H01M4/88 , H01M4/90 , B82Y30/00 , B82Y40/00 , H01G11/28 , H01M4/1393 , H01G11/68
CPC分类号： H01M4/133 , B82Y30/00 , B82Y40/00 , C01B32/05 , C01B32/158 , C01B32/168 , C01B32/174 , C01B2202/02 , C01B2202/22 , H01G11/28 , H01G11/36 , H01G11/38 , H01G11/68 , H01G11/86 , H01M4/0402 , H01M4/0404 , H01M4/0471 , H01M4/131 , H01M4/1393 , H01M4/525 , H01M4/5825 , H01M4/587 , H01M4/625 , H01M4/661 , H01M4/663 , H01M4/8605 , H01M4/8807 , H01M4/8878 , H01M4/9083 , H01M8/0234 , H01M8/1004 , H01M8/1007 , H01M10/0525 , H01M2004/027 , H01M2008/1095 , H01M2220/20 , H01M2220/30 , H01M2250/20 , Y02E60/122 , Y02E60/13 , Y02T90/32 , Y10S977/75 , Y10S977/842 , Y10S977/892 , Y10S977/948
摘要： Cohesive carbon assemblies are prepared by obtaining a carbon starting material in the form of powder, particles, flakes, or loose agglomerates, dispersing the carbon in a selected organic solvent by mechanical mixing and/or sonication, and substantially removing the organic solvent, typically by evaporation, whereby the cohesive assembly of carbon is formed. The method is suitable for preparing free-standing, monolithic assemblies of carbon nanotubes in the form of films, wafers, or discs, having high carbon packing density and low electrical resistivity. The method is suitable for preparing adherent cohesive carbon assemblies on substrates comprising various materials. The assemblies have various potential applications, such as electrodes or current collectors in electrochemical capacitors, fuel cells, and batteries, or as electromagnetic interference shielding materials.

14. 发明申请

US20170029634A1 METHOD FOR UNIFORM DISPERSION OF SINGLE-WALL CARBON NANOTUBES 有权
标题翻译：用于均匀分散单壁碳纳米管的方法
公开(公告)号：US20170029634A1
公开(公告)日：2017-02-02
申请号：US15106733
申请日：2014-11-28
申请人： BEIJING AGLAIA TECHNOLOGY DEVELOPMENT CO.,LTD.
发明人： Haiyan HAO , Xiliang CAO , Lei DAI , Lifei CAI
IPC分类号： C09D5/24 , H01B1/04 , C01B31/02
CPC分类号： C09D5/24 , B82Y30/00 , B82Y40/00 , C01B32/17 , C01B32/174 , C01B2202/02 , C08K3/041 , C09D7/70 , H01B1/04 , H01L51/444 , Y02E10/549 , Y10S977/75 , Y10S977/845 , Y10S977/932
摘要： Provided is a method for uniform dispersion of single-wall carbon nanotubes, comprising: (1) dispersing single-wall carbon nanotube powder in a low-boiling point alcohol or water or DMF, then placing into a UV bench for ultraviolet irradiation and oxidation; (2) after cleaning the carbon nanotubes in the UV bench, using a strong acid to carry out an oxidation reaction, then washing by centrifugation; (3) after cleaning with strong acid, subjecting the single-wall carbon nanotubes to ethanol or water ultrasonic dispersion 2-3 times, washing by centrifugation, then dissolving in low-boiling point alcohol or water or DMF solution to obtain a single-wall carbon nanotube dispersion. By means of the present method, the entire surface of a carbon nanotube is grafted with a functionalized group, achieving solubility of single-wall carbon nanotubes; further, high-performance carbon nanotube composite flexible transparent electrode materials can be prepared, which have high transmittance and low sheet resistance.
摘要翻译：提供了一种单壁碳纳米管均匀分散的方法，包括：（1）将单壁碳纳米管粉末分散在低沸点醇或水或DMF中，然后放入紫外线台架进行紫外线照射和氧化; （2）在UV台架上清洁碳纳米管后，使用强酸进行氧化反应，然后通过离心洗涤; （3）用强酸清洗后，将单壁碳纳米管经乙醇或水超声波分散2-3次，离心洗涤，然后溶于低沸点醇或水或DMF溶液中，得到单壁碳纳米管分散体。通过本方法，用功能化基团接枝碳纳米管的整个表面，达到单壁碳纳米管的溶解性; 此外，可以制备具有高透射率和低薄层电阻的高性能碳纳米管复合柔性透明电极材料。

15. 发明授权

US09550907B2 Carbon nanostructure preblends and their applications 有权
标题翻译：碳纳米结构预混料及其应用
公开(公告)号：US09550907B2
公开(公告)日：2017-01-24
申请号：US14633458
申请日：2015-02-27
申请人： GATES CORPORATION
发明人： Donald James Burlett , Henning Richter , Ramesh Sivarajan , Viktor Vejins
IPC分类号： C08K3/04 , C09D123/16 , C01B31/02 , C08K5/03 , C09C1/44 , C09C1/46 , C09C1/48 , C08J3/20 , C08J3/22
CPC分类号： C08J3/22 , C01B32/05 , C01B32/152 , C01B32/168 , C01B32/174 , C01B2202/02 , C01B2202/06 , C01P2002/82 , C01P2004/03 , C01P2004/13 , C01P2004/133 , C01P2004/84 , C08J3/20 , C08J3/223 , C08J2300/26 , C08J2323/16 , C08J2323/20 , C08J2323/22 , C08K3/04 , C08K3/041 , C08K3/042 , C08K3/045 , C08K5/03 , C08K2201/011 , C09C1/0081 , C09C1/44 , C09C1/46 , C09C1/48 , C09C1/58 , C09D123/16 , Y02E60/13 , C08L23/16
摘要： A method for preparing a “preblend” of nano-structured carbon, such as nanotubes, fullerenes, or graphene, and a particulate solid, such as carbon black, graphitic particles or glassy carbon involving wet-mixing and followed by optional drying to remove the liquid medium. The preblend may be in the form of a core-shell powder material with the nano-structured carbon as the shell on the particulate solid core. The preblend may provide particularly improved dispersion of single-wall nanotubes in ethylene-α-olefin elastomer compositions, resulting in improved reinforcement from the nanotubes. The improved elastomer compositions may show simultaneous improvement in both modulus and in elongation at break. The elastomer compositions may be formed into useful rubber articles.
摘要翻译：制备纳米结构碳如“纳米管”，“富勒烯”或“石墨烯”的“预混物”的方法，以及颗粒状固体，如碳黑，石墨颗粒或玻璃状碳，涉及湿法混合，然后任选干燥以除去液体介质。预混物可以是核 - 壳粉末材料的形式，其中纳米结构碳作为颗粒状固体核上的壳。预混物可以提供特别改进的单壁纳米管在乙烯-α-烯烃弹性体组合物中的分散性，从而提高了纳米管的强化。改进的弹性体组合物可以显示模量和断裂伸长率的同时改善。弹性体组合物可形成有用的橡胶制品。

16. 发明申请

US20160340193A1 CARBON NANOTUBE FIBER AND METHOD FOR PRODUCING SAME 有权
标题翻译：碳纳米纤维及其制造方法
公开(公告)号：US20160340193A1
公开(公告)日：2016-11-24
申请号：US15114581
申请日：2015-01-29
申请人： ZEON CORPORATION
发明人： Mitsugu UEJIMA
IPC分类号： C01B31/02 , D01F9/12
CPC分类号： C01B32/158 , C01B32/174 , C01B2202/02 , D01F9/12
摘要： A carbon nanotube fiber is provided that that has excellent properties such as electrical conductivity, thermal conductivity, and mechanical characteristics. The carbon nanotube fiber includes an assembly of a plurality of carbon nanotubes. The plurality of carbon nanotubes includes one or more carbon nanotubes having at least partially collapsed structures. Furthermore, a method for producing a carbon nanotube fiber is provided that includes spinning a carbon nanotube dispersion liquid containing a plurality of carbon nanotubes including one or more carbon nanotubes having at least partially collapsed structures, a dispersant, and a solvent by extruding the carbon nanotube dispersion liquid into a coagulant liquid.
摘要翻译：提供具有优异的性能如导电性，导热性和机械特性的碳纳米管纤维。碳纳米管纤维包括多个碳纳米管的组件。多个碳纳米管包括具有至少部分折叠结构的一个或多个碳纳米管。此外，提供一种碳纳米管纤维的制造方法，其包括通过挤出碳纳米管来纺丝含有多个碳纳米管的碳纳米管分散液，所述碳纳米管包含一个或多个具有至少部分塌陷结构的碳纳米管，分散剂和溶剂分散液进入凝结液。

17. 发明申请

US20160332884A1 CARBON NANOTUBE FREESTANDING MEMBRANE, PROCESS FOR PRODUCTION OF THE SAME, COMPOSITES HAVING CARBON NANOTUBE MEMBRANES AND PROCESS FOR PRODUCTION THEREOF 审中-公开
标题翻译：碳纳米管自动化膜，其制造方法，具有碳纳米管膜的复合材料及其生产方法
公开(公告)号：US20160332884A1
公开(公告)日：2016-11-17
申请号：US15219112
申请日：2016-07-25
申请人： The University of Tokyo
发明人： Shigeo Maruyama , Yoichi Murakami
IPC分类号： C01B31/02 , C04B35/622 , C04B35/52
CPC分类号： C04B35/52 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B32/168 , C01B2202/02 , C01B2202/06 , C01B2202/08 , C01B2202/34 , C01B2202/36 , C04B35/62222 , Y10S977/75 , Y10S977/752 , Y10S977/843 , Y10T428/26
摘要： The invention provides a composite comprising a substrate and a membrane of vertically aligned carbon nanotubes formed on the substrate which membrane is independent of the material of the substrate and a process for the production of the same. A process for producing the first composite comprising the first substrate and vertically aligned carbon nanotubes formed on the first substrate which comprises the step (a) of preparing the second composite comprising the second substrate made of quartz or silicon and vertically aligned carbon nanotubes formed on the second substrate, the step (b) of subjecting the second composite to water immersion wherein the temperature (Tw) of the water is higher than the temperature (Tc) of the second composite with a temperature difference ΔT (=Tw−Tc) of at least 25° C. to make the carbon nanotubes peel off the second substrate and arrange them either in water or on the surface thereof, and the step (c) of arranging the resulting vertically aligned carbon nanotubes on the first substrate.
摘要翻译：本发明提供了一种复合材料，其包括基材和形成在基材上的垂直取向的碳纳米管的膜，该膜独立于基材的材料及其制备方法。一种制备第一复合材料的方法，包括形成在第一基板上的第一基板和垂直排列的碳纳米管，其包括制备第二复合物的步骤（a），其包括由石英或硅制成的第二基板和在其上形成的垂直排列的碳纳米管第二基板，使第二复合物进行水浸的步骤（b），其中水的温度（Tw）高于第二复合材料的温度（Tc），温度差ΔT（= Tw-Tc）为at 至少25℃以使碳纳米管从第二衬底上剥离并将它们布置在水中或其表面上，以及将所得到的垂直排列的碳纳米管排列在第一衬底上的步骤（c）。

18. 发明授权

US09487877B2 Contact metallization of carbon nanotubes 有权
标题翻译：接触碳纳米管的金属化
公开(公告)号：US09487877B2
公开(公告)日：2016-11-08
申请号：US12024635
申请日：2008-02-01
申请人： Aaron D. Franklin , Matthew R. Maschmann , Timothy S. Fisher , Timothy D. Sands
发明人： Aaron D. Franklin , Matthew R. Maschmann , Timothy S. Fisher , Timothy D. Sands
IPC分类号： C25D5/02 , C25D11/04 , C01B31/02 , C25D7/00 , B82Y10/00 , B82Y30/00 , B82Y40/00 , C25D5/18
CPC分类号： C25D7/00 , B82Y10/00 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B32/168 , C01B2202/02 , C01B2202/08 , C25D5/02 , C25D5/18 , C25D11/045
摘要： In one embodiment, SWNTs are synthesized from an embedded catalyst in a modified porous anodic alumina (PAA) template. Pd is electrodeposited into the template to form nanowires that grow from an underlying conductive layer beneath the PAA and extend to the initiation sites of the SWNTs within each pore. Individual vertical channels of SWNTs are created, each with a vertical Pd nanowire back contact. Further Pd deposition results in annular Pd nanoparticles that form on portions of SWNTs extending onto the PAA surface. Two-terminal electrical characteristics produce linear I-V relationships, indicating ohmic contact in the devices.
摘要翻译：在一个实施方案中，SWNT由改性多孔阳极氧化铝（PAA）模板中的嵌入式催化剂合成。将Pd电沉积到模板中以形成从PAA下面的下面的导电层生长并延伸到每个孔内的SWNT的起始位点的纳米线。创建SWNT的单个垂直通道，每个垂直通道具有垂直的Pd纳米线背接触。进一步的Pd沉积导致在延伸到PAA表面上的SWNT的部分上形成环状Pd纳米颗粒。两端电特性产生线性I-V关系，表示器件中的欧姆接触。

19. 发明授权

US09468911B2 Catalyst for preparing chiral selective and conductive selective single-walled carbon nanotube, preparation method and application thereof 有权
标题翻译：用于制备手性选择性和导电性选择性单壁碳纳米管的催化剂，其制备方法和应用
公开(公告)号：US09468911B2
公开(公告)日：2016-10-18
申请号：US14414098
申请日：2013-07-10
申请人： PEKING UNIVERSITY
发明人： Yan Li , Feng Yang , Fei Peng , Juan Yang
IPC分类号： B01J23/888 , C01B31/02 , B01J23/34 , B01J23/30 , B01J37/08 , B01J37/18 , B01J23/889 , B01J23/36 , B01J23/652 , B01J23/89 , B82Y40/00
CPC分类号： B01J23/888 , B01J23/30 , B01J23/36 , B01J23/6527 , B01J23/8892 , B01J23/8993 , B01J37/08 , B01J37/18 , B82Y40/00 , C01B31/0233 , C01B32/162 , C01B2202/02 , C01B2202/22
摘要： It relates to a type of catalysts for preparation of chirality-selective and conductivity-selective single-walled carbon nanotubes. The catalysts have chemical compositions of ABy, wherein A is the metal tungsten (W), B stands for one or more metals selected from a group consisting of the transition metals manganese, iron, cobalt, copper, zinc, chromium, vanadium, rhodium, ruthenium, palladium, platinum, gold, silver, osmium, iridium, and the lanthanide rare earth metals, and y is in the range of 0.01-20.0. This catalyst can be used to catalyze the growth of single-walled carbon nanotubes with desired chirality and conductivity.
摘要翻译：它涉及一种用于制备手性选择性和导电性选择性单壁碳纳米管的催化剂。催化剂具有ABy的化学组成，其中A是金属钨（W），B代表一种或多种选自过渡金属锰，铁，钴，铜，锌，铬，钒，铑，钌，钯，铂，金，银，锇，铱和镧系稀土金属，y在0.01-20.0的范围内。该催化剂可用于以期望的手性和电导率催化单壁碳纳米管的生长。

20. 发明授权

US09425405B1 Continuous, floating evaporative assembly of aligned carbon nanotubes 有权
标题翻译：对准碳纳米管的连续，浮动蒸发组装
公开(公告)号：US09425405B1
公开(公告)日：2016-08-23
申请号：US14619465
申请日：2015-02-11
申请人： Wisconsin Alumni Research Foundation
发明人： Michael Scott Arnold , Harold T. Evensen , Gerald Joseph Brady , Padma Gopalan , Yongho Joo
IPC分类号： H01L51/00 , C01B31/02 , C09D11/52 , C09D11/106 , B05D1/18 , H01L29/06 , H01L29/78
CPC分类号： H01L51/0039 , B05D1/18 , B05D1/202 , C01B32/16 , C01B32/174 , C01B2202/02 , C09D11/037 , C09D11/106 , C09D11/52 , H01L51/0007 , H01L51/0043 , H01L51/0048 , H01L51/0558 , H01L51/0566
摘要： High density films of semiconducting single-walled carbon nanotubes having a high degree of nanotube alignment are provided. Also provided are methods of making the films and field effect transistors (FETs) that incorporate the films as conducting channel materials. The single-walled carbon nanotubes are deposited from a thin layer of organic solvent containing solubilized single-walled carbon nanotubes that is continuously supplied to the surface of an aqueous medium, inducing evaporative self-assembly upon contacting a solid substrate.
摘要翻译：提供具有高度纳米管取向度的半导体单壁碳纳米管的高密度膜。还提供了制造将膜和场效应晶体管（FET）合并为导电沟道材料的方法。单壁碳纳米管是从含有溶解的单壁碳纳米管的有机溶剂的薄层沉积的，所述单壁碳纳米管连续地供应到水性介质的表面，在接触固体基质时引起蒸发自组装。

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