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31. 发明授权

US07211534B2 Preparation of a magnesium halide support for olefin polymerization and a catalyst composition using the same 有权
标题翻译：制备用于烯烃聚合的卤化镁载体和使用其的催化剂组合物
公开(公告)号：US07211534B2
公开(公告)日：2007-05-01
申请号：US10365558
申请日：2003-02-12
申请人： Honglan Lu , Gapgoung Kong , Zhongyang Liu , Chih-Jian Chen
发明人： Honglan Lu , Gapgoung Kong , Zhongyang Liu , Chih-Jian Chen
IPC分类号： B01J31/00
CPC分类号： C08F10/00 , B01J27/138 , C08F10/02 , C08F210/16 , C08F4/6548 , C08F4/6557 , C08F4/6543 , C08F4/6546 , C08F4/651 , C08F4/6555 , C08F210/14 , C08F2500/12
摘要： A magnesium halide support material for a polyolefin catalysts is disclosed. The magnesium halide of present invention is prepared by reacting magnesium with an alkylhalide in a non-polar hydrocarbon solvent. Preparation of the support does not require the use electron donating solvents and therefore does not require extensive washing to remove the solvent from the support.
摘要翻译：公开了一种用于聚烯烃催化剂的卤化镁载体材料。本发明的卤化镁是通过使镁与烷基卤在非极性烃溶剂中反应来制备的。载体的制备不需要使用电子给体溶剂，因此不需要大量洗涤以从载体中除去溶剂。

32. 发明申请

US20070037949A1 Copolymers of ethylene and 1-heptane 有权
标题翻译：乙烯和1-庚烷的共聚物
公开(公告)号：US20070037949A1
公开(公告)日：2007-02-15
申请号：US10553766
申请日：2004-03-12
申请人： H. Hagen , L. P. P.M. Van Der Heijden
发明人： H. Hagen , L. P. P.M. Van Der Heijden
IPC分类号： C08F10/14
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/65912 , C08J5/18 , C08J2323/08 , C08F2/001 , C08F4/6555 , C08F4/6592 , C08F210/14 , C08F2500/12 , C08F2500/08 , C08F2500/26
摘要： The present invention relates to a copolymer comprising units derived from ethylene and 1-heptene, to a composition comprising such a copolymer, and to an article prepared from or containing such a copolymer.
摘要翻译：本发明涉及包含衍生自乙烯和1-庚烯的单元的共聚物，涉及包含这种共聚物的组合物，以及与由这种共聚物制备的物品。

33. 发明申请

US20060287445A1 Process for control of polymer fines in a gas-phase polymerization 失效
标题翻译：在气相聚合中控制聚合物细粉的方法
公开(公告)号：US20060287445A1
公开(公告)日：2006-12-21
申请号：US10553689
申请日：2004-04-07
申请人： Stephanie Whited , Michael Turner , Michael Kinnan , Robert Jurgensen
发明人： Stephanie Whited , Michael Turner , Michael Kinnan , Robert Jurgensen
IPC分类号： C08F4/44
CPC分类号： C08F10/00 , C08F210/16 , C08F4/6555 , C08F2/34 , C08F2/001 , C08F210/14 , C08F2500/12
摘要： A gas phase polymerization process comprising: (1) preparing a solution of a catalyst precursor comprising a mixture of magnesium and titanium compounds, an electron donor and a solvent; (2) adding a filler to the solution from step (1) to form a slurry; (3) spray drying the slurry from step (2) at a temperature of 100 to 140° C. to form a spray dried precursor, (4) slurring the spray dried precursor from step (3) in mineral oil, (5) partially or fully pre-activating the catalyst precursor by contacting the slurry of (4) with one or more Lewis Acids, and (6) transferring the partially or fully activated precursor from step (5) into a gas phase reactor in which an olefin polymerization reaction is in progress.
摘要翻译：一种气相聚合方法，包括：（1）制备包含镁和钛化合物，电子给体和溶剂的混合物的催化剂前体溶液; （2）向来自步骤（1）的溶液中加入填料以形成浆料; （3）在100〜140℃的温度下对来自步骤（2）的浆料进行喷雾干燥以形成喷雾干燥的前体，（4）将来自步骤（3）的喷雾干燥的前体在矿物油中sl浆，（5）部分或通过使（4）的浆料与一种或多种路易斯酸接触来完全预活化催化剂前体，和（6）将来自步骤（5）的部分或完全活化的前体转移到其中烯烃聚合反应正在进行中

34. 发明申请

US20060264585A1 Highly stereoregular polypropylene with improved properties 有权
标题翻译：高立体定向聚丙烯具有改进的性能
公开(公告)号：US20060264585A1
公开(公告)日：2006-11-23
申请号：US11496924
申请日：2006-08-01
申请人： Els Meesters , Jean News , Alessandro Guidicini
发明人： Els Meesters , Jean News , Alessandro Guidicini
IPC分类号： C08F4/44
CPC分类号： C08F110/06 , Y10T428/31909 , C08F4/6465 , C08F4/6555 , C08F4/651 , C08F4/6545 , C08F2500/15 , C08F2500/12 , C08F2500/04 , C08F2500/26
摘要： Propylene polymers having a content of isotactic pentads (mmmm) higher than 97%, molecular weight distribution, expressed by the formula (a) ratio, equal to or higher than 6 and a value of formula (b) ratio equal to or lower than 5.5. The said polymers are prepared in the presence of a particular combination of Ziegler-Natta solid catalyst components and highly stereoregulating electron-donor compounds. Laminated articles, in particular bi-axially oriented films and sheets, can be prepared with the said polymers.
摘要翻译：具有高于97％的全同立构五单元组（mmmm）含量的丙烯聚合物，由式（a）比率表示的分子量分布等于或高于6，式（b）的值等于或低于5.5 。所述聚合物在齐格勒 - 纳塔固体催化剂组分和高度立构调节电子给体化合物的特定组合的存在下制备。可以用所述聚合物制备层压制品，特别是双轴取向膜和片材。

35. 发明申请

US20060167192A1 Process for the production of linear low-density polyethlene composition 失效
标题翻译：生产线性低密度聚乙烯组合物的方法
公开(公告)号：US20060167192A1
公开(公告)日：2006-07-27
申请号：US10519326
申请日：2003-06-19
申请人： Jari Aarila , Irene Helland , Ole Myhre , Jorunn Nilsen , Markku Vahteri
发明人： Jari Aarila , Irene Helland , Ole Myhre , Jorunn Nilsen , Markku Vahteri
IPC分类号： C08F2/00
CPC分类号： C08F297/083 , C08F210/16 , C08F297/08 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08L2308/00 , C08F2/001 , C08L2666/06 , C08F210/08 , C08F2500/12 , C08F2500/05 , C08F2500/24 , C08F2500/26 , C08F4/6555 , C08F4/025
摘要： A process for producing bimodal linear low-density polyethylene polymer compositions, useful for making films. The polymer compositions have a melt flow rate MFR2 of 0.4 to 1.0 g/10 min and a density of 918 to 925 kn/m3. The process to produce the polymer compositions involves copolymerising ethylene with an alpha-olefin comonomer in a loop reactor to produce a low molecular weight polymer having a melt flow rate MFR2 of 50 to 500 g/10 min and a density of 945 to 953 kg/m3. The polymerisation is continued in a gas phase reactor to produce a high molecular weight polymer, such that the final polymer composition has the desired properties. The final composition contains from 41 to 48% by weight of the low molecular weight polymer and from 59 to 52% by weight of the high molecular weight polymer. The resulting films have an excellent visual appearance and good mechanical properties. The compositions can easily be converted to films. The process can be operated a long time without a shutdown.
摘要翻译：一种生产用于制备薄膜的双峰线性低密度聚乙烯聚合物组合物的方法。聚合物组合物的熔体流动速率MFR 2 <2>为0.4至1.0g / 10min，密度为918至925kn / m 3。制备聚合物组合物的方法包括在环管反应器中将乙烯与α-烯烃共聚单体共聚以产生具有50至500g / 10min的熔体流动速率MFR 2/2的低分子量聚合物，以及密度为945至953kg / m 3。在气相反应器中继续聚合以产生高分子量聚合物，使得最终的聚合物组合物具有所需的性质。最终组合物含有41至48重量％的低分子量聚合物和59至52重量％的高分子量聚合物。所得膜具有优异的视觉外观和良好的机械性能。组合物可以容易地转化成薄膜。该过程可以长时间运行，无需关机。

36. 发明申请

US20060166814A1 Process for preparing an olefin polymerisation catalyst component with improved high temperature activity 有权
标题翻译：制备具有改善的高温活性的烯烃聚合催化剂组分的方法
公开(公告)号：US20060166814A1
公开(公告)日：2006-07-27
申请号：US10529812
申请日：2003-09-30
申请人： Timo Leinonen , Peter Denifl , Holger Pohler
发明人： Timo Leinonen , Peter Denifl , Holger Pohler
IPC分类号： B01J31/00
CPC分类号： C08F110/06 , C08F4/651 , C08F4/6555 , C08F2500/12
摘要： The invention refers to a process for preparing a Group 2 metal/transition metal olefin polymerisation catalyst component in particulate form having an improved high temperature activity and the use thereof in a process for polymerising olefins.
摘要翻译：本发明涉及一种制备具有改善的高温活性的颗粒形式的第2族金属/过渡金属烯烃聚合催化剂组分的方法及其在聚合烯烃的方法中的用途。

37. 发明授权

US07019097B2 Process for the (co)polymerization of ethylene 失效
标题翻译：乙烯（共）聚合的方法
公开(公告)号：US07019097B2
公开(公告)日：2006-03-28
申请号：US10471497
申请日：2002-03-11
申请人： Mario Sacchetti , Diego Brita
发明人： Mario Sacchetti , Diego Brita
IPC分类号： C08F110/02 , C08F4/42
CPC分类号： C08F210/16 , C08F4/6555 , C08F2/34 , C08F4/6492 , C08F210/08 , C08F2500/26
摘要： A process for the (co)polymerization ethylene, optionally in mixtures with olefins CH═CHR in which R is hydrogen or a hydrocarbyl radical with 1–12 carbon atoms, carried out in the presence of a catalyst system comprising (A) a solid catalyst component which comprises Mg, halogen an electron donor selected form ethers, esters, or amines, and Ti atoms in an oxidation state such that the weight percentage ratio between Ti(red)/Ti(tot) ranges from about 0.05 to about 1; wherein Ti(red) is the weight percentage on the solid catalyst component of the Ti atoms having a valence less than 4 and Ti(tot) is the weight percentage on the solid catalyst component of all the Ti atoms and (B) an Al-alkyl compound. The said process is capable to produce ethylene polymers with a reduced oligomers content and/or improved mechanical characteristics.
摘要翻译：（共）聚合乙烯的方法，任选与烯烃CH-CHR（其中R是氢或具有1-12个碳原子的烃基）的混合物在催化剂体系存在下进行，所述催化剂体系包含（A）固体催化剂组分，其包含Mg，卤素，选自醚，酯或胺的电子给体和氧化态的Ti原子，使得Ti（重量）/ Ti（重量比））的范围为约0.05至约1; 其中Ti（红色）是价态小于4的Ti原子的固体催化剂组分的重量百分比，Ti（重量百分比）是固体上的重量百分数所有Ti原子的催化剂组分和（B）Al-烷基化合物。所述方法能够生产具有降低的低聚物含量和/或改善的机械特性的乙烯聚合物。

38. 发明申请

US20050020785A1 Olefin polymerization catalyst component, its preparation and use 有权
标题翻译：烯烃聚合催化剂组分，其制备和应用
公开(公告)号：US20050020785A1
公开(公告)日：2005-01-27
申请号：US10868509
申请日：2004-06-14
申请人： Jarmo Lindroos , Solveig Johansson , Paivi Waldvogel
发明人： Jarmo Lindroos , Solveig Johansson , Paivi Waldvogel
IPC分类号： C08J5/18 , C08F4/654 , C08F4/655 , C08F4/658 , C08F10/00 , C08F10/02 , C08F110/02 , C08L23/04 , C08F4/44
CPC分类号： C08F10/00 , C08F10/02 , C08F110/02 , C08L23/04 , C08L2205/02 , C08L2314/02 , C08F4/025 , C08F4/6555 , C08L2666/04 , C08F2500/12 , C08F2500/17
摘要： A process for polymerizing olefins using a high activity catalyst. The catalyst utilize in the present process has a good balance in activity and can be used to carry out ethylene polymerization at high and low melt flow rates to produce low gel or gel free product.
摘要翻译：一种使用高活性催化剂聚合烯烃的方法。在本方法中使用的催化剂具有良好的活性平衡，可用于以高和低熔体流动速率进行乙烯聚合以产生低凝胶或无凝胶产品。

39. 发明申请

US20040248729A1 Solid main catalyst component for ethylene polymerization, a process for preparing the same and a catalyst containing the same 有权
标题翻译：用于乙烯聚合的固体主催化剂组分，其制备方法和含有该催化剂的催化剂
公开(公告)号：US20040248729A1
公开(公告)日：2004-12-09
申请号：US10833889
申请日：2004-04-28
发明人： Mingwei Xiao , Shijiong Yu , Xiaofeng Ye
IPC分类号： B01J031/00
CPC分类号： C08F10/00 , C08F110/02 , C08F2500/07 , C08F4/6555
摘要： The present invention provides a high-activity solid main catalyst component for ethylene polymerization, a process for preparing the same and a catalyst containing the same. The main catalyst component consists essentially of a magnesium compound, a titanium compound, an electron donor, an alkyl aluminum compound and fumed silica, and is prepared by a process comprising the step of: reacting powdered magnesium with an alkyl halide to form a magnesium compound in the nascent state; adding the magnesium compound in the nascent state together with a titanium compound and an alkyl aluminum compound into an electron donor to form a complex; adding and well dispersing a fumed silica thereto to form a homogeneous thick mixture; molding and drying the mixture to form main catalyst component particles with good particle morphology; and optionally, dispersing the main catalyst component particles into a hydrocarbon solvent or a mineral oil to form a slurry. The main catalyst component has high magnesium/titanium ratio, high titanium content, high polymerization activity, moderate initial activity so that polymerization can be stably performed, and there is little or no agglomerates during the preparation of the main catalyst component.
摘要翻译：本发明提供了用于乙烯聚合的高活性固体主催化剂组分，其制备方法和含有它的催化剂。主催化剂组分基本上由镁化合物，钛化合物，电子给体，烷基铝化合物和热解法二氧化硅组成，并且通过包括以下步骤的方法制备，所述方法包括：使粉末状镁与烷基卤反应形成镁化合物在新生状态; 将新生镁化合物与钛化合物和烷基铝化合物一起加入电子给体中以形成络合物; 加入并充分分散热解二氧化硅以形成均匀的稠混合物; 模塑和干燥混合物以形成具有良好颗粒形态的主要催化剂组分颗粒; 并且任选地，将主催化剂组分颗粒分散到烃溶剂或矿物油中以形成浆料。主要催化剂组分镁/钛比高，钛含量高，聚合活性高，起始活性适中，可稳定地进行聚合，在制备主催化剂组分时几乎不发生聚集。

40. 发明授权

US06825293B1 Polymer control through co-catalyst 有权
标题翻译：通过助催化剂进行聚合物控制
公开(公告)号：US06825293B1
公开(公告)日：2004-11-30
申请号：US09932883
申请日：2001-08-20
申请人： Shivendra Kumar Goyal , Timothy Walter Wiwchar , Victoria Ker , Mark Kelly
发明人： Shivendra Kumar Goyal , Timothy Walter Wiwchar , Victoria Ker , Mark Kelly
IPC分类号： C08F442
CPC分类号： C08F210/16 , C08F10/00 , C08F2400/02 , Y10S526/901 , C08F4/025 , C08F4/6426 , C08F4/6555 , C08F2/00 , C08F2/34 , C08F210/14 , C08F2500/12
摘要： Some properties such as dart impact strength, hexane extractables and resin stickiness of a polyethylene copolymer produced in a gas phase polymerization using a Ziegler-Natta catalyst are better controlled by regulating the ratio of aluminum from the co-catalyst to the polymer production rate. This enables one to improve properties such as dart impact strength and reduce hexane extractables by changing the amount of co-catalyst fed into the reactor.
摘要翻译：使用齐格勒 - 纳塔催化剂的气相聚合中产生的聚乙烯共聚物中的一些性能如落镖冲击强度，己烷可萃取物和树脂粘性较好地通过调节从助催化剂的铝与聚合物生产速率的比例来控制。这使得能够通过改变进入反应器的助催化剂的量来改善诸如落镖冲击强度的特性并减少己烷可萃取物。

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