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    • 51. 发明授权
    • Stain resistant composition for polyamide containing substrates
    • 用于含聚酰胺的基材的耐污染组合物
    • US06280648B1
    • 2001-08-28
    • US09176072
    • 1998-10-20
    • Jim KonzelmanDavid A. MacEwenRobert B. Login
    • Jim KonzelmanDavid A. MacEwenRobert B. Login
    • D06M900
    • D06M11/13D06M15/195D06M15/233D06M15/263D06M15/412D06M2101/34D06M2200/25
    • A stain blocking composition for treating polyamide materials, such as nylon carpeting is disclosed. The stain blocking composition contains one or more novolak resins in combination with an addition polymer and a metal donor, such as a magnesium salt. The addition polymer is directed to a partially sulfonated styrene-maleic copolymer. The addition polymer not only serves as a stain blocking composition but also serves to reduce the yellowing effect sulfonated novolak resins may have on polyamide substrates. Besides containing a sulfonated novolak resin and the addition polymer, the composition of the present invention can include various other ingredients. For instance, the composition can contain an emulsifier or dispersant, antioxidants such as sodium thiocyanate or fluorocarbon repellents or mixtures thereof.
    • 公开了一种用于处理诸如尼龙地毯的聚酰胺材料的防污组合物。 防污组合物含有一种或多种与加成聚合物和金属给体如镁盐组合的酚醛清漆树脂。 加成聚合物被引导至部分磺化的苯乙烯 - 马来共聚物。 加成聚合物不仅用作防污组合物,而且还用于减少磺化酚醛清漆树脂在聚酰胺基材上可能发生的黄变效应。 除了含有磺化酚醛清漆树脂和加成聚合物外,本发明的组合物可以包括各种其它成分。 例如,组合物可以含有乳化剂或分散剂,抗氧化剂如硫氰酸钠或氟碳驱避剂或其混合物。
    • 59. 发明授权
    • Low formaldehyde, high gel fraction latex binder
    • 低甲醛,高凝胶分数乳胶粘合剂
    • US5494963A
    • 1996-02-27
    • US368526
    • 1995-01-04
    • Peter C. Hayes
    • Peter C. Hayes
    • C08L9/08C08F212/14C08F236/04C08F236/10C08L21/02C08L25/10C09D125/10C09J125/10D04H1/64D06M15/227D06M15/233D06M15/263D06M15/285D06M15/693D21H19/20D21H19/24D21H19/58C08L33/00
    • C08F212/14C08F236/10C08L25/10C09D125/10C09J125/10D04H1/587D04H1/64D06M15/227D06M15/233D06M15/263D06M15/285D06M15/693D21H19/58Y10T428/31895Y10T428/31982
    • A low formaldehyde high gel fraction latex binder is made utilizing a compound having the formula ##STR1## wherein R and R', independently, is an alkyl having from 1 to 10 carbon atoms, and R.sup.4 is hydrogen, or wherein R.sup.3 and R.sup.4, independently is an alkyl, an aromatic, or combinations thereof having from 1 to 10 carbon atoms, or wherein said R.sup.3 and R.sup.4 are connected to form an internal amide, and wherein the isopropenyl group is either in the ortho, meta or para position. The latex binder is generally an emulsion or latex copolymer made from various monomers including at least one or more conjugated dienes having a total of from 4 to 10 carbon atoms with butadiene being preferred and from one or more vinyl-substituted aromatics having from 8 to 14 carbon atoms, with styrene being preferred. The amount of the above formulation compounds is generally from about 0.25 to about 20 parts by weight based upon 100 parts by weight of the one or more conjugated dienes and the vinyl-substituted aromatic monomers. The latex binder has good stability, and has many applications such as to bind a paper-coating composition to a cellulose substrate, or to bind non-woven fibers together. The latex binder generally contains 10 parts or less by weight of formaldehyde per million parts by weight and desirably contains nil, that is, no detectable amounts of formaldehyde therein, even after extended periods of time, e.g., 28 days.
    • 使用具有下式的化合物制备低甲醛高凝胶分数乳胶粘合剂:其中R和R'独立地是具有1至10个碳原子的烷基,R 4是氢,或其中R 3 和R 4独立地是具有1至10个碳原子的烷基,芳族或其组合,或其中所述R 3和R 4连接形成内酰胺,并且其中所述异丙烯基在邻位,间位或对位 位置。 胶乳粘合剂通常是由各种单体制成的乳液或胶乳共聚物,包括至少一种或多种总共4至10个碳原子的共轭二烯,其中丁二烯是优选的,并且一种或多种乙烯基取代的芳族化合物具有8至14个 碳原子,苯乙烯是优选的。 基于100重量份的一种或多种共轭二烯和乙烯基取代的芳族单体,上述制剂化合物的量通常为约0.25至约20重量份。 胶乳粘合剂具有良好的稳定性,并且具有许多应用,例如将纸涂层组合物结合到纤维素基材上,或将非织造纤维粘合在一起。 胶乳粘合剂通常每百万重量份含有10重量份或更少的甲醛,并且理想地包含零,也就是说,即使在长时间(例如28天)之后也不含可检测量的甲醛。
    • 60. 发明授权
    • Low formaldehyde, high gel fraction latex binder
    • 低甲醛,高凝胶分数乳胶粘合剂
    • US5425999A
    • 1995-06-20
    • US192487
    • 1994-02-07
    • Peter C. Hayes
    • Peter C. Hayes
    • C08L9/08C08F212/14C08F236/04C08F236/10C08L21/02C08L25/10C09D125/10C09J125/10D04H1/64D06M15/227D06M15/233D06M15/263D06M15/285D06M15/693D21H19/20D21H19/24D21H19/58B32B23/08
    • C08F212/14C08F236/10C08L25/10C09D125/10C09J125/10D04H1/587D04H1/64D06M15/227D06M15/233D06M15/263D06M15/285D06M15/693D21H19/58Y10T428/31895Y10T428/31982
    • A low formaldehyde, high gel fraction latex binder is made utilizing a compound having the formula ##STR1## wherein R and R', independently, is an alkyl having from 1 to 10 carbon atoms, and R.sup.4 is hydrogen, or wherein R.sup.3 and R.sup.4, independently is an alkyl, an aromatic, or combinations thereof having from 1 to 10 carbon atoms, or wherein said R.sup.3 and R.sup.4 are connected to form an internal amide, and wherein the isopropenyl group is either in the ortho, meta or para position. The latex binder is generally an emulsion or latex copolymer made from various monomers including at least one or more conjugated dienes having a total of from 4 to 10 carbon atoms with butadiene being preferred and from one or more vinyl-substituted aromatics having from 8 to 14 carbon atoms, with styrene being preferred. The amount of the above formulation compounds is generally from about 0.25 to about 20 parts by weight based upon 100 parts by weight of the one or more conjugated dienes and the vinyl-substituted aromatic monomers. The latex binder has good stability, and has many applications such as to bind a paper-coating composition to a cellulose substrate, or to bind non-woven fibers together. The latex binder generally contains 10 parts or less by weight of formaldehyde per million parts by weight and desirably contains nil, that is, no detectable amounts of formaldehyde therein, even after extended periods of time, e.g., 28 days.
    • 使用具有下列化学式的化合物制备低甲醛,高凝胶分数胶乳粘合剂,其中,是具有1至10个碳原子的烷基,R 4是氢,或者其中R 3和R 4独立地是烷基,芳族或 其组合具有1至10个碳原子,或其中所述R 3和R 4连接形成内酰胺,并且其中所述异丙烯基在邻位,间位或对位。 胶乳粘合剂通常是由各种单体制成的乳液或胶乳共聚物,包括至少一种或多种总共4至10个碳原子的共轭二烯,其中丁二烯是优选的,并且一种或多种乙烯基取代的芳族化合物具有8至14个 碳原子,苯乙烯是优选的。 基于100重量份的一种或多种共轭二烯和乙烯基取代的芳族单体,上述制剂化合物的量通常为约0.25至约20重量份。 胶乳粘合剂具有良好的稳定性,并且具有许多应用,例如将纸涂层组合物结合到纤维素基材上,或将非织造纤维粘合在一起。 胶乳粘合剂通常每百万重量份含有10重量份或更少的甲醛,并且理想地包含零,也就是说,即使在长时间(例如28天)之后也不含可检测量的甲醛。