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    • 66. 发明授权
    • Defect free composite membranes, method for producing said membranes and use of the same
    • 无缺陷复合膜,制造所述膜的方法及其用途
    • US07165682B1
    • 2007-01-23
    • US10620715
    • 2003-07-16
    • Jiang Ji
    • Jiang Ji
    • B01D29/00B01D39/00B01D67/00B01D63/00B01D39/14B01D53/00
    • B01D69/085A23C9/1422A23C2210/202A23L2/74B01D65/003B01D67/0093B01D69/04B01D69/06B01D69/087B01D69/10B01D69/12B01D69/141B01D2323/02B01D2323/12B01D2323/345C02F1/44C12H1/16C13B20/165
    • A defect free semipermeable composite membrane having excellent integrity and high water permeability is provided. Said composite membrane comprises an inside support layer to provide sufficient mechanical strength; an outside barrier layer to provide selective separation; and a middle layer to provide both chemical and physical binding between said support and said barrier layer to bond them together. Three different methods for making said defect free composite membrane are discovered. These methods have been successfully utilized to produce high quality coatings and defect free composite membranes, which are independent of chemical composition and physical structure of said support. In the present invention, ultrasonic sonication is discovered to be effective to speed up the phase inversion process of a membrane casting solution, thus allows produce a composite membrane at a speed higher than those disclosed in the prior art. Said defect free composite membranes have broad applications, ranging from filtration of fruit juice, wine and milk to biotech down stream processing and purification of drinking water, municipal and industrial wastewater.
    • 提供了具有优异的完整性和高透水性的无缺陷半透膜复合膜。 所述复合膜包括内部支撑层以提供足够的机械强度; 外部阻挡层以提供选择性分离; 以及中间层,以在所述载体和所述阻挡层之间提供化学和物理结合以将它们结合在一起。 发现制造所述无缺陷复合膜的三种不同的方法。 这些方法已经成功地用于生产高质量的涂层和无缺陷的复合膜,它们独立于所述载体的化学组成和物理结构。 在本发明中,发现超声波超声处理有效地加速了膜流延溶液的相转化过程,从而能够以比现有技术公开的速度高的速度制造复合膜。 所述无缺陷复合膜具有广泛的应用,从果汁,葡萄酒和牛奶过滤到生物技术下游加工和净化饮用水,市政和工业废水。
    • 68. 发明授权
    • Super selective hollow fibre membranes
    • 超选择性中空纤维膜
    • US06521025B1
    • 2003-02-18
    • US09831548
    • 2001-06-28
    • Simon James ShiltonAhmad Fauzi Ismail
    • Simon James ShiltonAhmad Fauzi Ismail
    • B01D6908
    • B01D69/08B01D67/0009B01D67/0016B01D69/085B01D2323/12B01D2325/022Y10S55/05
    • A hollow fibre membrane has an active layer (2) in which elongate polymer molecules (3) are longitudinally aligned essentially parallel to the extrusion direction to thereby define a plurality of spaced free volume cavities (4) which are particularly numerous and are essentially regularly spaced to provide enhanced selectivity when used in gas separation. The hollow fibre membrane is manufactured using a dry/wet phase separation process by spinning a dope composition which is extruded through a spinneret (12) having an annulus or annular orifice (16) together with a bore-forming fluid or coagulant. The dope composition has a power law index of less than 1 (unity) and the bore coagulant has a water activity of less than 1 (unity).
    • 中空纤维膜具有活性层(2),其中细长聚合物分子(3)基本上平行于挤出方向纵向排列,从而限定多个间隔开的自由体积空腔(4),其特别多,并且基本上规则地间隔开 以在气体分离中使用时提供增强的选择性。 使用干/湿相分离方法制造中空纤维膜,通过纺丝通过具有环形或环形孔口(16)的喷丝头(12)与孔形成流体或凝结剂一起挤出的涂料组合物。 涂料组合物的幂律指数小于1(单位),孔混凝剂的水分活度小于1(统一)。