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    • 73. 发明申请
    • RADIATION ENHANCED RESISTIVE SWITCHING LAYERS
    • 辐射增强电阻开关层
    • US20140175364A1
    • 2014-06-26
    • US13722155
    • 2012-12-20
    • Intermolecular Inc.Kabushiki Kaisha ToshibaSanDisk 3D LLC
    • Yun WangTony P. ChiangTim MinvielleTakeshi Yamaguchi
    • H01L45/00
    • H01L45/1253H01L27/2463H01L45/08H01L45/146H01L45/1641
    • Provided are radiation enhanced resistive switching layers, resistive random access memory (ReRAM) cells including these layers, as well as methods of forming these layers and cells. Radiation creates defects in resistive switching materials that allow forming and breaking conductive paths in these materials thereby improving their resistive switching characteristics. For example, ionizing radiation may break chemical bonds in various materials used for such a layer, while non-ionizing radiation may form electronic traps. Radiation power, dozing, and other processing characteristics can be controlled to generate a distribution of defects within the resistive switching layer. For example, an uneven distribution of defects through the thickness of a layer may help with lowering switching voltages and/or currents. Radiation may be performed before or after thermal annealing, which may be used to control distribution of radiation created defects and other types of defects in resistive switching layers.
    • 提供了辐射增强的电阻式开关层,包括这些层的电阻随机存取存储器(ReRAM)单元,以及形成这些层和单元的方法。 辐射在电阻开关材料中产生缺陷,允许在这些材料中形成和断开导电路径,从而提高其电阻开关特性。 例如,电离辐射可以破坏用于这种层的各种材料中的化学键,而非电离辐射可以形成电子陷阱。 可以控制辐射功率,打盹等处理特性,以产生电阻式开关层内的缺陷分布。 例如,通过层的厚度的缺陷的不均匀分布可能有助于降低开关电压和/或电流。 可以在热退火之前或之后进行辐射,其可以用于控制电阻开关层中辐射产生的缺陷和其他类型的缺陷的分布。
    • 74. 发明申请
    • Bilayered Oxide Structures for ReRAM Cells
    • 用于ReRAM电池的双层氧化物结构
    • US20140175360A1
    • 2014-06-26
    • US13721358
    • 2012-12-20
    • Intermolecular Inc.Kabushiki Kaisha ToshibaSanDisk 3D LLC
    • Mihir TendulkarVidyut GopalImran HashimRandall J. HiguchiTim MinvielleYun WangTakeshi Yamaguchi
    • H01L45/00
    • H01L45/146H01L27/2481H01L45/08H01L45/10H01L45/1233H01L45/1625
    • Provided are resistive random access memory (ReRAM) cells having bi-layered metal oxide structures. The layers of a bi-layered structure may have different compositions and thicknesses. Specifically, one layer may be thinner than the other layer, sometimes as much as 5 to 20 times thinner. The thinner layer may be less than 30 Angstroms thick or even less than 10 Angstroms thick. The thinner layer is generally more oxygen rich than the thicker layer. Oxygen deficiency of the thinner layer may be less than 5 atomic percent or even less than 2 atomic percent. In some embodiments, a highest oxidation state metal oxide may be used to form a thinner layer. The thinner layer typically directly interfaces with one of the electrodes, such as an electrode made from doped polysilicon. Combining these specifically configured layers into the bi-layered structure allows improving forming and operating characteristics of ReRAM cells.
    • 提供了具有双层金属氧化物结构的电阻随机存取存储器(ReRAM)单元。 双层结构的层可以具有不同的组成和厚度。 具体地说,一层可以比另一层薄一些,有时可以减薄5至20倍。 较薄的层可以小于30埃厚或甚至小于10埃厚。 较薄的层通常比较厚的层富氧。 较薄层的缺氧可能小于5原子%或甚至小于2原子%。 在一些实施方案中,可以使用最高氧化态金属氧化物来形成较薄的层。 较薄的层通常直接与一个电极(例如由掺杂多晶硅制成的电极)接合。 将这些特定配置的层组合成双层结构允许改善ReRAM单元的成形和操作特性。
    • 76. 发明授权
    • Bipolar multistate nonvolatile memory
    • 双极多态非易失性存储器
    • US08742392B2
    • 2014-06-03
    • US13953296
    • 2013-07-29
    • Intermolecular Inc.Kabushiki Kaisha ToshibaSanDisk 3D LLC
    • Tony Chiang
    • H01L45/00
    • H01L45/1608H01L27/2409H01L27/2481H01L45/08H01L45/1233H01L45/1253H01L45/145H01L45/146H01L45/147H01L45/1616
    • Embodiments generally include a method of forming a nonvolatile memory device that contains a resistive switching memory element that has an improved device switching capacity by using multiple layers of variable resistance layers. In one embodiment, the resistive switching element comprises at least three layers of variable resistance materials to increase the number of logic states. Each variable resistance layer may have an associated high resistance state and an associated low resistance state. As the resistance of each variable resistance layer determines the digital data bit that is stored, the multiple variable resistance layers per memory element allows for additional data storage without the need to further increase the density of nonvolatile memory devices. Typically, resistive switching memory elements may be formed as part of a high-capacity nonvolatile memory integrated circuit, which can be used in various electronic devices, such as digital cameras, mobile telephones, handheld computers, and music players.
    • 实施例通常包括形成非易失性存储器件的方法,该非易失性存储器件包含通过使用多层可变电阻层而具有改进的器件开关容量的电阻式开关存储器元件。 在一个实施例中,电阻式开关元件包括至少三层可变电阻材料以增加逻辑状态的数量。 每个可变电阻层可以具有相关联的高电阻状态和相关联的低电阻状态。 由于每个可变电阻层的电阻决定了存储的数字数据位,每个存储元件的多个可变电阻层允许额外的数据存储,而不需要进一步增加非易失性存储器件的密度。 通常,电阻式开关存储器元件可以形成为可用于各种电子设备(例如数码相机,移动电话,手持式计算机和音乐播放器)的大容量非易失性存储器集成电路的一部分。