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    • 82. 发明申请
    • Method for Manufacturing Nano-Graphene Sheets
    • 制造纳米石墨烯片的方法
    • US20150158729A1
    • 2015-06-11
    • US14303409
    • 2014-06-12
    • Enerage Inc.
    • Mark Y WUCheng-Yu HSIEHGeng-Wei LINPing-Yun YEHTsung-Han CHEN
    • C01B31/04
    • C01B32/192C01B2204/32
    • A method for manufacturing nano-graphene sheets, includes: intercalating and oxidizing a graphite material to form a graphite oxide by mixing the graphite material with an intercalation agent and oxidant; contacting the graphite oxide with a heat source to thermally flake the graphite oxide to nano-graphite sheets; suspending the nano-graphite sheets in a liquid medium and applying a mechanical shear force larger than 5,000 psi to mechanically flake the nano-graphite sheets for reducing the lateral size and thickness to form a nano-graphene suspension solution; separating the nano-graphene sheets from the nano-graphene suspension solution and drying the nano-graphene sheets; and finally reducing and heat treating the nano-graphene sheets to lower the oxygen content to less than 3 wt % and decrease the crystal defects.
    • 制造纳米石墨烯片的方法包括:通过将石墨材料与嵌入剂和氧化剂混合来嵌入和氧化石墨材料以形成氧化石墨; 使石墨氧化物与热源接触以将石墨氧化物热剥离成纳米石墨片; 将纳米石墨片悬浮在液体介质中并施加大于5,000psi的机械剪切力以机械剥离纳米石墨片以减小横向尺寸和厚度以形成纳米石墨烯悬浮液; 将纳米石墨烯片与纳米石墨烯悬浮溶液分离并干燥纳米石墨烯片; 最后还原和热处理纳米石墨烯片,将氧含量降至3重量%以下,降低晶体缺陷。
    • 89. 发明授权
    • Supercritical fluid process for producing nano graphene platelets
    • 制备纳米石墨烯血小板的超临界流体工艺
    • US08696938B2
    • 2014-04-15
    • US12229493
    • 2008-08-25
    • Aruna ZhamuBor Z. Jang
    • Aruna ZhamuBor Z. Jang
    • C01B31/04C04B14/00
    • B82Y40/00B82Y30/00C01B32/19C01B32/192C01B2204/02C01B2204/22C01P2006/12Y02P20/544
    • The present invention provides a process for producing pristine or non-oxidized nano graphene platelets (NGPs) that are highly conductive. The process comprises: (i) subjecting a graphitic material to a supercritical fluid at a first temperature and a first pressure for a first period of time in a pressure vessel and then (ii) rapidly depressurizing the fluid at a fluid release rate sufficient for effecting exfoliation of the graphitic material to obtain the NGP material. Conductive NGPs can be used as a conductive additive in transparent electrodes for solar cells or flat panel displays (e.g., to replace expensive indium-tin oxide), battery and supercapacitor electrodes, and nanocomposite for electromagnetic wave interference (EMI) shielding and static charge dissipation, etc.
    • 本发明提供了一种生产高导电性的原始或未氧化的纳米石墨烯片晶(NGP)的方法。 该方法包括:(i)在压力容器中将石墨材料在第一温度和第一压力下经历第一个压力的超临界流体,然后(ii)以足以实现的流体释放速率快速减压流体 石墨材料的剥离以获得NGP材料。 导电NGP可用作太阳能电池或平板显示器的透明电极(例如,替代昂贵的氧化铟锡),电池和超级电容器电极以及用于电磁波干扰(EMI)屏蔽和静电荷耗散的纳米复合材料的导电添加剂 等等