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    • 81. 再颁专利
    • Composition of organic compounds, optical film and method of production thereof
    • 有机化合物的组成,光学膜及其制造方法
    • USRE45850E1
    • 2016-01-19
    • US14563821
    • 2014-12-08
    • Crysoptix K.K.
    • Irina KasianovaEllina Kharatiyan
    • G02B5/30C09K19/12C09K19/32C09K19/20C09K19/54G02F1/1335G02F1/1337C09K19/60C09K19/38
    • C09K19/60C09K19/3804C09K19/3809G02B5/3083Y10T428/10Y10T428/1041
    • A composition includes at least one organic compound of a first type of the general formula I and at least one organic compound of a second type of the general structural formula II, wherein Core in formula I is a conjugated organic unit capable of forming a rigid rod-like macromolecule, Gk is a set of ionogenic side-groups providing solubility of the organic compound of the first type in a solvent and give rigidity to the rod-like macromolecule; and wherein Sys in formula II is an at least partially conjugated substantially planar polycyclic molecular system capable of forming board-like supramolecules via π-π-interaction, and X, Y, Z and Q are substituents. The composition is capable of forming a lyotropic liquid crystal solution, which can form a solid retardation layer of biaxial type substantially transparent to electromagnetic radiation in the visible spectral range. The type and degree of biaxiality of the said optical retardation layer is controlled by a molar ratio of the organic compounds of the first and the second type in the composition. An optical film comprising a solid retardation layer formed of the composition, a method of producing the optical film, and a vertical alignment liquid crystal display using said retardation layer are also provided.
    • 组合物包含至少一种通式I的第一类有机化合物和至少一种通式II的第二类型的有机化合物,其中式I中的核心是能够形成刚性棒的共轭有机单元 Gk是一组提供第一类有机化合物在溶剂中的溶解度的离子发生侧基,对棒状高分子具有刚性; 并且其中式II中的Sys是至少部分共轭的基本上平面的多环分子体系,其能够经由和相互作用形成板状超分子,X,Y,Z和Q是取代基。 该组合物能够形成溶致液晶溶液,其可以形成对可见光谱范围内的电磁辐射基本透明的双轴型固体延迟层。 所述光学延迟层的双轴性的类型和程度由组合物中第一种和第二种类型的有机化合物的摩尔比来控制。 还提供了一种包括由该组合物形成的固体相位差层的光学膜,该光学膜的制造方法和使用该延迟层的垂直取向液晶显示器。
    • 82. 发明申请
    • Organic Compound, Optical Film and Method of Production thereof
    • 有机化合物,光学膜及其制造方法
    • US20140186637A1
    • 2014-07-03
    • US14109850
    • 2013-12-17
    • CRYSOPTIX KK
    • Irina KasianovaDarya Yurchenko
    • C09D177/06
    • C09D177/06C09K19/3804C09K19/3809C09K2019/0444Y10T428/31623Y10T428/31725
    • An organic compound has the general structural formula I. In the formula I, Core is a conjugated organic unit capable of forming a rod-like macromolecule, n is a number of the conjugated organic units in the rod-like macromolecule, Gk is a set of ionogenic side-groups, and k is a number of the side-groups in the set Gk. The set of the ionogenic side-groups provide solubility of the organic compound or its salts and give rigidity to the rod-like macromolecule. The number n provides molecule anisotropy that promotes self-assembling of macromolecules in a solution of the organic compound or its salts, forming lyotropic liquid crystal. The solution is capable of forming a solid optical retardation layer of positive A-type substantially transparent to electromagnetic radiation in the visible spectral range. An optical film based on an organic compound of the general formula I and a method of making same are also disclosed.
    • 有机化合物具有通式结构式I.在式I中,Core是能够形成棒状高分子的共轭有机单元,n是棒状高分子中的多个共轭有机单元,G k是一个 的离子源侧基,k是组Gk中的侧基的数目。 一组离子型侧基提供了有机化合物或其盐的溶解性,并且使得棒状大分子具有刚性。 数字n提供分子各向异性,其促进大分子在有机化合物或其盐的溶液中的自组装,形成溶致液晶。 该解决方案能够形成对可见光谱范围内的电磁辐射基本上透明的正A型固体光学延迟层。 还公开了一种基于通式I的有机化合物的光学膜及其制备方法。
    • 83. 发明授权
    • Patternable liquid crystal polymer comprising thio-ether units
    • 包含硫醚单元的可成形液晶聚合物
    • US08574454B2
    • 2013-11-05
    • US12515918
    • 2007-12-11
    • Thomas BachelsIzabela BuryGuy MarckHubert SeiberlePeggy StuderStefano Tugulu
    • Thomas BachelsIzabela BuryGuy MarckHubert SeiberlePeggy StuderStefano Tugulu
    • C09K19/52C09K19/06C09K19/00G02F1/1333C08G75/04
    • C09K19/3804C09K19/38C09K19/54C09K2019/0448C09K2219/03
    • The present invention relates to a photo-polymerized, patterned or unpatterned liquid crystal polymer, especially a liquid crystal polymer film or a liquid crystal polymer network, comprising thio-ether units of formula (I) * covalent bond, which links the unit of formula (I) to the residue of the polymer wherein LC1 is selected from the group of liquid crystal residues, X1 is selected from the group of aliphatic organic residues, and n1 is an integer ≧0 and m1 is an integer ≧0; with the proviso that if n1 is 0, then m1 is >0, and if m1 is 0, then n1>0; which is prepared in an atmosphere containing oxygen, preferably with an amount of 0.1≦oxygen≦50%, more preferably 1≦oxygen≦25%, most preferably in air; with the proviso that polymer dispersed liquid crystals are excluded. Further, this invention relates to a composition used for the preparation of that photo-polymerized liquid crystal polymer of the invention, to processes of the preparation of that liquid crystal polymer and to its use.
    • 本发明涉及光聚合,图案化或未图案化的液晶聚合物,特别是液晶聚合物膜或液晶聚合物网络,其包含式(I)*共价键的硫醚单元,其将式 (I)所示的聚合物的残基,其中LC1选自液晶残基,X1选自脂族有机残基,n1为整数> = 0,m1为整数> = 0; 条件是如果n1为0,则m1> 0,如果m1为0,则n1> 0; 其在含有氧气的气氛中制备,优选以25%的0.1%氧气,更优选25%的氧气,最优选在空气中制备; 条件是排除聚合物分散的液晶。 此外,本发明涉及用于制备本发明的光聚合液晶聚合物的组合物,该液晶聚合物的制备方法及其用途。
    • 84. 发明授权
    • Composition of organic compounds, optical film and method of production thereof
    • 有机化合物的组成,光学膜及其制造方法
    • US08512824B2
    • 2013-08-20
    • US12541362
    • 2009-08-14
    • Irina KasianovaEllina Kharatiyan
    • Irina KasianovaEllina Kharatiyan
    • G02B5/30C09K19/32C09K19/12C09K19/20C09K19/54G02F1/1335G02F1/1337
    • C09K19/60C09K19/3804C09K19/3809G02B5/3083Y10T428/10Y10T428/1041
    • A composition includes at least one organic compound of a first type of the general formula I and at least one organic compound of a second type of the general structural formula II, wherein Core in formula I is a conjugated organic unit capable of forming a rigid rod-like macromolecule, Gk is a set of ionogenic side-groups providing solubility of the organic compound of the first type in a solvent and give rigidity to the rod-like macromolecule; and wherein Sys in formula II is an at least partially conjugated substantially planar polycyclic molecular system capable of forming board-like supramolecules via π-π-interaction, and X, Y, Z and Q are substituents. The composition is capable of forming a lyotropic liquid crystal solution, which can form a solid retardation layer of biaxial type substantially transparent to electromagnetic radiation in the visible spectral range. The type and degree of biaxiality of the said optical retardation layer is controlled by a molar ratio of the organic compounds of the first and the second type in the composition. An optical film comprising a solid retardation layer formed of the composition, a method of producing the optical film, and a vertical alignment liquid crystal display using said retardation layer are also provided.
    • 组合物包含至少一种通式I的第一类有机化合物和至少一种通式II的第二类型的有机化合物,其中式I中的核心是能够形成刚性棒的共轭有机单元 Gk是一组提供第一类有机化合物在溶剂中的溶解度的离子发生侧基,对棒状高分子具有刚性; 并且其中式II中的Sys是能够通过π-π相互作用形成板状超分子的至少部分共轭的基本上平面的多环分子体系,X,Y,Z和Q是取代基。 该组合物能够形成溶致液晶溶液,其可以形成对可见光谱范围内的电磁辐射基本透明的双轴型固体延迟层。 所述光学延迟层的双轴性的类型和程度由组合物中第一种和第二种类型的有机化合物的摩尔比来控制。 还提供了一种包括由该组合物形成的固体相位差层的光学膜,该光学膜的制造方法和使用该延迟层的垂直取向液晶显示器。