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    • 8. 发明申请
    • Liquid crystalline thermosets from ester, ester-imide, and ester-amide oligomers
    • 来自酯,酯 - 酰亚胺和酯 - 酰胺低聚物的液晶热固性材料
    • US20050209429A1
    • 2005-09-22
    • US11124508
    • 2005-04-29
    • Theodorus DingemansErik WeiserTerry St. Clair
    • Theodorus DingemansErik WeiserTerry St. Clair
    • C08L101/12C08G63/60C08G63/685C08G69/44C08G73/16C09K19/38C08G18/10
    • C09K19/3823C08G63/60C08G63/6854C08G69/44C08G73/16C09K19/3804
    • Main chain thermotropic liquid crystal esters, ester-imides, and ester-amides were prepared from AA, BB, and AB type monomeric materials and end-capped with phenylacetylene, phenylmaleimide, or nadimide reactive end-groups. The end-capped liquid crystal oligomers are thermotropic and have, preferably, molecular weights in the range of approximately 1000-15,000 grams per mole. The end-capped liquid crystal oligomers have broad liquid crystalline melting ranges and exhibit high melt stability and very low melt viscosities at accessible temperatures. The end-capped liquid crystal oligomers are stable for up to an hour in the melt phase. They are highly processable by a variety of melt process shape forming and blending techniques. Once processed and shaped, the end-capped liquid crystal oligomers were heated to further polymerize and form liquid crystalline thermosets (LCT). The fully cured products are rubbers above their glass transition temperatures.
    • 主链热致液晶酯,酯 - 酰亚胺和酯 - 酰胺由AA,BB和AB型单体材料制成,并用苯乙炔,苯基马来酰亚胺或纳二酰胺反应性端基封端。 封端的液晶低聚物是热致变性的,并且优选分子量在约1000-15,000克/摩尔的范围内。 封端的液晶低聚物具有宽的液晶熔融范围,并且在可接近的温度下表现出高的熔体稳定性和非常低的熔体粘度。 封端的液晶低聚物在熔融相中稳定长达一个小时。 它们通过各种熔体加工形状和混合技术可高度加工。 一旦加工和成形,加热封端的液晶低聚物进一步聚合并形成液晶热固性塑料(LCT)。 完全固化的产品是高于其玻璃化转变温度的橡胶。