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    • 5. 发明申请
    • COPPER COMPOUND AND METHOD FOR PRODUCING COPPER THIN FILM USING THE SAME
    • 铜化合物和使用该铜复合薄膜的方法
    • US20100029969A1
    • 2010-02-04
    • US12578182
    • 2009-10-13
    • Minoru OTANIJun HISADAToyoki MAWATARI
    • Minoru OTANIJun HISADAToyoki MAWATARI
    • C07F1/08
    • C23C18/08
    • The present invention provides a copper compound having a decomposition temperature in a range of 100° C. to 300° C. and including one unit or a plurality of connected units represented by the following Formula (1): [R1COO]n[NH3]mCuX1p  (1) where n is 1 to 3; m is 1 to 3; p is 0 to 1; n pieces of R1 respectively represent the following Formula (2), CH2X2, CH2X2(CHX2)q, NH2, or H, and may be the same or different from each other, or n is 2 and two pieces of [R1COO] represent together the following Formula (3); R2, R3, and R4 are respectively CH2X2, CH2X2(CHX2)q, NH2, or H; R5 is —(CHX2)r—; X2 is H, OH, or NH2; r is 0 to 4; q is 1 to 4; and X1 is NH4+, H2O, or solvent molecules According to the above configuration, there are provided a copper compound capable of forming a copper thin film required for producing an electronic device or the like safely, inexpensively, and easily, and a method for producing a copper thin film using the copper compound.
    • 本发明提供一种铜化合物,其分解温度在100℃至300℃的范围内,并且包括由下式(1)表示的一个单元或多个连接单元:[R 1 COO] n [NH 3] mCuX1p(1)其中n为1至3; m为1〜3; p为0〜1; n个R1分别表示下式(2),CH2X2,CH2X2(CHX2)q,NH2或H,可以相同或不同,或n为2,两个[R 1 COO]表示在一起 以下公式(3); R2,R3和R4分别是CH2X2,CH2X2(CHX2)q,NH2或H; R5是 - (CHX2)r-; X2是H,OH或NH2; r为0〜4; q为1〜4; X 1为NH 4 +,H 2 O或溶剂分子根据上述结构,提供了能够安全,廉价且容易地形成电子器件等制造所需的铜薄膜的铜化合物及其制造方法 使用铜化合物的铜薄膜。
    • 8. 发明申请
    • Metal removing solution and metal removing method using the same
    • 金属去除溶液及使用其的金属去除方法
    • US20080073614A1
    • 2008-03-27
    • US11903837
    • 2007-09-25
    • Daisaku AkiyamaDaisuke Katayama
    • Daisaku AkiyamaDaisuke Katayama
    • C09K13/08
    • H05K3/26C23F1/30C23F1/44H05K3/108H05K3/181H05K2201/0761
    • A metal removing solution of the present invention is a solution for removing palladium, tin, silver, palladium alloy, silver alloy, and tin alloy, and the metal removing solution contains a chain thiocarbonyl compound. A removing method of the present invention for removing palladium, tin, silver, palladium alloy, silver alloy, and tin alloy is a method for selectively removing a metal other than copper or copper alloy, from a system that includes copper or copper alloy and at least one selected from palladium, tin, silver, palladium alloy, silver alloy, and tin alloy, by using a metal removing solution containing a chain thiocarbonyl compound. Thus, the present invention provides the metal removing solution capable of removing palladium, tin, silver, palladium alloy, silver alloy, and tin alloy, the solution having an excellent property of removing palladium, tin, silver, palladium alloy, silver alloy, tin alloy, and the like without attacking copper, and having an excellent handleability since the solution does not contain any toxic substance; and the removing method using the foregoing metal removing solution.
    • 本发明的金属去除溶液是用于除去钯,锡,银,钯合金,银合金和锡合金的溶液,金属去除溶液含有链硫代羰基化合物。 本发明的除去钯,锡,银,钯合金,银合金,锡合金的除去方法是从包含铜或铜合金的系统中选择除去铜或铜合金以外的金属的方法, 通过使用含有链硫代羰基化合物的金属去除溶液,选自钯,锡,银,钯合金,银合金和锡合金中的至少一种。 因此,本发明提供能够除去钯,锡,银,钯合金,银合金和锡合金的金属去除溶液,该溶液具有优异的除去钯,锡,银,钯合金,银合金,锡 合金等而不侵蚀铜,并且由于溶液不含任何有毒物质,因此具有优异的可操作性; 以及使用上述金属去除溶液的除去方法。
    • 9. 发明申请
    • Etchant and replenishment solution therefor, and etching method and method for producing wiring board using the same
    • 蚀刻剂和补充溶液,以及使用其制造布线板的蚀刻方法和方法
    • US20080011981A1
    • 2008-01-17
    • US11900959
    • 2007-09-14
    • Masayo KuriyamaRyo OgushiDaisaku AkiyamaKaoru Urushibata
    • Masayo KuriyamaRyo OgushiDaisaku AkiyamaKaoru Urushibata
    • C09K13/04C09K13/06
    • H05K3/26C23F1/28C23F1/30H05K3/181H05K2201/0761H05K2203/0789H05K2203/124
    • An etchant of the present invention includes an aqueous solution containing hydrochloric acid, nitric acid, and a cupric ion source. An etching method of the present invention includes bringing the etchant into contact with at least one metal selected from nickel, chromium, nickel-chromium alloys, and palladium. Another etching method of the present invention includes bringing a first etchant that includes an aqueous solution containing at least the following components A to C (A. hydrochloric acid; B. at least one compound selected from the following (a) to (c): (a) compounds with 7 or less carbon atoms, containing a sulfur atom(s) and at least one group selected from an amino group, an imino group, a carboxyl group, a carbonyl group, and a hydroxyl group; (b) thiazole; and (c) thiazole compounds; and C. a surfactant) into contact with a surface of the metal, and then bringing a second solution that includes an aqueous solution containing hydrochloric acid, nitric acid, and a cupric ion source into contact with the surface of the metal. According to the etchant and the etching methods of the present invention, it is possible to etch at least one metal selected from nickel, chromium, nickel-chromium alloys, and palladium quickly and suppress excessive dissolution of copper.
    • 本发明的蚀刻剂包括含有盐酸,硝酸和铜离子源的水溶液。 本发明的蚀刻方法包括使蚀刻剂与选自镍,铬,镍 - 铬合金和钯中的至少一种金属接触。 本发明的另一种蚀刻方法包括使包含至少含有以下组分A至C的水溶液的第一蚀刻剂(A.盐酸; B.至少一种选自以下(a)至(c)的化合物: (a)具有7个以下碳原子的含有硫原子和至少1个选自氨基,亚氨基,羧基,羰基和羟基的基团的化合物;(b)噻唑 ;和(c)噻唑化合物;和C.a表面活性剂)与金属的表面接触,然后使包含含有盐酸,硝酸和铜离子源的水溶液的第二溶液与 金属表面。 根据本发明的蚀刻剂和蚀刻方法,可以快速地蚀刻选自镍,铬,镍 - 铬合金和钯中的至少一种金属并抑制铜的过度溶解。
    • 10. 发明授权
    • Resin surface treating agent and resin surface treatment
    • 树脂表面处理剂和树脂表面处理
    • US07297757B2
    • 2007-11-20
    • US11153968
    • 2005-06-16
    • Sachiko NakamuraYoshinari MiyataTerukazu IshidaMiho Misumi
    • Sachiko NakamuraYoshinari MiyataTerukazu IshidaMiho Misumi
    • C08F6/00
    • C08J7/06C08J7/12H05K3/381
    • The present invention relates to a resin surface treating agent containing as an effective component at least one cerium compound selected from tetravalent and trivalent cerium compounds. The surface treating method of the present invention is a method of bringing a surface of a resin into contact with a surface treating agent containing as an effective component at least one cerium compound selected from tetravalent and trivalent cerium compounds, and thereafter treating the surface with an acidic aqueous solution. This activates the resin surface and thereby increases a strength of adhesion of, for instance, a polyimide-based resin film with metal wires, as well as a strength of adhesion of a polyimide-based resin film with another resin. Thus, a resin surface treating agent that provides excellent productivity and reduces processing costs, as well as a surface treating method using the same, are provided.
    • 本发明涉及含有至少一种选自四价和三价铈化合物的铈化合物作为有效成分的树脂表面处理剂。 本发明的表面处理方法是使树脂的表面与含有选自四价和三价铈化合物的至少一种铈化合物作为有效成分的表面处理剂接触,然后用 酸性水溶液。 这激活树脂表面,从而增加例如具有金属线的聚酰亚胺系树脂膜的粘附强度,以及聚酰亚胺系树脂膜与其他树脂的粘合强度。 因此,提供了提供优异的生产率和降低加工成本的树脂表面处理剂以及使用其的表面处理方法。