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    • 8. 发明申请
    • PRODUCTION METHOD AND DEVICE OF SURFACE ROUGHENED COPPER PLATE, AND SURFACE ROUGHENED COPPER PLATE
    • 表面粗糙化铜板和表面粗化铜板的生产方法和装置
    • US20140339094A1
    • 2014-11-20
    • US14337264
    • 2014-07-22
    • Furukawa Electric Co., Ltd.
    • Hajime WATANABESadao ISHIHAMAKiyoteru YAMAMOTOTakahiro IMAIToshihiro OYOSHI
    • C25D5/02H05K3/00C25D7/00
    • C25D5/02C25D3/38C25D5/10C25D5/18C25D5/34C25D5/48C25D7/00C25D17/00C25F3/02H05K1/056H05K3/0085H05K3/384H05K2201/0355H05K2203/0307H05K2203/0723H05K2203/1572Y10S205/92Y10T428/12361
    • PROBLEMS TO BE SOLVED: To provide a process for roughening both sides of a copper plate by forming a protrusion with a fine bump shape on the both sides of the copper plate, and then to provide a process for a deterioration of an electroplating solution for plating copper to become hard to progress therein.MEANS FOR SOLVING THE PROBLEMS: First of all, there is designed to be arranged electrodes (3, 3) as a similar pole for therebetween to be opposed to each other in an electroplating copper solution 2, and then to be arranged a copper plate 4 at therebetween. And then at first there becomes to be performed an anodic treatment for generating a copper fine particles on both surfaces of the copper plate 4, by performing an electrolytic process with the copper plate 4 as a positive electrode and the electrodes 3 as negative electrodes. And then thereafter there becomes to be performed a cathodic treatment, by performing an electroplating of copper with the copper plate 4 as a negative electrode and the electrodes 3 as positive electrodes, for the copper fine particles to be fixed onto the surfaces of the copper plate 4. Furthermore, there becomes to be formed the above mentioned protrusion with the fine bump shape thereon, by performing the anodic treatment and then the cathodic treatment as not less than one cycle thereof.
    • 要解决的问题:提供一种通过在铜板的两面上形成具有微小凸起形状的突起来提供铜板两侧粗糙化的方法,然后提供用于电镀的电镀液的劣化的工艺 铜变得难以进展。 解决问题的手段:首先,设计为在电镀铜溶液2中彼此相对地设置作为相似的极的电极(3,3),然后设置为铜板4 在它们之间。 首先,通过以铜板4为正极进行电解处理,将电极3作为负极进行电镀处理,在铜板4的两面上进行阳极处理,生成铜微粒。 然后,进行阴极处理,通过以铜板4作为负极进行铜的电镀,将电极3作为正极进行阴极处理,将铜微粒固定在铜板的表面上 此外,通过进行阳极处理,然后阴极处理为不止一个循环,形成上述具有微小凸起形状的突起。
    • 10. 发明申请
    • COPPER FOIL FOR PRINTED CIRCUIT
    • 印刷电路用铜箔
    • US20140057123A1
    • 2014-02-27
    • US14006140
    • 2012-02-10
    • Hideta AraiAtsushi Miki
    • Hideta AraiAtsushi Miki
    • H05K1/09
    • H05K1/09C25D5/14C25D5/48C25D7/0614H05K3/384H05K3/388H05K3/389H05K2201/0352H05K2201/0355H05K2203/0723Y10T428/12049Y10T428/12076Y10T428/12438
    • Provided is a copper foil with surface treated layers, wherein a copper foil or a copper alloy foil includes a plurality of surface treated layers configured from a roughened layer formed on the copper foil or the copper alloy foil by roughening treatment, a heat-resistant layer made from a Ni—Co layer formed on the roughened layer, and a weathering layer and a rust-preventive layer which contain Zn, Ni, and Cr and is formed on the heat-resistant layer, and the surface treated layers having a (total Zn)/[(total Zn)+(total Ni)] ratio of 0.13 or more and 0.23 or less. In a copper foil clad laminate which uses a copper foil for a printed circuit obtained by performing roughening treatment on a surface of a copper foil and then forming a heat-resistant layer and a rust-preventive layer thereon, and to which silane coupling treatment is subsequently performed, the copper foil for a printed circuit can further inhibit the deterioration in adhesion caused by the acid infiltration into the interface of the copper foil circuit and the substrate resin upon performing acid treatment or chemical etching to the substrate after forming a fine-pattern printed circuit. Thus, the copper foil for printed circuit has superior acid-resistant adhesive strength and superior alkali etchability.
    • 提供一种具有表面处理层的铜箔,其中铜箔或铜合金箔包括通过粗糙化处理在铜箔或铜合金箔上形成的粗糙层构成的多个表面处理层,耐热层 由形成在粗糙层上的Ni-Co层制成,并且在耐热层上形成含有Zn,Ni和Cr的耐候层和防锈层,并且表面处理层具有(总计 Zn)/ [(总Zn)+(总Ni)]比为0.13以上且0.23以下。 在使用铜箔作为印刷电路的铜箔复合层叠体上,通过对铜箔的表面进行粗糙化处理,然后在其上形成耐热层和防锈层而得到,并且硅烷偶联处理为 随后,印刷电路用铜箔可以进一步抑制由于在形成精细图案之后对基板进行酸处理或化学蚀刻时,酸浸入到铜箔电路和基板树脂的界面中引起的粘附性的劣化 印刷电路 因此,用于印刷电路的铜箔具有优异的耐酸粘合强度和优异的碱蚀刻性。