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1. 发明授权

US08425822B2 Spinning, doping, dedoping and redoping polyaniline fiber 失效
公开(公告)号：US08425822B2
公开(公告)日：2013-04-23
申请号：US13037178
申请日：2011-02-28
申请人： Benjamin R. Mattes , Phillip N. Adams , Dali Yang , Lori A. Brown , Andrei G. Fadeev , Ian D. Norris
发明人： Benjamin R. Mattes , Phillip N. Adams , Dali Yang , Lori A. Brown , Andrei G. Fadeev , Ian D. Norris
IPC分类号： D01D5/06 , D01F6/74 , H01B1/12
CPC分类号： C08L79/02 , C08G73/0266 , C08K5/42 , D01D5/06 , D01F6/74 , H01B1/128
摘要： A composition of matter suitable for spinning polyaniline fiber, a method for spinning electrically conductive polyaniline fiber, a method for exchanging dopants in polyaniline fibers, and methods for dedoping and redoping polyaniline fibers are described.

2. 发明申请

US20110266503A1 SPINNING, DOPING, DEDOPING AND REDOPING POLYANILINE FIBER 失效
标题翻译：旋转，掺杂，切割和缩小聚氨酯纤维
公开(公告)号：US20110266503A1
公开(公告)日：2011-11-03
申请号：US13037178
申请日：2011-02-28
申请人： Benjamin R. Mattes , Phillip N. Adams , Dali Yang , Lori A. Brown , Andrei G. Fadeev , Ian D. Norris
发明人： Benjamin R. Mattes , Phillip N. Adams , Dali Yang , Lori A. Brown , Andrei G. Fadeev , Ian D. Norris
IPC分类号： H01B1/12
CPC分类号： C08L79/02 , C08G73/0266 , C08K5/42 , D01D5/06 , D01F6/74 , H01B1/128
摘要： A composition of matter suitable for spinning polyaniline fiber, a method for spinning electrically conductive polyaniline fiber, a method for exchanging dopants in polyaniline fibers, and methods for dedoping and redoping polyaniline fibers are described.
摘要翻译：描述了适用于纺丝聚苯胺纤维的物质组合物，导电聚苯胺纤维的纺丝方法，聚苯胺纤维中的掺杂剂的交换方法以及聚苯胺纤维的去掺杂和重掺杂方法。

3. 发明授权

US06982514B1 Electrochemical devices incorporating high-conductivity conjugated polymers 失效
标题翻译：掺有高导电性共轭聚合物的电化学装置
公开(公告)号：US06982514B1
公开(公告)日：2006-01-03
申请号：US09863808
申请日：2001-05-22
申请人： Wen Lu , Elisabeth Smela , Benjamin R. Mattes , Philip N. Adams , Guido Zuccarello
发明人： Wen Lu , Elisabeth Smela , Benjamin R. Mattes , Philip N. Adams , Guido Zuccarello
IPC分类号： H02N11/00 , H02N2/00
CPC分类号： F03G7/005 , H01B1/127 , H01B1/128 , H02N11/006 , Y10S310/80
摘要： The present invention includes the preparation of highly conducting conjugated polymers and their use as electrochemical actuators, A typical electrochemical actuator comprises a highly conducting, conjugated polymer for the anode or the cathode, or for both the anode and the cathode; suitable conjugate polymers have a conductivity ≧100 S/cm. The material may have any form, including films and fibers. A preferred shape is a strip or a fiber, where the fiber can be solid or hollow, although any shape may be used. Before use, the material may be treated, for example, by immersion in an acid, in order to dope/protonate the material or to introduce anions or to exchange the anion in the polymer for another anion. Other materials may be incorporated in the polyaniline to increase its conductivity or to provide other benefits, such as increased strength. Useful conducting polymers include monomers of anilines, pyrroles, thiophenes, phenylene vinylenes, and derivatives thereof.
摘要翻译：本发明包括制备高导电性共轭聚合物及其作为电化学致动器的用途。典型的电化学致动器包括用于阳极或阴极或阳极和阴极的高导电共轭聚合物; 合适的共轭聚合物的导电率> 100S / cm。该材料可以具有任何形式，包括膜和纤维。优选的形状是条或纤维，其中纤维可以是固体或中空的，尽管可以使用任何形状。在使用之前，可以例如通过浸入酸中来处理材料，以便掺杂或质子化材料或引入阴离子或交换聚合物中的阴离子用于另一种阴离子。可以将其它材料引入聚苯胺中以增加其导电性或提供其它益处，例如增加的强度。有用的导电聚合物包括苯胺，吡咯，噻吩，亚苯基乙烯基单体及其衍生物。

4. 发明申请

US20100170886A1 MULTIFUNCTIONAL CONDUCTING POLYMER STRUCTURES 审中-公开
标题翻译：多功能导电聚合物结构
公开(公告)号：US20100170886A1
公开(公告)日：2010-07-08
申请号：US12728968
申请日：2010-03-22
申请人： Baohua Qi , Benjamin R. Mattes
发明人： Baohua Qi , Benjamin R. Mattes
IPC分类号： H05B3/02 , G01R27/08
CPC分类号： H01B1/124
摘要： The present invention includes the use of conducting polymers as sensors in distributed sensing systems, as sensors and operating elements in multifunctional devices, and for conducting-polymer based multifunctional sensing fabrics suitable for monitoring humidity, breath, heart rate, blood (location of wounds), blood pressure, skin temperature, weight and movement, in a wearable, electronic embedded sensor system, as examples. A fabric comprising conducting polyaniline fibers that can be used to distribute energy for resistive heating as well as for sensing the fabric temperature is described as an example of a multifunctional sensing fabric.
摘要翻译：本发明包括使用导电聚合物作为分布式感测系统中的传感器，作为多功能装置中的传感器和操作元件，以及适于监测湿度，呼吸，心率，血液（伤口位置）的基于导电聚合物的多功能感测织物，，血压，皮肤温度，重量和运动，在可穿戴的电子嵌入式传感器系统中，作为示例。作为多功能传感织物的实例，描述了包括导电聚苯胺纤维的织物，其可用于分布用于电阻加热的能量以及感测织物温度。

5. 发明授权

US07628944B2 Spinning, doping, dedoping and redoping polyaniline fiber 失效
标题翻译：纺丝，掺杂，去掺杂和重掺杂聚苯胺纤维
公开(公告)号：US07628944B2
公开(公告)日：2009-12-08
申请号：US10672323
申请日：2003-09-26
申请人： Benjamin R. Mattes , Phillip N. Adams , Dali Yang , Lori A. Brown , Andrei G. Fadeev , Ian D. Norris
发明人： Benjamin R. Mattes , Phillip N. Adams , Dali Yang , Lori A. Brown , Andrei G. Fadeev , Ian D. Norris
IPC分类号： D01D5/06 , D01D5/16 , D01D7/00 , D01D10/02 , D01F6/74
CPC分类号： C08L79/02 , C08G73/0266 , C08K5/42 , D01D5/06 , D01F6/74 , H01B1/128
摘要： A composition of matter suitable for spinning polyaniline fiber, a method for spinning electrically conductive polyaniline fiber, a method for exchanging dopants in polyaniline fibers, and methods for dedoping and redoping polyaniline fibers are described.
摘要翻译：描述了适用于纺丝聚苯胺纤维的物质组合物，导电聚苯胺纤维的纺丝方法，聚苯胺纤维中的掺杂剂的交换方法以及聚苯胺纤维的去掺杂和重掺杂方法。

6. 发明授权

US07463040B2 Multifunctional conducting polymer structures 失效
标题翻译：多功能导电聚合物结构
公开(公告)号：US07463040B2
公开(公告)日：2008-12-09
申请号：US10910169
申请日：2004-08-02
申请人： Baohua Qi , Benjamin R. Mattes
发明人： Baohua Qi , Benjamin R. Mattes
IPC分类号： G01R27/08
CPC分类号： H01B1/124
摘要： The present invention includes the use of conducting polymers as sensors in distributed sensing systems, as sensors and operating elements in multifunctional devices, and for conducting-polymer based multifunctional sensing fabrics suitable for monitoring humidity, breath, heart rate, blood (location of wounds), blood pressure, skin temperature, weight and movement, in a wearable, electronic embedded sensor system, as examples. A fabric comprising conducting polyaniline fibers that can be used to distribute energy for resistive heating as well as for sensing the fabric temperature is described as an example of a multifunctional sensing fabric.
摘要翻译：本发明包括使用导电聚合物作为分布式感测系统中的传感器，作为多功能装置中的传感器和操作元件，以及适于监测湿度，呼吸，心率，血液（伤口位置）的基于导电聚合物的多功能感测织物，，血压，皮肤温度，重量和运动，在可穿戴的电子嵌入式传感器系统中，作为示例。作为多功能传感织物的实例，描述了包括导电聚苯胺纤维的织物，其可用于分布用于电阻加热的能量以及感测织物温度。

7. 发明申请

US20100072428A1 SPINNING, DOPING, DEDOPING AND REDOPING POLYANILINE FIBER 有权
标题翻译：旋转，掺杂，切割和缩小聚氨酯纤维
公开(公告)号：US20100072428A1
公开(公告)日：2010-03-25
申请号：US12629759
申请日：2009-12-02
申请人： Benjamin R. Mattes , Phillip N. Adams , Dali Yang , Lori A. Brown , Andrei G. Fadeev , Ian D. Norris
发明人： Benjamin R. Mattes , Phillip N. Adams , Dali Yang , Lori A. Brown , Andrei G. Fadeev , Ian D. Norris
IPC分类号： H01B1/12
CPC分类号： C08L79/02 , C08G73/0266 , C08K5/42 , D01D5/06 , D01F6/74 , H01B1/128
摘要： A composition of matter suitable for spinning polyaniline fiber, a method for spinning electrically conductive polyaniline fiber, a method for exchanging dopants in polyaniline fibers, and methods for dedoping and redoping polyaniline fibers are described.
摘要翻译：描述了适用于纺丝聚苯胺纤维的物质组合物，导电聚苯胺纤维的纺丝方法，聚苯胺纤维中的掺杂剂的交换方法以及聚苯胺纤维的去掺杂和重掺杂方法。

8. 发明授权

US07683643B2 Multifunctional conducting polymer structures 失效
标题翻译：多功能导电聚合物结构
公开(公告)号：US07683643B2
公开(公告)日：2010-03-23
申请号：US12331010
申请日：2008-12-09
申请人： Baohua Qi , Benjamin R. Mattes
发明人： Baohua Qi , Benjamin R. Mattes
IPC分类号： G01R27/08
CPC分类号： H01B1/124
摘要： The present invention includes the use of conducting polymers as sensors in distributed sensing systems, as sensors and operating elements in multifunctional devices, and for conducting-polymer based multifunctional sensing fabrics suitable for monitoring humidity, breath, heart rate, blood (location of wounds), blood pressure, skin temperature, weight and movement, in a wearable, electronic embedded sensor system, as examples. A fabric comprising conducting polyaniline fibers that can be used to distribute energy for resistive heating as well as for sensing the fabric temperature is described as an example of a multifunctional sensing fabric.
摘要翻译：本发明包括使用导电聚合物作为分布式感测系统中的传感器，作为多功能装置中的传感器和操作元件，以及适于监测湿度，呼吸，心率，血液（伤口位置）的基于导电聚合物的多功能感测织物，，血压，皮肤温度，重量和运动，在可穿戴的电子嵌入式传感器系统中，作为示例。作为多功能传感织物的实例，描述了包括导电聚苯胺纤维的织物，其可用于分布用于电阻加热的能量以及感测织物温度。

9. 发明授权

US07288871B1 Solid-in-hollow polymer fiber electrochemical devices 失效
标题翻译：固体中空聚合物纤维电化学装置
公开(公告)号：US07288871B1
公开(公告)日：2007-10-30
申请号：US10886001
申请日：2004-07-06
申请人： Wen Lu , Elisabeth Smela , Phillip N. Adams , Guido Zuccarello , Benjamin R. Mattes
发明人： Wen Lu , Elisabeth Smela , Phillip N. Adams , Guido Zuccarello , Benjamin R. Mattes
IPC分类号： H02N11/00 , B32B23/00
CPC分类号： H02N11/006 , Y10T428/2929 , Y10T428/2933 , Y10T428/2965
摘要： A linear electrochemical actuator is described where at least one electrically conductive (between 400 and 1000 S/cm), doped polyaniline solid fiber or a yarn produced from such fibers is disposed in an electrolyte inside of a electrically conductive polyaniline hollow fiber, thereby allowing 2-electrode operation without a metal backing. This is an example of the electrochemical devices of the present invention having a solid-in-hollow polymer fiber configuration. In a propylene carbonate electrolyte, the electrochemical and actuation behavior of the fibers was found to be influenced by the solubility and size of the polymer dopants. That is, solubility of the dopant in the electrolyte resulted in high electroactivity and strain in the fibers. Actuation of fibers was also affected by electrolyte anions, small anions resulting in anion-exchange dominated actuation, while large anions resulted in cation-exchange dominated actuation. Isotonic strains of 0.9% and isometric stresses of 0.9 MPa were realized for the solid-in-hollow polyaniline fiber actuators.
摘要翻译：描述了线性电化学致动器，其中至少一种导电（在400和1000S / cm）掺杂的聚苯胺固体纤维或由这种纤维产生的纱线设置在导电聚苯胺中空纤维内部的电解质中，从而允许2 - 没有金属背衬的电极操作。这是具有中空聚合物纤维结构的本发明的电化学装置的实例。在碳酸亚丙酯电解质中，发现纤维的电化学和致动性受聚合物掺杂剂的溶解度和尺寸的影响。也就是说，掺杂剂在电解质中的溶解度导致纤维中的高电活性和应变。纤维的致动也受到电解质阴离子的影响，小的阴离子导致阴离子交换主导致动，而大的阴离子导致阳离子交换主导致动。对于固体中空聚苯胺纤维致动器，实现了0.9％的等渗应变和0.9MPa的等长应力。

10. 发明授权

US06936955B1 Conjugated polymer actuator responsive to electrical stimulation 失效
标题翻译：响应于电刺激的共轭聚合物致动器
公开(公告)号：US06936955B1
公开(公告)日：2005-08-30
申请号：US09918293
申请日：2001-07-30
申请人： Elisabeth Smela , Mark W. Tilden , Benjamin R. Mattes
发明人： Elisabeth Smela , Mark W. Tilden , Benjamin R. Mattes
IPC分类号： H02N11/00 , H02N2/00
CPC分类号： H02N11/006
摘要： A conjugated polymer actuator having attached electrodes is described wherein direct electrical stimulation induces changes in the dimensions and mechanical properties thereof without the need for electrolytes or counter electrodes.
摘要翻译：描述了具有连接电极的共轭聚合物致动器，其中直接电刺激引起其尺寸和机械性能的变化，而不需要电解质或对电极。

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