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    • 3. 发明授权
    • Electrochemical devices incorporating high-conductivity conjugated polymers
    • 掺有高导电性共轭聚合物的电化学装置
    • US06982514B1
    • 2006-01-03
    • US09863808
    • 2001-05-22
    • Wen LuElisabeth SmelaBenjamin R. MattesPhilip N. AdamsGuido Zuccarello
    • Wen LuElisabeth SmelaBenjamin R. MattesPhilip N. AdamsGuido Zuccarello
    • H02N11/00H02N2/00
    • F03G7/005H01B1/127H01B1/128H02N11/006Y10S310/80
    • The present invention includes the preparation of highly conducting conjugated polymers and their use as electrochemical actuators, A typical electrochemical actuator comprises a highly conducting, conjugated polymer for the anode or the cathode, or for both the anode and the cathode; suitable conjugate polymers have a conductivity ≧100 S/cm. The material may have any form, including films and fibers. A preferred shape is a strip or a fiber, where the fiber can be solid or hollow, although any shape may be used. Before use, the material may be treated, for example, by immersion in an acid, in order to dope/protonate the material or to introduce anions or to exchange the anion in the polymer for another anion. Other materials may be incorporated in the polyaniline to increase its conductivity or to provide other benefits, such as increased strength. Useful conducting polymers include monomers of anilines, pyrroles, thiophenes, phenylene vinylenes, and derivatives thereof.
    • 本发明包括制备高导电性共轭聚合物及其作为电化学致动器的用途。典型的电化学致动器包括用于阳极或阴极或阳极和阴极的高导电共轭聚合物; 合适的共轭聚合物的导电率> 100S / cm。 该材料可以具有任何形式,包括膜和纤维。 优选的形状是条或纤维,其中纤维可以是固体或中空的,尽管可以使用任何形状。 在使用之前,可以例如通过浸入酸中来处理材料,以便掺杂或质子化材料或引入阴离子或交换聚合物中的阴离子用于另一种阴离子。 可以将其它材料引入聚苯胺中以增加其导电性或提供其它益处,例如增加的强度。 有用的导电聚合物包括苯胺,吡咯,噻吩,亚苯基乙烯基单体及其衍生物。
    • 5. 发明授权
    • Method for preparing polyaniline fibers
    • 聚苯胺纤维的制备方法
    • US06123883A
    • 2000-09-26
    • US334719
    • 1999-06-16
    • Benjamin R. MattesHsing-Lin Wang
    • Benjamin R. MattesHsing-Lin Wang
    • C08J5/18C08G73/00C08G73/02D01F6/26D01F6/76H01B1/12D01D5/06D01F1/09D01F6/96
    • C08G73/0266D01F6/76H01B1/128
    • Stable, concentrated solutions of high molecular weight polyaniline. In order to process high quality fibers and other articles possessing good mechanical properties, it is known that solution concentrations of the chosen polymer should be in the range from 15-30% (w/w). Moreover, it is desirable to use the highest molecular weight consistent with the solubility properties of the polymer. However, such solutions are inherently unstable, forming gels before processing can be achieved. The present invention describes the addition gel inhibitors (GIs) to the polymer solution, thereby permitting high concentrations (>15% (w/w)) of high molecular weight ((M.sub.w)>120,000, and (M.sub.n)>30,000) emeraldine base (EB) polyaniline to be dissolved. Secondary amines have been used for this purpose in concentrations which are small compared to those which might otherwise be used in a cosolvent role therefor. The resulting solutions are useful for generating excellent fibers, films, coatings and other objects, since the solutions are stable for significant time periods, and the GIs are present in too small concentrations to cause polymer deterioration. It is demonstrated that the GIs found to be useful do not act as cosolvents, and that gelation times of the solutions are directly proportional to the concentration of GI. In particular, there is a preferred concentration of GI, which if exceeded causes structural and electrical conductivity degradation of resulting articles. Heating of the solutions significantly improves solubility.
    • 稳定的高分子量聚苯胺浓缩溶液。 为了处理具有良好机械性能的高品质纤维和其它制品,已知所选聚合物的溶液浓度应在15-30%(w / w)的范围内。 此外,期望使用与聚合物的溶解性质一致的最高分子量。 然而,这种溶液固有地不稳定,可以在加工前形成凝胶。 本发明描述了对聚合物溶液的加成凝胶抑制剂(GI),从而允许高分子量((Mw)> 120,000和(Mn)> 30,000)翠绿亚胺碱的高浓度(> 15%(w / w) (EB)聚苯胺溶解。 为了这个目的已经使用了仲胺,其浓度与可能用于其共溶剂作用的那些相比,其用量较小。 所得到的溶液可用于产生优异的纤维,膜,涂层和其它物体,因为溶液在相当长的时间内是稳定的,并且GI以太小的浓度存在以引起聚合物劣化。 证明发现有用的GI不能作为共溶剂,溶液的凝胶化时间与GI的浓度成正比。 特别地,存在优选的GI浓度,如果超过,则导致所得制品的结构和电导率降低。 溶液的加热显着提高了溶解度。
    • 6. 发明授权
    • Stable, concentrated solutions of high molecular weight polyaniline and
articles therefrom
    • 稳定的高分子量聚苯胺浓缩溶液及其制品
    • US5981695A
    • 1999-11-09
    • US926338
    • 1997-09-05
    • Benjamin R. MattesHsing-Lin Wang
    • Benjamin R. MattesHsing-Lin Wang
    • C08J5/18C08G73/00C08G73/02D01F6/26D01F6/76H01B1/12C08J3/00
    • C08G73/0266D01F6/76H01B1/128
    • Stable, concentrated solutions of high molecular weight polyaniline. In order to process high quality fibers and other articles possessing good mechanical properties, it is known that solution concentrations of the chosen polymer should be in the range from 15-30% (w/w). Moreover, it is desirable to use the highest molecular weight consistent with the solubility properties of the polymer. However, such solutions are inherently unstable, forming gels before processing can be achieved. The present invention describes the addition gel inhibitors (GIs) to the polymer solution, thereby permitting high concentrations (between 15% and 30% (w/w)) of high molecular weight ((M.sub.w)>120,000, and (M.sub.n)>30,000) emeraldine base (EB) polyaniline to be dissolved. Secondary amines have been used for this purpose in concentrations which are small compared to those which might otherwise be used in a cosolvent role therefor. The resulting solutions are useful for generating excellent fibers, films, coatings and other objects, since the solutions are stable for significant time periods, and the GIs are present in too small concentrations to cause polymer deterioration. It is demonstrated that the GIs found to be useful do not act as cosolvents, and that gelation times of the solutions are directly proportional to the concentration of GI. In particular, there is a preferred concentration of GI, which if exceeded causes structural and electrical conductivity degradation of resulting articles. Heating of the solutions significantly improves solubility.
    • 稳定的高分子量聚苯胺浓缩溶液。 为了处理具有良好机械性能的高质量纤维和其它制品,已知所选聚合物的溶液浓度应在15-30%(w / w)的范围内。 此外,期望使用与聚合物的溶解性质一致的最高分子量。 然而,这种溶液固有地不稳定,可以在加工前形成凝胶。 本发明描述了对聚合物溶液的添加凝胶抑制剂(GI),从而允许高分子量((Mw)> 120,000和(Mn)> 30,000的高浓度(15%至30%(w / w) )翠绿碱(EB)聚苯胺溶解。 为了这个目的已经使用了仲胺,其浓度与可能用于其共溶剂作用的那些相比,其用量较小。 所得到的溶液可用于产生优异的纤维,膜,涂层和其它物体,因为溶液在相当长的时间内是稳定的,并且GI以太小的浓度存在以引起聚合物劣化。 证明发现有用的GI不能作为共溶剂,溶液的凝胶化时间与GI的浓度成正比。 特别地,存在优选的GI浓度,如果超过,则导致所得制品的结构和电导率降低。 溶液的加热显着提高了溶解度。
    • 8. 发明申请
    • MULTIFUNCTIONAL CONDUCTING POLYMER STRUCTURES
    • 多功能导电聚合物结构
    • US20100170886A1
    • 2010-07-08
    • US12728968
    • 2010-03-22
    • Baohua QiBenjamin R. Mattes
    • Baohua QiBenjamin R. Mattes
    • H05B3/02G01R27/08
    • H01B1/124
    • The present invention includes the use of conducting polymers as sensors in distributed sensing systems, as sensors and operating elements in multifunctional devices, and for conducting-polymer based multifunctional sensing fabrics suitable for monitoring humidity, breath, heart rate, blood (location of wounds), blood pressure, skin temperature, weight and movement, in a wearable, electronic embedded sensor system, as examples. A fabric comprising conducting polyaniline fibers that can be used to distribute energy for resistive heating as well as for sensing the fabric temperature is described as an example of a multifunctional sensing fabric.
    • 本发明包括使用导电聚合物作为分布式感测系统中的传感器,作为多功能装置中的传感器和操作元件,以及适于监测湿度,呼吸,心率,血液(伤口位置)的基于导电聚合物的多功能感测织物, ,血压,皮肤温度,重量和运动,在可穿戴的电子嵌入式传感器系统中,作为示例。 作为多功能传感织物的实例,描述了包括导电聚苯胺纤维的织物,其可用于分布用于电阻加热的能量以及感测织物温度。
    • 10. 发明授权
    • Multifunctional conducting polymer structures
    • 多功能导电聚合物结构
    • US07463040B2
    • 2008-12-09
    • US10910169
    • 2004-08-02
    • Baohua QiBenjamin R. Mattes
    • Baohua QiBenjamin R. Mattes
    • G01R27/08
    • H01B1/124
    • The present invention includes the use of conducting polymers as sensors in distributed sensing systems, as sensors and operating elements in multifunctional devices, and for conducting-polymer based multifunctional sensing fabrics suitable for monitoring humidity, breath, heart rate, blood (location of wounds), blood pressure, skin temperature, weight and movement, in a wearable, electronic embedded sensor system, as examples. A fabric comprising conducting polyaniline fibers that can be used to distribute energy for resistive heating as well as for sensing the fabric temperature is described as an example of a multifunctional sensing fabric.
    • 本发明包括使用导电聚合物作为分布式感测系统中的传感器,作为多功能装置中的传感器和操作元件,以及适于监测湿度,呼吸,心率,血液(伤口位置)的基于导电聚合物的多功能感测织物, ,血压,皮肤温度,重量和运动,在可穿戴的电子嵌入式传感器系统中,作为示例。 作为多功能传感织物的实例,描述了包括导电聚苯胺纤维的织物,其可用于分布用于电阻加热的能量以及感测织物温度。